Huttonite

Last updated
Huttonite
Huttonite unit cell Th green Si grey O red.png
Unit cell of huttonite
General
Category Silicate mineral
Formula
(repeating unit)
ThSiO4
IMA symbol Ht [1]
Strunz classification 9.AD.35
Crystal system Monoclinic
Crystal class Prismatic (2/m)
(same H-M symbol)
Space group P21/n
Unit cell a = 6.77 Å, b = 6.96 Å
c = 6.49 Å; β = 104.99°; Z = 4
Identification
Formula mass 324.12 g/mol
ColorColorless, cream, pale yellow
Crystal habit Prismatic, flattened; typically as anhedral grains
Cleavage Distinct along [001], indistinct along [100]
Fracture Conchoidal
Mohs scale hardness4.5
Luster Adamantine
Streak White
Diaphaneity Transparent to translucent
Specific gravity 7.1
Optical propertiesBiaxial (+)
Refractive index nα = 1.898, nβ = 1.900, nγ = 1.922
Birefringence δ = 0.0240
2V angle 25°
Dispersion r < v (moderate)
Ultraviolet fluorescence Dull white (under shortwave)
Other characteristics Radioactive.svg Radioactive
References [2] [3] [4]

Huttonite is a thorium nesosilicate mineral with the chemical formula Th Si O 4 and which crystallizes in the monoclinic system. It is dimorphous with tetragonal thorite, and isostructual with monazite. An uncommon mineral, huttonite forms transparent or translucent creamcolored crystals. It was first identified in samples of beach sands from the West Coast region of New Zealand by the mineralogist Colin Osborne Hutton (1910–1971). [5] Owing to its rarity, huttonite is not an industrially useful mineral.

Contents

Occurrence

Huttonite was first described in 1950 from beach sand and fluvio-glacial deposits in South Westland, New Zealand, where it was found as anhedral grains of no more than 0.2 mm maximum dimension. It is most prevalent in the sand at Gillespies Beach, near Fox Glacier, [5] [6] which is the type location, where it is accompanied by scheelite, cassiterite, zircon, uranothorite, ilmenite and gold. It was found at a further six nearby locations in less plentiful amounts. [7] Huttonite was extracted from the sands by first fractionating in iodomethane and then electromagnetically. Pure samples were subsequently obtained by handpicking huttonite grains under a microscope. This was accomplished either in the presence of short wave (2540 Å) fluorescent light, where the dull white fluorescence distinguishes it from scheelite (fluoresces blue) and zircon (fluoresces yellow), or by first boiling the impure sample in hydrochloric acid to induce an oxide surface on scheelite and permitting handpicking under visible light. [7]

Hutton suggested the huttonite contained in the beach sand and fluvio-glacial deposits originated from Otago schists or pegmatitic veins in the Southern Alps. [7]

In addition to New Zealand, huttonite has been found in granitic pegmatites of Bogatynia, Poland, [8] where it associated with cheralite, thorogummite, and ningyoite; and in nepheline syenites of Brevik, Norway. [9]

Physical properties

Huttonite typically occurs as anhedral grains with no external crystal faces. It is usually colorless but also appears in colors; such as cream and pale yellow. It has a white streak. It has a hardness of 4.5 and exhibits distinct cleavage parallel to the c-axis [001] and an indistinct cleavage along the a-axis [100].

Structure

Huttonite is a thorium nesosilicate with the chemical formula ThSiO4. It is composed (by weight) of 71.59% thorium, 19.74% oxygen, and 8.67% silicon. Huttonite is found very close to its ideal stoichiometric composition, with impurities contributing less than 7% mole fraction. The most significant impurities to be observed are UO2 and P2O5 . [10]

Atomic environment along a SiO4-ThO5 chain (parallel to the c axis) Huttonite c-axis Th green Si grey O red 2.png
Atomic environment along a SiO4ThO5 chain (parallel to the c axis)

Huttonite crystallizes in the monoclinic system with space group P21/n. The unit cell contains four ThSiO4 units, and has dimensions a = 6.784 ± 0.002Å, b = 6.974 ± 0.003Å, c = 6.500 ± 0.003Å, and interaxis angle β = 104.92 ± 0.03o. The structure is that of a nesosilicate   discrete SiO42 tetrahedra coordinating thorium ions. Each thorium has coordination number nine. Axially, four oxygen atoms, representing the edges of two SiO4 monomers on opposite sides of the thorium atom, form a (SiO4Th) chain parallel to the c axis. Equatorially, five nearly planar oxygen atoms representing vertices of distinct silicate tetrahedra coordinate each thorium. The lengths of the axial ThO bonds are 2.43 Å, 2.51 Å, 2.52 Å, 2.81 Å, and of the equatorial bonds, 2.40 Å, 2.41 Å, 2.41 Å, 2.50 Å, and 2.58 Å. The SiO bonds are nearly equal, with lengths 1.58 Å, 1.62 Å, 1.63 Å, and 1.64 Å. [11]

