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Nanofluid-based direct solar collectors are solar thermal collectors where nanoparticles in a liquid medium can scatter and absorb solar radiation. They have recently received interest to efficiently distribute solar energy. Nanofluid-based solar collector have the potential to harness solar radiant energy more efficiently compared to conventional solar collectors. [1] [2] [3] [4] [5] [6] [7] Nanofluids have recently found relevance in applications requiring quick and effective heat transfer such as industrial applications, cooling of microchips, microscopic fluidic applications, etc. Moreover, in contrast to conventional heat transfer (for solar thermal applications [8] ) like water, ethylene glycol, and molten salts, nanofluids are not transparent to solar radiant energy; instead, they absorb and scatter significantly the solar irradiance passing through them. [9] Typical solar collectors use a black-surface absorber to collect the sun's heat energy which is then transferred to a fluid running in tubes embedded within. Various limitations have been discovered with these configuration and alternative concepts have been addressed. Among these, the use of nanoparticles suspended in a liquid is the subject of research. Nanoparticle materials including aluminium, [10] copper, [11] carbon nanotubes [12] and carbon-nanohorns have been added to different base fluids and characterized in terms of their performance for improving heat transfer efficiency. [13]
Dispersing trace amounts of nanoparticles into common base fluids has a significant impact on the optical [14] as well as thermo physical properties of base fluid, mainly increasing the thermal conductivity. This characteristic can be used to effectively capture and transport solar radiation. Enhancement of the solar irradiance absorption capacity leads to a higher heat transfer resulting in more efficient heat transfer as shown in figure 2. The efficiency of a solar thermal system is reliant on several energy conversion steps, which are in turn governed by the effectiveness of the heat transfer processes. While higher conversion efficiency of solar to thermal energy is possible, the key components that need to be improved are the solar collector. An ideal solar collector will absorb the concentrated solar radiation, convert partially that incident solar radiation into heat and transfer the heat to the heat transfer fluid. Higher the heat transfer rate to the fluid leads to higher outlet temperature and higher temperatues leads to improved conversion efficiency in the power cycle. nanoparticles have several orders of magnitude higher heat transfer coefficient when transferring heat immediately to the surrounding fluid. This is simply due to the small size of nanoparticle.
Keblinski et al. [15] had named four main possible mechanisms for the anomalous increase in nanofluids heat transfer which are :
Due to Brownian motion particles randomly move through the liquid. And hence better transport of heat. Although it was originally believed that the fluid motions resulting from Brownian motion of the nanoparticles could explain the enhancement in heat transfer properties, this hypothesis was later rejected.
Liquid molecules can form a layer around the solid particles and there by enhance the local ordering of the atomic structure at the interface region.hence, the atomic structure of such liquid layer is more ordered than that of the bulk liquid.
The effective volume of a cluster is considered much larger than the volume of the particles due to the lower packing fraction of the cluster. Since, heat can be transferred rapidly within the such clusters, the volume fraction of the highly conductive phase is larger than the volume of solid, thus increasing its thermal conductivity
In the last ten years, many experiments have been conducted numerically and analytically to validate the importance of nanofluids.
From the table 1 [16] it is clear that nanofluid-based collector have a higher efficiency than a conventional collector. So, it is clear that we can improve conventional collector simply by adding trace amounts of nano-particles. It has also been observed through numerical simulation that mean outlet temperature increase by increasing volume fraction of nanoparticles, length of tube and decreases by decreasing velocity. [16]
Nanofluids poses the following advantages as compared to conventional fluids which makes them suitable for use in solar collectors:
The fundamental difference between the conventional and nanofluid-based collector lies in the mode of heating of the working fluid. In the former case the sunlight is absorbed by a surface, where as in the latter case the sunlight is directly absorbed by the working fluid (through radiative transfer). On reaching the receiver the solar radiations transfer energy to the nanofluid via scattering and absorption.
Boiling or ebullition is the rapid phase transition from liquid to gas or vapor; the reverse of boiling is condensation. Boiling occurs when a liquid is heated to its boiling point, so that the vapour pressure of the liquid is equal to the pressure exerted on the liquid by the surrounding atmosphere. Boiling and evaporation are the two main forms of liquid vapourization.
Thermal insulation is the reduction of heat transfer between objects in thermal contact or in range of radiative influence. Thermal insulation can be achieved with specially engineered methods or processes, as well as with suitable object shapes and materials.
Heat transfer is a discipline of thermal engineering that concerns the generation, use, conversion, and exchange of thermal energy (heat) between physical systems. Heat transfer is classified into various mechanisms, such as thermal conduction, thermal convection, thermal radiation, and transfer of energy by phase changes. Engineers also consider the transfer of mass of differing chemical species, either cold or hot, to achieve heat transfer. While these mechanisms have distinct characteristics, they often occur simultaneously in the same system.
Thermal radiation is electromagnetic radiation emitted by the thermal motion of particles in matter. Thermal radiation transmits as an electromagnetic wave through both matter and vacuum. When matter absorbs thermal radiation its temperature will tend to rise. All matter with a temperature greater than absolute zero emits thermal radiation. The emission of energy arises from a combination of electronic, molecular, and lattice oscillations in a material. Kinetic energy is converted to electromagnetism due to charge-acceleration or dipole oscillation. At room temperature, most of the emission is in the infrared (IR) spectrum. Thermal radiation is one of the fundamental mechanisms of heat transfer, along with conduction and convection.
A heat sink is a passive heat exchanger that transfers the heat generated by an electronic or a mechanical device to a fluid medium, often air or a liquid coolant, where it is dissipated away from the device, thereby allowing regulation of the device's temperature. In computers, heat sinks are used to cool CPUs, GPUs, and some chipsets and RAM modules. Heat sinks are used with other high-power semiconductor devices such as power transistors and optoelectronics such as lasers and light-emitting diodes (LEDs), where the heat dissipation ability of the component itself is insufficient to moderate its temperature.
