Huygens principle of double refraction, named after Dutch physicist Christiaan Huygens, explains the phenomenon of double refraction observed in uniaxial anisotropic material such as calcite. When unpolarized light propagates in such materials (along a direction different from the optical axis), it splits into two different rays, known as ordinary and extraordinary rays. [1] The principle states that every point on the wavefront of birefringent material produces two types of wavefronts or wavelets: spherical wavefronts and ellipsoidal wavefronts. These secondary wavelets, originating from different points, interact and interfere with each other. As a result, the new wavefront is formed by the superposition of these wavelets. [1]
The systematic exploration of light polarization began during the 17th century. In 1669, Rasmus Bartholin made an observation of double refraction in a calcite crystal and documented it in a published work in 1670. [2] Later, in 1690, Huygens identified polarization as a characteristic of light and provided a demonstration using two identical blocks of calcite placed in succession. Each crystal divided an incoming ray of light into two, which Huygens referred to as "regular" and "irregular" (in modern terminology: ordinary and extraordinary). However, if the two crystals were aligned in the same orientation, no further division of the light occurred. [3]
While the Huygens' principle of double refraction explains the phenomenon of double refraction in an optically anisotropic medium, the Huygens–Fresnel principle pertains to the propagation of waves in an optically isotropic medium. [3] [4] According to the Huygens–Fresnel principle, each point on a wavefront can be considered a secondary point source of waves, so a new wavefront is formed after the secondary wavelets have traveled for a period equal to one vibration cycle. This new wavefront can be described as an envelope or tangent surface to these secondary wavelets. [5] Understanding and forecasting the classical wave propagation of light is based on the Huygens-Fresnel principle. [3]
Electric and magnetic fields that are mutually perpendicular and fluctuating give rise to the transverse electromagnetic wave known as light. Electric and magnetic fields are perpendicular to the propagation direction of the wave. For example, if the wave propagation is in the z-direction, both the electric field and the magnetic field lie in the xy-plane. The electric field points in a specific direction in space since it is a vector. The direction of an electromagnetic wave's electric field vector E is referred to as polarization. If the electric field oscillates in the x-direction, the polarization of the light will be linear, along the x-direction. [1] [6]
The electromagnetic wave equation's sinusoidal solution has the following form: [7] where
The wave vector is related to the angular frequency and speed of light c by
where k is the wavenumber (the magnitude of the wave vector) and λ is the wavelength.
If we were able to observe a light wave originating from an ordinary source and directed toward us, such as the light emitted by an incandescent bulb, we would find that it consists of mixture of light waves. These waves exhibit electric field components that fluctuate at a rapid pace, nearly matching the optical frequency itself, with a time scale of approximately 10−14 seconds. Consequently, the direction of oscillation of the electric field vector occurs in all possible planes perpendicular to the direction of the light beam. Unpolarized light is a type of light wave where the electric field vector oscillates in multiple planes. Light emitted by the sun, incandescent lamps, or candle flames is considered to be unpolarized. [1] [5]
The light wave polarization specifies the form and location of the electric field vector's direction at a particular point in space as a function of time (in the plane perpendicular to the propagation direction). There are three possible polarization states for light, depending on where the vector's direction is located. The first is plane or linear polarization, the second is elliptical polarization, and the third is circular polarization.
The light may also be partially polarized in addition to these. The polarization of light cannot be determined by the human eye on its own. However, some animals and insects have a vision that is sensitive to polarization. [1]
Light waves that exhibit oscillation in a single plane are referred to as plane-polarized light waves. In such waves, the electric field vector (E) oscillates exclusively within a single plane that is perpendicular to the direction of wave propagation. This type of wave is also called a linearly polarized wave since the orientation of the field vector at any given point in space and time lies along a line within a plane perpendicular to the wave's direction of propagation. [1] [8]
Materials can be classified into two categories based on their isotropy. Materials that are isotropic have the same physical characteristics throughout. In other words, regardless of the direction in which they are measured, their characteristics, such as optical, electrical, and mechanical, stay constant. Gases, liquids, and amorphous solids like glass are instances of isotropic materials. [9] On the other hand, anisotropic materials show various physical characteristics depending on the direction of measurement. Their characteristics are not constant throughout the substance. Crystal structure, molecule orientation, or the presence of preferred axes can all be causes of anisotropy. Crystals, certain polymers, calcite, and numerous minerals are typical examples of anisotropic materials. The physical characteristics of anisotropic materials, such as refractive index, electrical conductivity, and mechanical qualities, can differ depending on the direction of measurement. [9]
A frequent notion in the study of anisotropic materials, particularly in the context of optics, is the optical axis. It refers to a particular axis within the material along which certain optical characteristics remain unaltered. To put it in another way, the light that travels along the optical axis does not experience anisotropic behaviours on the transverse plane. [10]