Huttonite is isostructural with monazite. Substitution of the rare-earth elements and phosphorus of monazite with thorium and silicon of huttonite can occur to generates a solid solution. At the huttonite end-member, continuous rare-earth substitution of thorium of up to 20% by weight has been observed. Thorium substitution in monazite has been observed up to 27% by weight. Substitution of PO4 for SiO4 also occurs associated with the introduction of fluoride, hydroxide, and metal ions. [12]

Huttonite is dimorphic with thorite. Thorite crystallizes in a higher symmetry and lower density tetragonal form in which the thorium atoms coordinate to one less oxygen atom in an octahedral arrangement. Thorite is stable at lower temperatures than huttonite; at 1 atmosphere, the thorite–huttonite phase transition occurs between 1210 and 1225 °C. With increasing pressure the transition temperature increases. This relatively high transition temperature is thought to explain the relative rarity of huttonite on the Earth's crust. [13] Unlike thorite, huttonite is not affected by metamictization.

Related Research Articles

<span class="mw-page-title-main">Mineral</span> Crystalline chemical element or compound formed by geologic processes

In geology and mineralogy, a mineral or mineral species is, broadly speaking, a solid substance with a fairly well-defined chemical composition and a specific crystal structure that occurs naturally in pure form.

<span class="mw-page-title-main">Zircon</span> Zirconium silicate, a mineral belonging to the group of nesosilicates

Zircon is a mineral belonging to the group of nesosilicates and is a source of the metal zirconium. Its chemical name is zirconium(IV) silicate, and its corresponding chemical formula is ZrSiO4. An empirical formula showing some of the range of substitution in zircon is (Zr1–y, REEy)(SiO4)1–x(OH)4x–y. Zircon precipitates from silicate melts and has relatively high concentrations of high field strength incompatible elements. For example, hafnium is almost always present in quantities ranging from 1 to 4%. The crystal structure of zircon is tetragonal crystal system. The natural color of zircon varies between colorless, yellow-golden, red, brown, blue, and green.

<span class="mw-page-title-main">Monazite</span> Mineral containing rare-earth elements

Monazite is a primarily reddish-brown phosphate mineral that contains rare-earth elements. Due to variability in composition, monazite is considered a group of minerals. The most common species of the group is monazite-(Ce), that is, the cerium-dominant member of the group. It occurs usually in small isolated crystals. It has a hardness of 5.0 to 5.5 on the Mohs scale of mineral hardness and is relatively dense, about 4.6 to 5.7 g/cm3. There are five different most common species of monazite, depending on the relative amounts of the rare earth elements in the mineral:

<span class="mw-page-title-main">Cristobalite</span> Silica mineral, polymorph of quartz

Cristobalite is a mineral polymorph of silica that is formed at very high temperatures. It has the same chemical formula as quartz, SiO2, but a distinct crystal structure. Both quartz and cristobalite are polymorphs with all the members of the quartz group, which also include coesite, tridymite and stishovite. It is named after Cerro San Cristóbal in Pachuca Municipality, Hidalgo, Mexico.

<span class="mw-page-title-main">Coffinite</span> Uranium-bearing silicate mineral

Coffinite is a uranium-bearing silicate mineral with formula: U(SiO4)1−x(OH)4x.

<span class="mw-page-title-main">Forsterite</span> Magnesium end-member of olivine, a nesosilicate mineral

Forsterite (Mg2SiO4; commonly abbreviated as Fo; also known as white olivine) is the magnesium-rich end-member of the olivine solid solution series. It is isomorphous with the iron-rich end-member, fayalite. Forsterite crystallizes in the orthorhombic system (space group Pbnm) with cell parameters a 4.75 Å (0.475 nm), b 10.20 Å (1.020 nm) and c 5.98 Å (0.598 nm).

<span class="mw-page-title-main">Thorite</span> Nesosilicate mineral

Thorite, (Th,U)SiO4, is a rare nesosilicate of thorium that crystallizes in the tetragonal system and is isomorphous with zircon and hafnon. It is the most common mineral of thorium and is nearly always strongly radioactive. Thorite was discovered in 1828 on the island of Løvøya, Norway, by the vicar and mineralogist, Hans Morten Thrane Esmark. First specimens of Thorite were sent to his father, Jens Esmark, who was a professor of mineralogy and geology. It was named in 1829 to reflect its thorium content.

<span class="mw-page-title-main">Silicate mineral</span> Rock-forming minerals with predominantly silicate anions

Silicate minerals are rock-forming minerals made up of silicate groups. They are the largest and most important class of minerals and make up approximately 90 percent of Earth's crust.

