Methyl perchlorate

Methyl perchlorate

Names
Preferred IUPAC name Methyl perchlorate
Other names Perchloric acid, methyl ester;
Identifiers
CAS Number	17043-56-0 [1]
3D model (JSmol)	Interactive image
ChemSpider	10179111
PubChem CID	12776836
InChI InChI=1S/CH3ClO4/c1-6-2(3,4)5/h1H3 Key: NHZLDRXCSVFATE-UHFFFAOYSA-N
SMILES COCl(=O)(=O)=O
Properties
Chemical formula	CH3ClO4
Molar mass	114.48 g·mol−1
Appearance	liquid
Boiling point	52.0 °C (125.6 °F; 325.1 K)
Hazards
Flash point	−14.8 ± 18.7 °C
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). Infobox references

Methyl perchlorate is an organic chemical compound with the chemical formula C H ₃ Cl O ₄. Its molecular structure is a methyl group covalently bonded by a single bond to a perchlorate group, CH₃−O−Cl(=O)₃, in which chlorine has an oxidation state of +7. Like many other perchlorates, it is a high energy material, more explosive than methyl nitrate. ^[2] It is also a toxic alkylating agent and exposure to the vapor can cause death. ^[3]

It can be prepared by treating iodomethane with a solution of silver perchlorate in benzene,^{[ citation needed ]} distillation of barium methylsulfate and barium perchlorate, or bubbling diazomethane into anhydrous perchloric acid. ^[2]

References

1. Urben, Peter (2017). Bretherick's Handbook of Reactive Chemical Hazards. Elsevier. p. 116. ISBN   9780081010594.
2. Burton, H.; Praill, P. F. G. (Jan 1955) [July 21st, 1954]. "Perchloric acid and some organic perchlorates" (PDF). Analyst. 80: 10. Archived from the original (PDF) on 28 April 2025.
3. "Alkyl Perchlorate Esters - energeticchemical". Energeticchemical. Retrieved 13 June 2017.^{[ unreliable source? ]}