It is possible to further divide anisotropic materials into two categories: uniaxial anisotropic and biaxial anisotropic materials. One optical axis, also referred to as the extraordinary axis, exists in uniaxially anisotropic materials. In these materials, light propagating along the optical axis experience the same effects independently of the polarization. The optical plane, also known as the plane of polarization, is perpendicular to the optical axis. Light exhibits birefringence within this plane, which means that the refractive index and all the phenomena associated to that, depend on the polarization. A common effect that can be observed is the splitting of an incident ray into two rays when propagating in a birefringent medium. [9] [10] Due to the presence of two independent optical axes in biaxial anisotropic materials, light travelling in two different directions will experience different optical characteristics. [9]
There are two types of uniaxial material depending on the value of index of refraction for the e-ray and o-ray. When the value of the refractive index of the e-ray (ne) is larger than the index of refraction index of the o-ray(n0), the material is positive uniaxial. On the other hand, when the value of refractive index of the e-ray (ne) is less than index of refraction index of the o-ray (n0), the material is negative uniaxial material. Ice and quartz are examples for positive uniaxial material. Calcite and tourmaline are examples of negative uniaxial materials. [1]
The ordinary ray (o-ray) has a spherical wavefront because the o-ray has a constant refractive index (n0) independent of propagation direction inside the uniaxial material and the same velocity in all directions. On the other hand, the extraordinary ray (E-ray) has an ellipsoidal wavefront due to its refractive index, which varies with the propagation direction within the uniaxial material, leading to different velocities in different directions. The two wavefronts come into contact at the points where they intersect with the optical axis. [1]
When unpolarized light incidents on the birefringent material, the o-ray and e-ray will generate new wavefronts. The new wavefront for the o-ray will be tangent to the spherical wavelets, while the new wavefront for the e-ray will be tangent to the ellipsoidal wavelets. Each plane wavefront propagates straight ahead but with different velocities: V0 for the o-ray and Ve for the e-ray. The direction of the k-vector is always perpendicular to the wavefronts and is calculated from Snell's law. For normal incidence, the o-ray and e-ray having the same k-vector direction. However, the Poynting vector, describing the direction of propagation of optical power, is different for the two rays. The power direction for each ray is determined by connecting the line from the imaginary source on the old wavefront to the intersection point between the new wavefront and the spherical or ellipsoidal wavefront. As a result, the o-ray and e-ray will propagate in different directions with different velocities inside the material. For the e-ray, the angle between the k-vector and the power direction is called walk-off angle. [11]
When a light travels through the crystal, these two wave surfaces follow distinct paths within the crystal. Eventually, two refracted rays emerge as a result of this propagation. [12]
Augustin-Jean Fresnel was a French civil engineer and physicist whose research in optics led to the almost unanimous acceptance of the wave theory of light, excluding any remnant of Newton's corpuscular theory, from the late 1830s until the end of the 19th century. He is perhaps better known for inventing the catadioptric (reflective/refractive) Fresnel lens and for pioneering the use of "stepped" lenses to extend the visibility of lighthouses, saving countless lives at sea. The simpler dioptric stepped lens, first proposed by Count Buffon and independently reinvented by Fresnel, is used in screen magnifiers and in condenser lenses for overhead projectors.
The Fresnel equations describe the reflection and transmission of light when incident on an interface between different optical media. They were deduced by French engineer and physicist Augustin-Jean Fresnel who was the first to understand that light is a transverse wave, when no one realized that the waves were electric and magnetic fields. For the first time, polarization could be understood quantitatively, as Fresnel's equations correctly predicted the differing behaviour of waves of the s and p polarizations incident upon a material interface.
Nonlinear optics (NLO) is the branch of optics that describes the behaviour of light in nonlinear media, that is, media in which the polarization density P responds non-linearly to the electric field E of the light. The non-linearity is typically observed only at very high light intensities (when the electric field of the light is >108 V/m and thus comparable to the atomic electric field of ~1011 V/m) such as those provided by lasers. Above the Schwinger limit, the vacuum itself is expected to become nonlinear. In nonlinear optics, the superposition principle no longer holds.
In physics, total internal reflection (TIR) is the phenomenon in which waves arriving at the interface (boundary) from one medium to another are not refracted into the second ("external") medium, but completely reflected back into the first ("internal") medium. It occurs when the second medium has a higher wave speed than the first, and the waves are incident at a sufficiently oblique angle on the interface. For example, the water-to-air surface in a typical fish tank, when viewed obliquely from below, reflects the underwater scene like a mirror with no loss of brightness (Fig. 1).
Fermat's principle, also known as the principle of least time, is the link between ray optics and wave optics. Fermat's principle states that the path taken by a ray between two given points is the path that can be traveled in the least time.
Optical rotation, also known as polarization rotation or circular birefringence, is the rotation of the orientation of the plane of polarization about the optical axis of linearly polarized light as it travels through certain materials. Circular birefringence and circular dichroism are the manifestations of optical activity. Optical activity occurs only in chiral materials, those lacking microscopic mirror symmetry. Unlike other sources of birefringence which alter a beam's state of polarization, optical activity can be observed in fluids. This can include gases or solutions of chiral molecules such as sugars, molecules with helical secondary structure such as some proteins, and also chiral liquid crystals. It can also be observed in chiral solids such as certain crystals with a rotation between adjacent crystal planes or metamaterials.