<span class="mw-page-title-main">Clinohumite</span> Nesosilicate mineral

Clinohumite is an uncommon member of the humite group, a magnesium silicate according to the chemical formula (Mg, Fe)9(SiO4)4(F,OH)2. The formula can be thought of as four olivine (Mg2SiO4), plus one brucite (Mg(OH)2). Indeed, the mineral is essentially a hydrated olivine and occurs in altered ultramafic rocks and carbonatites. Most commonly found as tiny indistinct grains, large euhedral clinohumite crystals are sought by collectors and occasionally fashioned into bright, yellow-orange gemstones. Only two sources of gem-quality material are known: the Pamir Mountains of Tajikistan, and the Taymyr region of northern Siberia. It is one of two humite group minerals that have been cut into gems, the other being the much more common chondrodite.

<span class="mw-page-title-main">Afwillite</span> Nesosilicate alteration mineral also sometimes found in hydrated cement paste

Afwillite is a calcium hydroxide nesosilicate mineral with formula Ca3(SiO3OH)2·2H2O. It occurs as glassy, colorless to white prismatic monoclinic crystals. Its Mohs scale hardness is between 3 and 4. It occurs as an alteration mineral in contact metamorphism of limestone. It occurs in association with apophyllite, natrolite, thaumasite, merwinite, spurrite, gehlenite, ettringite, portlandite, hillebrandite, foshagite, brucite and calcite.

<span class="mw-page-title-main">Hauyne</span> Silicate mineral

Hauyne or haüyne, also called hauynite or haüynite, is a Rare tectosilicate sulfate mineral with endmember formula Na3Ca(Si3Al3)O12(SO4). As much as 5 wt % K2O may be present, and also H2O and Cl. It is a feldspathoid and a member of the sodalite group. Hauyne was first described in 1807 from samples discovered in Vesuvian lavas in Monte Somma, Italy, and was named in 1807 by Brunn-Neergard for the French crystallographer René Just Haüy (1743–1822). It is sometimes used as a gemstone.

<span class="mw-page-title-main">Chondrodite</span>

Chondrodite is a nesosilicate mineral with formula (Mg,Fe)
5
(SiO
4
)
2
(F,OH,O)
2
. Although it is a fairly rare mineral, it is the most frequently encountered member of the humite group of minerals. It is formed in hydrothermal deposits from locally metamorphosed dolomite. It is also found associated with skarn and serpentinite. It was discovered in 1817 at Pargas in Finland, and named from the Greek for "granule", which is a common habit for this mineral.

<span class="mw-page-title-main">Wadsleyite</span> Mineral thought to be abundant in the Earths mantle

Wadsleyite is an orthorhombic mineral with the formula β-(Mg,Fe)2SiO4. It was first found in nature in the Peace River meteorite from Alberta, Canada. It is formed by a phase transformation from olivine (α-(Mg,Fe)2SiO4) under increasing pressure and eventually transforms into spinel-structured ringwoodite (γ-(Mg,Fe)2SiO4) as pressure increases further. The structure can take up a limited amount of other bivalent cations instead of magnesium, but contrary to the α and γ structures, a β structure with the sum formula Fe2SiO4 is not thermodynamically stable. Its cell parameters are approximately a = 5.7 Å, b = 11.71 Å and c = 8.24 Å.

<span class="mw-page-title-main">Julgoldite</span>

Julgoldite is a member of the pumpellyite mineral series, a series of minerals characterized by the chemical bonding of silica tetrahedra with alkali and transition metal cations. Julgoldites, along with more common minerals like epidote and vesuvianite, belong to the subclass of sorosilicates, the rock-forming minerals that contain SiO4 tetrahedra that share a common oxygen to form Si2O7 ions with a charge of 6− (Deer et al., 1996). Julgoldite has been recognized for its importance in low grade metamorphism, forming under shear stress accompanied by relatively low temperatures (Coombs, 1953). Julgoldite was named in honor of Professor Julian Royce Goldsmith (1918–1999) of the University of Chicago.

<span class="mw-page-title-main">Hafnon</span>

Hafnon is a hafnium nesosilicate mineral, chemical formula (Hf,Zr)SiO4 or (Hf,Zr,Th,U,Y)SiO4. In natural zircon ZrSiO4 part of the zirconium is replaced by the very similar hafnium and so natural zircon is never pure ZrSiO4. A zircon with 100% hafnium substitution can be made synthetically and is hafnon.

<span class="mw-page-title-main">Tobermorite</span> Inosilicate alteration mineral in metamorphosed limestone and in skarn

Tobermorite is a calcium silicate hydrate mineral with chemical formula: Ca5Si6O16(OH)2·4H2O or Ca5Si6(O,OH)18·5H2O.

