Rheology is the study of the flow of matter, primarily in a fluid state, but also as "soft solids" or solids under conditions in which they respond with plastic flow rather than deforming elastically in response to an applied force. Rheology is a branch of physics, and it is the science that deals with the deformation and flow of materials, both solids and liquids.
A viscometer is an instrument used to measure the viscosity of a fluid. For liquids with viscosities which vary with flow conditions, an instrument called a rheometer is used. Thus, a rheometer can be considered as a special type of viscometer. Viscometers can measure only constant viscosity, that is, viscosity that does not change with flow conditions.
A non-Newtonian fluid is a fluid that does not follow Newton's law of viscosity, that is, it has variable viscosity dependent on stress. In non-Newtonian fluids, viscosity can change when under force to either more liquid or more solid. Ketchup, for example, becomes runnier when shaken and is thus a non-Newtonian fluid. Many salt solutions and molten polymers are non-Newtonian fluids, as are many commonly found substances such as custard, toothpaste, starch suspensions, corn starch, paint, blood, melted butter, and shampoo.
The Deborah number (De) is a dimensionless number, often used in rheology to characterize the fluidity of materials under specific flow conditions. It quantifies the observation that given enough time even a solid-like material might flow, or a fluid-like material can act solid when it is deformed rapidly enough. Materials that have low relaxation times flow easily and as such show relatively rapid stress decay.
Dynamic mechanical analysis is a technique used to study and characterize materials. It is most useful for studying the viscoelastic behavior of polymers. A sinusoidal stress is applied and the strain in the material is measured, allowing one to determine the complex modulus. The temperature of the sample or the frequency of the stress are often varied, leading to variations in the complex modulus; this approach can be used to locate the glass transition temperature of the material, as well as to identify transitions corresponding to other molecular motions.
Shear stress is the component of stress coplanar with a material cross section. It arises from the shear force, the component of force vector parallel to the material cross section. Normal stress, on the other hand, arises from the force vector component perpendicular to the material cross section on which it acts.
Hemorheology, also spelled haemorheology, or blood rheology, is the study of flow properties of blood and its elements of plasma and cells. Proper tissue perfusion can occur only when blood's rheological properties are within certain levels. Alterations of these properties play significant roles in disease processes. Blood viscosity is determined by plasma viscosity, hematocrit and mechanical properties of red blood cells. Red blood cells have unique mechanical behavior, which can be discussed under the terms erythrocyte deformability and erythrocyte aggregation. Because of that, blood behaves as a non-Newtonian fluid. As such, the viscosity of blood varies with shear rate. Blood becomes less viscous at high shear rates like those experienced with increased flow such as during exercise or in peak-systole. Therefore, blood is a shear-thinning fluid. Contrarily, blood viscosity increases when shear rate goes down with increased vessel diameters or with low flow, such as downstream from an obstruction or in diastole. Blood viscosity also increases with increases in red cell aggregability.
A magnetorheological fluid is a type of smart fluid in a carrier fluid, usually a type of oil. When subjected to a magnetic field, the fluid greatly increases its apparent viscosity, to the point of becoming a viscoelastic solid. Importantly, the yield stress of the fluid when in its active ("on") state can be controlled very accurately by varying the magnetic field intensity. The upshot is that the fluid's ability to transmit force can be controlled with an electromagnet, which gives rise to its many possible control-based applications.
In materials science and continuum mechanics, viscoelasticity is the property of materials that exhibit both viscous and elastic characteristics when undergoing deformation. Viscous materials, like water, resist shear flow and strain linearly with time when a stress is applied. Elastic materials strain when stretched and immediately return to their original state once the stress is removed.
A dilatant material is one in which viscosity increases with the rate of shear strain. Such a shear thickening fluid, also known by the initialism STF, is an example of a non-Newtonian fluid. This behaviour is usually not observed in pure materials, but can occur in suspensions.
Rheometry generically refers to the experimental techniques used to determine the rheological properties of materials, that is the qualitative and quantitative relationships between stresses and strains and their derivatives. The techniques used are experimental. Rheometry investigates materials in relatively simple flows like steady shear flow, small amplitude oscillatory shear, and extensional flow.
The Melt Flow Index (MFI) is a measure of the ease of flow of the melt of a thermoplastic polymer. It is defined as the mass of polymer, in grams, flowing in ten minutes through a capillary of a specific diameter and length by a pressure applied via prescribed alternative gravimetric weights for alternative prescribed temperatures. Polymer processors usually correlate the value of MFI with the polymer grade that they have to choose for different processes, and most often this value is not accompanied by the units, because it is taken for granted to be g/10min. Similarly, the test conditions of MFI measurement are normally expressed in kilograms rather than any other units. The method is described in the similar standards ASTM D1238 and ISO 1133.
In rheology, shear thinning is the non-Newtonian behavior of fluids whose viscosity decreases under shear strain. It is sometimes considered synonymous for pseudo-plastic behaviour, and is usually defined as excluding time-dependent effects, such as thixotropy.
Manfred Hermann Wagner is the author of Wagner model and the molecular stress function theory for polymer rheology. He is a Professor for Polymer engineering and Polymer physics at the Technical University of Berlin.
An acoustic rheometer employs a piezo-electric crystal that can easily launch a successive wave of extensions and contractions into the fluid. It applies an oscillating extensional stress to the system. System response can be interpreted in terms of extensional rheology.
Extensional viscosity is a viscosity coefficient when applied stress is extensional stress. It is often used for characterizing polymer solutions. Extensional viscosity can be measured using rheometers that apply extensional stress. Acoustic rheometer is one example of such devices.
Brookfield Engineering is an engineering and manufacturing company with headquarters in Middleboro, Massachusetts. It is a subsidiary of the conglomerate Ametek. Its product line includes laboratory viscometers, rheometers, texture analyzers, and powder flow testers as well as in-line process instrumentation. These instruments are used by research, design, and process control departments.
The viscosity of a fluid is a measure of its resistance to deformation at a given rate. For liquids, it corresponds to the informal concept of "thickness": for example, syrup has a higher viscosity than water.
Constant viscosity elastic liquids, also known as Boger fluids are elastic fluids with constant viscosity. This creates an effect in the fluid where it flows like a liquid, yet behaves like an elastic solid when stretched out. Most elastic fluids exhibit shear thinning, because they are solutions containing polymers. But Boger fluids are exceptions since they are highly dilute solutions, so dilute that shear thinning caused by the polymers can be ignored. Boger fluids are made primarily by adding a small amount of polymer to a Newtonian fluid with a high viscosity, a typical solution being polyacrylamide mixed with corn syrup. It is a simple compound to synthesize but important to the study of rheology because elastic effects and shear effects can be clearly distinguished in experiments using Boger fluids. Without Boger fluids, it was difficult to determine if a non-Newtonian effect was caused by elasticity, shear thinning, or both; non-Newtonian flow caused by elasticity was rarely identifiable. Since Boger fluids can have constant viscosity, an experiment can be done where the results of the flow rates of a Boger liquid and a Newtonian liquid with the same viscosity can be compared, and the difference in the flow rates would show the change caused by the elasticity of the Boger liquid.
Capillary breakup rheometry is an experimental technique used to assess the extensional rheological response of low viscous fluids. Unlike most shear and extensional rheometers, this technique does not involve active stretch or measurement of stress or strain but exploits only surface tension to create a uniaxial extensional flow. Hence, although it is common practice to use the name rheometer, capillary breakup techniques should be better addressed to as indexers.
