Kazuhiko Takai

Last updated

Kazuhiko Takai is a professor of applied chemistry at Okayama University and is the recipient of the 2013 Chemical Society of Japan Award for his work on the use of catalytic metals in synthesis reactions. [1] He studied at Kyoto University with Hitosi Nozaki and at the University of California, Berkeley with Clayton Heathcock. [2]

Related Research Articles

Chemistry is the scientific study of the properties and behavior of matter. It is a physical science under natural sciences that covers the elements that make up matter to the compounds made of atoms, molecules and ions: their composition, structure, properties, behavior and the changes they undergo during a reaction with other substances. Chemistry also addresses the nature of chemical bonds in chemical compounds.

<span class="mw-page-title-main">Catalysis</span> Process of increasing the rate of a chemical reaction

Catalysis is the process of increasing the rate of a chemical reaction by adding a substance known as a catalyst. Catalysts are not consumed in the reaction and remain unchanged after it. If the reaction is rapid and the catalyst recycles quickly, very small amounts of catalyst often suffice; mixing, surface area, and temperature are important factors in reaction rate. Catalysts generally react with one or more reactants to form intermediates that subsequently give the final reaction product, in the process of regenerating the catalyst.

<span class="mw-page-title-main">Meitnerium</span> Chemical element, symbol Mt and atomic number 109

Meitnerium is a synthetic chemical element with the symbol Mt and atomic number 109. It is an extremely radioactive synthetic element. The most stable known isotope, meitnerium-278, has a half-life of 4.5 seconds, although the unconfirmed meitnerium-282 may have a longer half-life of 67 seconds. The GSI Helmholtz Centre for Heavy Ion Research near Darmstadt, Germany, first created this element in 1982. It is named after Lise Meitner.

<span class="mw-page-title-main">Seaborgium</span> Chemical element, symbol Sg and atomic number 106

Seaborgium is a synthetic chemical element with the symbol Sg and atomic number 106. It is named after the American nuclear chemist Glenn T. Seaborg. As a synthetic element, it can be created in a laboratory but is not found in nature. It is also radioactive; the most stable known isotope, 269Sg, has a half-life of approximately 14 minutes.

<span class="mw-page-title-main">Ununennium</span> Chemical element, symbol Uue and atomic number 119

Ununennium, also known as eka-francium or element 119, is the hypothetical chemical element with symbol Uue and atomic number 119. Ununennium and Uue are the temporary systematic IUPAC name and symbol respectively, which are used until the element is discovered, confirmed, and a permanent name is decided upon. In the periodic table of the elements, it is expected to be an s-block element, an alkali metal, and the first element in the eighth period. It is the lightest element that has not yet been synthesized.

<span class="mw-page-title-main">Robert Burns Woodward</span> American chemist (1917–1979)

Robert Burns Woodward was an American organic chemist. He is considered by many to be the most preeminent synthetic organic chemist of the twentieth century, having made many key contributions to the subject, especially in the synthesis of complex natural products and the determination of their molecular structure. He also worked closely with Roald Hoffmann on theoretical studies of chemical reactions. He was awarded the Nobel Prize in Chemistry in 1965.

<span class="mw-page-title-main">Epoxide</span> Organic compounds with a carbon-carbon-oxygen ring

In organic chemistry, an epoxide is a cyclic ether, where the ether forms a three-atom ring: two atoms of carbon and one atom of oxygen. This triangular structure has substantial ring strain, making epoxides highly reactive, more so than other ethers. They are produced on a large scale for many applications. In general, low molecular weight epoxides are colourless and nonpolar, and often volatile.

The Reformatsky reaction is an organic reaction which condenses aldehydes or ketones with α-halo esters using metallic zinc to form β-hydroxy-esters:

Deoxygenation is a chemical reaction involving the removal of oxygen atoms from a molecule. The term also refers to the removal of molecular oxygen (O2) from gases and solvents, a step in air-free technique and gas purifiers. As applied to organic compounds, deoxygenation is a component of fuels production as well a type of reaction employed in organic synthesis, e.g. of pharmaceuticals.