<span class="mw-page-title-main">Malayaite</span>

Malayaite is a calcium tin silicate mineral with formula CaSnOSiO4. It is a member of the titanite group.

<span class="mw-page-title-main">Vlasovite</span>

Vlasovite is a rare inosilicate (chain silicate) mineral with sodium and zirconium, with the chemical formula Na2ZrSi4O11. It was discovered in 1961 at Vavnbed Mountain in the Lovozero Massif, in the Northern Region of Russia. The researchers who first identified it, R P Tikhonenkova and M E Kazakova, named it for Kuzma Aleksevich Vlasov (1905–1964), a Russian mineralogist and geochemist who studied the Lovozero massif, and who was the founder of the Institute of Mineralogy, Geochemistry, and Crystal Chemistry of Rare Elements, Moscow, Russia.

<span class="mw-page-title-main">Fluorellestadite</span> Nesosilicate mineral

Fluorellestadite is a rare nesosilicate of calcium, with sulfate and fluorine, with the chemical formula Ca10(SiO4)3(SO4)3F2. It is a member of the apatite group, and forms a series with hydroxylellestadite.

<span class="mw-page-title-main">Sinoite</span>

Sinoite is rare mineral with the chemical formula Si2N2O. It was first found in 1905 in chondrite meteorites and identified as a distinct mineral in 1965. Sinoite crystallizes upon meteorite impact as grains smaller than 0.2 mm surrounded by Fe-Ni alloys and the mineral enstatite. It is named after its SiNO composition and can be prepared in the laboratory as a silicon oxynitride ceramic.

References

  1. Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine. 85 (3): 291–320. Bibcode:2021MinM...85..291W. doi: 10.1180/mgm.2021.43 . S2CID   235729616.
  2. Anthony, John W.; Richard A. Bideaux; Kenneth W. Bladh; Monte C. Nichols (1995). Handbook of Mineralogy: Silica, Silicates (PDF). Tucson, Arizona: Mineral Data Publishing. ISBN   978-0-9622097-1-0. Archived from the original (PDF) on 2011-07-26. Retrieved 2008-12-14.
  3. "Huttonite Mineral Data". WebMineral.com. Retrieved 2008-12-13.
  4. Mindat.org
  5. 1 2 Pabst, A. (1950). "Monoclinic Thorium Silicate". Nature. 166 (4212): 157. Bibcode:1950Natur.166..157P. doi: 10.1038/166157a0 . PMID   15439198. S2CID   4200225.
  6. Pabst, A.; C. Osborne Hutton (1951). "Huttonite, a new monoclinic thorium silicate" (PDF). Am. Mineral. 36: 60–69.
  7. 1 2 3 Hutton, C. Osborne (1951). "Occurrence, optical properties and chemical composition of huttonite" (PDF). Am. Mineral. 36 (1): 66–69.
  8. Kucha, H (1980). "Continuity in the monazitehuttonite series". Mineralogical Magazine. 43 (332): 1031–1034. Bibcode:1980MinM...43.1031K. doi:10.1180/minmag.1980.043.332.12. S2CID   54584872.
  9. Meldrum, A., Boatner, L.A., Zinkle, S.J., Wang, S.-X., Wang, L.-M., and Ewing, R.C. (1999). "Effects of dose rate and temperature on the crystallinetometamict transformation in the ABO4 orthosilicates". Canadian Mineralogist. 37: 207–221.{{cite journal}}: CS1 maint: multiple names: authors list (link)
  10. Förster H. J., Harlov D. E., Milke R., H.-J.; Harlov, D. E.; Milke, R. (2000). "Composition and Th –U –total Pb ages of huttonite and thorite from Gillespie's Beach,. South Island, New Zealand". The Canadian Mineralogist. 38 (3): 675–684. Bibcode:2000CaMin..38..675F. CiteSeerX   10.1.1.579.7465 . doi:10.2113/gscanmin.38.3.675.{{cite journal}}: CS1 maint: multiple names: authors list (link)
  11. Taylor, Mark; Ewing, R. C. (1978). "The Crystal Structures of the ThSiO4 Polymorphs: Huttonite and Thorite". Acta Crystallogr. B. 34 (4): 1074–1079. Bibcode:1978AcCrB..34.1074T. doi:10.1107/S0567740878004951.
  12. Kucha, Henryk (1980). "Continuity in the monazitehuttonite series". Mineralogical Magazine. 43 (332): 1031–1034. Bibcode:1980MinM...43.1031K. doi:10.1180/minmag.1980.043.332.12. S2CID   54584872.
  13. Speer, J. A. (1980). "The actinide orthosilicates". Reviews in Mineralogy and Geochemistry. 5 (1): 113–135.