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Names | |
---|---|
IUPAC name 4-(methylamino)phenol sulfate | |
Other names N-methyl-p-aminophenol sulfate, Pictol, p-(methylamino)phenol sulfate, monomethyl-p-aminophenol hemisulfate, Metol, Elon, Rhodol, Enel, Viterol, Scalol, Genol, Satrapol, Photol. | |
Identifiers | |
3D model (JSmol) | |
ChEBI | |
ChemSpider | |
ECHA InfoCard | 100.000.216 |
KEGG | |
PubChem CID | |
UNII | |
CompTox Dashboard (EPA) | |
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Properties | |
(C7H10NO)2SO4 | |
Molar mass | 344.38 g/mol |
Melting point | 260 °C (500 °F; 533 K) |
Hazards | |
GHS labelling: [1] | |
Warning | |
H302, H317, H373, H410 | |
P260, P280, P301+P312+P330 | |
Safety data sheet (SDS) | Oxford MSDS |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). |
Metol (or Elon) is a trade name for the organic compound with the formula [HOC6H4NH2(CH3)]2HSO4. It is the sulfate salt of N-methylaminophenol. This colourless salt is a popular photographic developer used in monochrome photography. [2]
Several methods exist for the preparation of N-methylaminophenol. It arises by decarboxylation of N-4-hydroxyphenylglycine (Glycin). It can be obtained by reaction of hydroquinone with methylamine. [3]
Metol is an excellent developing agent for most continuous tone developer applications, and it has been widely used in published developer formulas as well as commercial products. However, it is difficult to produce highly concentrated developer solutions using Metol, and therefore most Metol developers are supplied in dry chemical mix. A developer containing both Metol and hydroquinone is called an MQ developer. This combination of agents provides greater developer activity since the rate of development by both agents together is greater than the sum of rates of development by each agent used alone (superadditivity). This combination is very versatile; by varying the quantities of Metol, hydroquinone, and restrainer, and adjusting the pH, the entire range of continuous tone developers can be made. Therefore, this form of Metol replaced most other developing agents except for hydroquinone, Phenidone (which is more recent than Metol), and derivatives of Phenidone. Notable formulas include Eastman Kodak D-76 film developer, D-72 print developer, and D-96 motion picture negative developer.
Alfred Bogisch, working for a chemical company owned by Julius Hauff, discovered in 1891 that methylated p-aminophenol has more vigorous developing action than p-aminophenol. Hauff introduced this compound as a developing agent. The exact composition of Bogisch and Hauff's early Metol is unknown, but it was most likely methylated at the ortho position of the benzene ring (p-amino-o-methylphenol), rather than at the amino group. Some time later, Metol came to mean the N-methylated variety, and the o-methylated variety fell out of use. Aktien-Gesellschaft für Anilinfabrikation (AGFA) sold this compound under the trade name Metol, which became by far the most common name, followed by Eastman Kodak's trade name Elon.
Because it has been in use for this purpose for over 100 years, and often by amateur photographers, there is a substantial body of evidence regarding the health problems that contact with Metol can cause. These are principally local dermatitis of the hands and forearms. There is also some evidence of sensitization dermatitis, in which repeated exposure triggers a chronic condition that is resistant to medication. The use of Metol in highly caustic solutions and the presence of other materials in darkrooms that have been implicated in dermatitis—such as hexavalent chromium salts—may exacerbate some health impacts.[ citation needed ]
Kodachrome is the brand name for a color reversal film introduced by Eastman Kodak in 1935. It was one of the first successful color materials and was used for both cinematography and still photography. For many years, Kodachrome was widely used for professional color photography, especially for images intended for publication in print media.
Photographic processing or photographic development is the chemical means by which photographic film or paper is treated after photographic exposure to produce a negative or positive image. Photographic processing transforms the latent image into a visible image, makes this permanent and renders it insensitive to light.
Photographic paper is a paper coated with a light-sensitive chemical, used for making photographic prints. When photographic paper is exposed to light, it captures a latent image that is then developed to form a visible image; with most papers the image density from exposure can be sufficient to not require further development, aside from fixing and clearing, though latent exposure is also usually present. The light-sensitive layer of the paper is called the emulsion, and functions similarly to photographic film. The most common chemistry used is gelatin silver, but other alternatives have also been used.
In the processing of photographic films, plates or papers, the photographic developer is one or more chemicals that convert the latent image to a visible image. Developing agents achieve this conversion by reducing the silver halides, which are pale-colored, into silver metal, which is black when in the form of fine particles. The conversion occurs within the gelatine matrix. The special feature of photography is that the developer acts more quickly on those particles of silver halide that have been exposed to light. When left in developer, all the silver halides will eventually be reduced and turn black. Generally, the longer a developer is allowed to work, the darker the image.
