Metalloles are metallacycle derivatives of cyclopentadiene in which the carbon atom at position 5, the saturated carbon, is replaced by a heteroatom. [1] In contrast to its parent compound, the numbering of the metallole starts at the heteroatom. Some of these compounds are described as organometallic compounds, but in the list below quite a number of metalloids are present too. Some metalloles are fluorescent. [2] Polymeric derivatives of pyrrole and thiophene are of interest in molecular electronics. Metalloles, which can also be viewed as structural analogs of pyrrole, include:
Name | M | d(M-C), Å | d(M-H), Å | α(C-M-C), ° | E, kJ/mol |
---|---|---|---|---|---|
Pyrrole | N | 1.37 | 1.01 | 110 | 0 |
Phosphole | P | 1.81 | 1.425 | 90.5 | 67 |
Arsole | As | 1.94 | 1.53 | 86 | 125 |
Stibole | Sb | 2.14 | 1.725 | 80.5 | 160 |
Bismole | Bi | 2.24 | 1.82 | 78 | 220 |