<span class="mw-page-title-main">David MacMillan</span> Scottish organic chemist

Sir David William Cross MacMillan is a Scottish chemist and the James S. McDonnell Distinguished University Professor of Chemistry at Princeton University, where he was also the chair of the Department of Chemistry from 2010 to 2015. He shared the 2021 Nobel Prize in Chemistry with Benjamin List "for the development of asymmetric organocatalysis".

<span class="mw-page-title-main">Takai olefination</span>

Takai olefination in organic chemistry describes the organic reaction of an aldehyde with a diorganochromium compound to form an alkene. It is a name reaction, referencing Kazuhiko Takai, who first reported it in 1986. In the original reaction, the organochromium species is generated from iodoform or bromoform and an excess of chromium(II) chloride and the product is a vinyl halide. One main advantage of this reaction is the E-configuration of the double bond that is formed. According to the original report, existing alternatives such as the Wittig reaction only gave mixtures.

<span class="mw-page-title-main">Nozaki–Hiyama–Kishi reaction</span> Coupling reaction used in organic synthesis

The Nozaki–Hiyama–Kishi reaction is a nickel/chromium coupling reaction forming an alcohol from the reaction of an aldehyde with an allyl or vinyl halide. In their original 1977 publication, Tamejiro Hiyama and Hitoshi Nozaki reported on a chromium(II) salt solution prepared by reduction of chromic chloride by lithium aluminium hydride to which was added benzaldehyde and allyl chloride:

Angela K. Wilson is an American scientist and former (2022) President of the American Chemical Society. She currently serves as the John A. Hannah Distinguished Professor of Chemistry, Associate Dean for Strategic Initiatives in the College of Natural Sciences, and Director of the MSU Center for Quantum Computing, Science, and Engineering (MSU-Q) at Michigan State University.

<span class="mw-page-title-main">Yoshito Kishi</span> Japanese chemistry professor (1937–2023)

Yoshito Kishi was a Japanese chemist who was the Morris Loeb Professor of Chemistry at Harvard University. He was known for his contributions to the sciences of organic synthesis and total synthesis.

<span class="mw-page-title-main">Akira Suzuki (chemist)</span> Japanese chemist (born 1930)

Akira Suzuki is a Japanese chemist and Nobel Prize Laureate (2010), who first published the Suzuki reaction, the organic reaction of an aryl- or vinyl-boronic acid with an aryl- or vinyl-halide catalyzed by a palladium(0) complex, in 1979.

Akira Hosomi was a Japanese chemist. He was professor emeritus at Tsukuba University, a fellow of the Chemical Society of Japan, a visiting professor at Chuo University, and an academic advisor at Kyushu University.

<span class="mw-page-title-main">Roger A. Sheldon</span>

Roger Arthur Sheldon is emeritus professor of Biocatalysis and Organic Chemistry at Delft University of Technology in the Netherlands.

<span class="mw-page-title-main">Organotantalum chemistry</span> Chemistry of compounds containing a carbon-to-tantalum bond

Organotantalum chemistry is the chemistry of chemical compounds containing a carbon-to-tantalum chemical bond. A wide variety of compound have been reported, initially with cyclopentadienyl and CO ligands. Oxidation states vary from Ta(V) to Ta(-I).

The Mukaiyama hydration is an organic reaction involving formal addition of an equivalent of water across an olefin by the action of catalytic bis(acetylacetonato)cobalt(II) complex, phenylsilane and atmospheric oxygen to produce an alcohol with Markovnikov selectivity.

Francesca M. Kerton is a green chemist and Professor of Chemistry at Memorial University of Newfoundland, Canada.

References

  1. "Development of Novel Synthetic Organic Reactions by the Use of Group 4-7 Metals". Chemical Society of Japan. September 11, 2014. Retrieved 2020-11-03.
  2. "Kazuhiko Takai". Okayama University Department of Applied Chemistry. Retrieved 2020-11-03.