Polarization is a property of transverse waves which specifies the geometrical orientation of the oscillations. In a transverse wave, the direction of the oscillation is perpendicular to the direction of motion of the wave. A simple example of a polarized transverse wave is vibrations traveling along a taut string (see image); for example, in a musical instrument like a guitar string. Depending on how the string is plucked, the vibrations can be in a vertical direction, horizontal direction, or at any angle perpendicular to the string. In contrast, in longitudinal waves, such as sound waves in a liquid or gas, the displacement of the particles in the oscillation is always in the direction of propagation, so these waves do not exhibit polarization. Transverse waves that exhibit polarization include electromagnetic waves such as light and radio waves, gravitational waves, and transverse sound waves in solids.
A waveplate or retarder is an optical device that alters the polarization state of a light wave travelling through it. Two common types of waveplates are the half-wave plate, which rotates the polarization direction of linearly polarized light, and the quarter-wave plate, which converts between different elliptical polarizations
Crystal optics is the branch of optics that describes the behaviour of light in anisotropic media, that is, media in which light behaves differently depending on which direction the light is propagating. The index of refraction depends on both composition and crystal structure and can be calculated using the Gladstone–Dale relation. Crystals are often naturally anisotropic, and in some media it is possible to induce anisotropy by applying an external electric field.
Birefringence is the optical property of a material having a refractive index that depends on the polarization and propagation direction of light. These optically anisotropic materials are described as birefringent or birefractive. The birefringence is often quantified as the maximum difference between refractive indices exhibited by the material. Crystals with non-cubic crystal structures are often birefringent, as are plastics under mechanical stress.
In electromagnetics, an evanescent field, or evanescent wave, is an oscillating electric and/or magnetic field that does not propagate as an electromagnetic wave but whose energy is spatially concentrated in the vicinity of the source. Even when there is a propagating electromagnetic wave produced, one can still identify as an evanescent field the component of the electric or magnetic field that cannot be attributed to the propagating wave observed at a distance of many wavelengths.
The Kerr effect, also called the quadratic electro-optic (QEO) effect, is a change in the refractive index of a material in response to an applied electric field. The Kerr effect is distinct from the Pockels effect in that the induced index change for the Kerr effect is directly proportional to the square of the electric field instead of varying linearly with it. All materials show a Kerr effect, but certain liquids display it more strongly than others. The Kerr effect was discovered in 1875 by Scottish physicist John Kerr.
Specular reflection, or regular reflection, is the mirror-like reflection of waves, such as light, from a surface.
In physics, the wavefront of a time-varying wave field is the set (locus) of all points having the same phase. The term is generally meaningful only for fields that, at each point, vary sinusoidally in time with a single temporal frequency.
In crystal optics, the index ellipsoid is a geometric construction which concisely represents the refractive indices and associated polarizations of light, as functions of the orientation of the wavefront, in a doubly-refractive crystal. When this ellipsoid is cut through its center by a plane parallel to the wavefront, the resulting intersection is an ellipse whose major and minor semiaxes have lengths equal to the two refractive indices for that orientation of the wavefront, and have the directions of the respective polarizations as expressed by the electric displacement vector D. The principal semiaxes of the index ellipsoid are called the principal refractive indices.
A polarizer or polariser is an optical filter that lets light waves of a specific polarization pass through while blocking light waves of other polarizations. It can filter a beam of light of undefined or mixed polarization into a beam of well-defined polarization, known as polarized light. Polarizers are used in many optical techniques and instruments. Polarizers find applications in photography and LCD technology. In photography, a polarizing filter can be used to filter out reflections.
In optics, a ray is an idealized geometrical model of light or other electromagnetic radiation, obtained by choosing a curve that is perpendicular to the wavefronts of the actual light, and that points in the direction of energy flow. Rays are used to model the propagation of light through an optical system, by dividing the real light field up into discrete rays that can be computationally propagated through the system by the techniques of ray tracing. This allows even very complex optical systems to be analyzed mathematically or simulated by computer. Ray tracing uses approximate solutions to Maxwell's equations that are valid as long as the light waves propagate through and around objects whose dimensions are much greater than the light's wavelength. Ray optics or geometrical optics does not describe phenomena such as diffraction, which require wave optics theory. Some wave phenomena such as interference can be modeled in limited circumstances by adding phase to the ray model.
An optic axis of a crystal is a direction in which a ray of transmitted light suffers no birefringence. An optic axis is a direction rather than a single line: all rays that are parallel to that direction exhibit the same lack of birefringence.
Treatise on Light: In Which Are Explained the Causes of That Which Occurs in Reflection & Refraction is a book written by Dutch polymath Christiaan Huygens that was published in French in 1690. The book describes Huygens's conception of the nature of light propagation which makes it possible to explain the laws of geometrical optics shown in Descartes's Dioptrique, which Huygens aimed to replace.
For light and other electromagnetic radiation, the plane of polarization is the plane spanned by the direction of propagation and either the electric vector or the magnetic vector, depending on the convention. It can be defined for polarized light, remains fixed in space for linearly-polarized light, and undergoes axial rotation for circularly-polarized light.
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