Solar thermal energy (STE) is a form of energy and a technology for harnessing solar energy to generate thermal energy for use in industry, and in the residential and commercial sectors. Solar thermal collectors are classified by the United States Energy Information Administration as low-, medium-, or high-temperature collectors. Low-temperature collectors are generally unglazed and used to heat swimming pools or to heat ventilation air. Medium-temperature collectors are also usually flat plates but are used for heating water or air for residential and commercial use.
A heat pipe is a heat-transfer device that employs phase transition to transfer heat between two solid interfaces.
Solar water heating (SWH) is heating water by sunlight, using a solar thermal collector. A variety of configurations are available at varying cost to provide solutions in different climates and latitudes. SWHs are widely used for residential and some industrial applications.
A solar thermal collector collects heat by absorbing sunlight. The term "solar collector" commonly refers to a device for solar hot water heating, but may refer to large power generating installations such as solar parabolic troughs and solar towers or non water heating devices such as solar cooker, solar air heaters.
A phase-change material (PCM) is a substance which releases/absorbs sufficient energy at phase transition to provide useful heat or cooling. Generally the transition will be from one of the first two fundamental states of matter - solid and liquid - to the other. The phase transition may also be between non-classical states of matter, such as the conformity of crystals, where the material goes from conforming to one crystalline structure to conforming to another, which may be a higher or lower energy state.
A coolant is a substance, typically liquid, that is used to reduce or regulate the temperature of a system. An ideal coolant has high thermal capacity, low viscosity, is low-cost, non-toxic, chemically inert and neither causes nor promotes corrosion of the cooling system. Some applications also require the coolant to be an electrical insulator.
Thermal energy storage (TES) is the storage of thermal energy for later reuse. Employing widely different technologies, it allows surplus thermal energy to be stored for hours, days, or months. Scale both of storage and use vary from small to large – from individual processes to district, town, or region. Usage examples are the balancing of energy demand between daytime and nighttime, storing summer heat for winter heating, or winter cold for summer cooling. Storage media include water or ice-slush tanks, masses of native earth or bedrock accessed with heat exchangers by means of boreholes, deep aquifers contained between impermeable strata; shallow, lined pits filled with gravel and water and insulated at the top, as well as eutectic solutions and phase-change materials.
Solar air conditioning, or "solar-powered air conditioning", refers to any air conditioning (cooling) system that uses solar power.
Steam is a substance containing water in the gas phase, often mixed with air and/or an aerosol of liquid water droplets. This may occur due to evaporation or due to boiling, where heat is applied until water reaches the enthalpy of vaporization. Steam that is saturated or superheated is invisible; however, wet steam, a visible mist or aerosol of water droplets, is often referred to as "steam".
Photovoltaic thermal collectors, typically abbreviated as PVT collectors and also known as hybrid solar collectors, photovoltaic thermal solar collectors, PV/T collectors or solar cogeneration systems, are power generation technologies that convert solar radiation into usable thermal and electrical energy. PVT collectors combine photovoltaic solar cells, which convert sunlight into electricity, with a solar thermal collector, which transfers the otherwise unused waste heat from the PV module to a heat transfer fluid. By combining electricity and heat generation within the same component, these technologies can reach a higher overall efficiency than solar photovoltaic (PV) or solar thermal (T) alone.
Solar air heating is a solar thermal technology in which the energy from the sun, insolation, is captured by an absorbing medium and used to heat air. Solar air heating is a renewable energy heating technology used to heat or condition air for buildings or process heat applications. It is typically the most cost-effective out of all the solar technologies, especially in commercial and industrial applications, and it addresses the largest usage of building energy in heating climates, which is space heating and industrial process heating.
A nanofluid is a fluid containing nanometer-sized particles, called nanoparticles. These fluids are engineered colloidal suspensions of nanoparticles in a base fluid. The nanoparticles used in nanofluids are typically made of metals, oxides, carbides, or carbon nanotubes. Common base fluids include water, ethylene glycol and oil.
The liquid droplet radiator (LDR) or previously termed liquid droplet stream radiator is a proposed lightweight radiator for the dissipation of waste heat generated by power plants, propulsion or spacecraft systems in space.
A nanoparticle interfacial layer is a well structured layer of typically organic molecules around a nanoparticle. These molecules are known as stabilizers, capping and surface ligands or passivating agents. The interfacial layer has a significant effect on the properties of the nanoparticle and is therefore often considered as an integral part of a nanoparticle. The interfacial layer has an typical thickness between 0.1 and 4 nm, which is dependent on the type of the molecules the layer is made of. The organic molecules that make up the interfacial layer are often amphiphilic molecules, meaning that they have a polar head group combined with a non-polar tail.
A particle receiver is an object placed on the top of a solar tower on which surface solar energy is concentrated by means of a solar field composed of large number of mirrors, called heliostats. The goal is to transform solar energy into thermal energy that can be used in a heat process, thermochemical process, or in a heat engine to produce electricity in a solar tower power plant. To accomplish this, it is necessary to introduce certain material, called heat transfer medium, to the receiver that is then heated up, either directly or indirectly, by the concentrated solar energy before leaving the receiver at a higher temperature. Unlike receivers used in conventional concentrated solar power (CSP), power plants which employ molten salts as a heat transfer medium that is heated indirectly by flowing through the metal tubes that are exposed to the concentrated solar energy, particle receivers adopt solid particles which then can be heated either directly or indirectly, depending on the technology considered.
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