Hair coloring, or hair dyeing, is the practice of changing the color of the hair on humans' heads. The main reasons for this are cosmetic: to cover gray or white hair, to alter hair to create a specific look, to change a color to suit preference or to restore the original hair color after it has been discolored by hairdressing processes or sun bleaching.
The gelatin silver process is the most commonly used chemical process in black-and-white photography, and is the fundamental chemical process for modern analog color photography. As such, films and printing papers available for analog photography rarely rely on any other chemical process to record an image. A suspension of silver salts in gelatin is coated onto a support such as glass, flexible plastic or film, baryta paper, or resin-coated paper. These light-sensitive materials are stable under normal keeping conditions and are able to be exposed and processed even many years after their manufacture. The "dry plate" gelatin process was an improvement on the collodion wet-plate process dominant from the 1850s–1880s, which had to be exposed and developed immediately after coating.
Platinum prints, also called platinotypes, are photographic prints made by a monochrome printing process involving platinum.
Hydroquinone, also known as benzene-1,4-diol or quinol, is an aromatic organic compound that is a type of phenol, a derivative of benzene, having the chemical formula C6H4(OH)2. It has two hydroxyl groups bonded to a benzene ring in a para position. It is a white granular solid. Substituted derivatives of this parent compound are also referred to as hydroquinones. The name "hydroquinone" was coined by Friedrich Wöhler in 1843.
In photography, toning is a method of altering the color of black-and-white photographs. In analog photography, it is a chemical process carried out on metal salt-based prints, such as silver prints, iron-based prints, or platinum or palladium prints. This darkroom process cannot be performed with a color photograph. The effects of this process can be emulated with software in digital photography. Sepia is considered a form of black-and-white or monochrome photography.
Pyrogallol is an organic compound with the formula C6H3(OH)3. It is a water-soluble, white solid although samples are typically brownish because of its sensitivity toward oxygen. It is one of three isomers of benzenetriols.
The E-4 process is a now outdated process for developing color reversal (transparency) photographic film, which was introduced in 1966.
Uranyl nitrate is a water-soluble yellow uranium salt with the formula UO2(NO3)2 · n H2O. The hexa-, tri-, and dihydrates are known. The compound is mainly of interest because it is an intermediate in the preparation of nuclear fuels. In the nuclear industry, it is commonly referred to as yellow salt.
Ethylenediamine (abbreviated as en when a ligand) is the organic compound with the formula C2H4(NH2)2. This colorless liquid with an ammonia-like odor is a basic amine. It is a widely used building block in chemical synthesis, with approximately 500,000 tonnes produced in 1998. Ethylenediamine is the first member of the so-called polyethylene amines.
1,4-Benzoquinone, commonly known as para-quinone, is a chemical compound with the formula C6H4O2. In a pure state, it forms bright-yellow crystals with a characteristic irritating odor, resembling that of chlorine, bleach, and hot plastic or formaldehyde. This six-membered ring compound is the oxidized derivative of 1,4-hydroquinone. The molecule is multifunctional: it exhibits properties of a ketone, being able to form oximes; an oxidant, forming the dihydroxy derivative; and an alkene, undergoing addition reactions, especially those typical for α,β-unsaturated ketones. 1,4-Benzoquinone is sensitive toward both strong mineral acids and alkali, which cause condensation and decomposition of the compound.
Glycin, or N-(4-hydroxyphenyl)glycine, is N-substituted p-aminophenol. It is a photographic developing agent used in classic black-and-white developer solutions. It is not identical to, but derived from glycine, the proteinogenic amino acid. It is typically characterized as thin plates of white or silvery powder, although aged samples appear brown. It is sparingly soluble in water and most organic solvents; it is readily soluble in alkalies and acids.
4-Aminophenol (or para-aminophenol or p-aminophenol) is an organic compound with the formula H2NC6H4OH. Typically available as a white powder, it is commonly used as a developer for black-and-white film, marketed under the name Rodinal.
Photographic developer solutions may contain more than one developing agents, such as Metol and hydroquinone, or Phenidone and hydroquinone. This is because they work together to a synergistic effect, called superadditive development.
FX-55 is an 'eco-friendly' photographic developer for monochrome film devised by Geoffrey Crawley. It was first published in Amateur Photographer.
Xtol is a photographic developer manufactured by Eastman Kodak company.
Foma Bohemia is a photographic private limited company based in Hradec Králové, Czech Republic. It was established in 1921, originally as Fotochema, being renamed in 1995 on privatisation. They are mostly known for their line of black and white films and papers but also produce movie film, X-ray films for medicine and industry and personal dosimetry film along with processing chemicals. They formerly produced aerial and surveillance films.