Sarabauite

Last updated
Sarabauite
Sarabauite.jpg
Sarabauite from its type locality, the Sarabau Mine in Malaysia
General
Category Sulfide mineral
Formula
(repeating unit)
CaSb10O10S6
IMA symbol Sbu [1]
Strunz classification 2.MA.10
Crystal system Monoclinic
Crystal class Prismatic (2/m)
(same H-M symbol)
Space group C2/c
Unit cell a = 25.37  Å, b = 5.65 Å
c = 16.87 Å; β = 117.58°; Z = 4
Identification
ColorCarmine red
Crystal habit Red tabular crystals
Cleavage None
Fracture Conchoidal
Tenacity Somewhat sectile
Mohs scale hardness4
Luster Resinous
Streak Orange
Diaphaneity Translucent
Specific gravity 4.8
Optical propertiesBiaxial (–)
Pleochroism x is reddish yellow; y is brownish red
References [2] [3] [4] [5]

Sarabauite (sar-a-bau'-ite) is a red monoclinic sulfide mineral with the chemical formula: CaSb10O10S6. [2]

Contents

Origin of name and type locality

Sarabauite was first described in 1977 and named for its type locality, the Sarabau Mine (Lucky Hill mine) in Sarawak, Malaysia. [2] [4] [6] It has also been reported from the Castelo Branco District of Portugal. [2]

Crystallography

Sarabauite is a monoclinic mineral. [2] [6] Monoclinic minerals have three crystallographic axes of unequal length. Two of the inter-axial angles are 90 degrees, while the third angle, between the optic axis and the plane containing the other two axes, is unequal to the other inter-axial angles. The monoclinic system includes crystal classes with a single twofold rotation axis and/or a mirror plane. Sarabauite is of the 2/m crystal class; it has a 2 fold rotation axis perpendicular to a mirror plane. [7]

Optical properties

Sarabauite is a biaxial negative mineral. [3] All minerals of the monoclinic, orthorhombic, and triclinic systems are biaxial minerals. Unlike uniaxial minerals, biaxial crystals have 2 optic axes. This means they have two directions in which light can travel without birefringence, three principal axes, and accordingly three different indices of refraction. Biaxial minerals are further subdivided by optic sign. The optic angle, 2V, is the angle between the two optic axes that is split by the direction of the lowest index of refraction. If 2V is acute, the mineral is biaxial positive. In sarabauite crystals this angle is obtuse, thus the mineral is biaxial negative. [7]

Geologic setting

The mining region that contains the Sarabau Mine is part of the Sumatra Orogen. The region consists of a system of faults and joints through which hydrothermal fluids responsible for the mineralization of sarabauite rise into the overlying carbonate rock. [4]

Mineral importance

Sarabauite is a notable mineral for its antimony content, fluid inclusions, accompaniment of gold, and its two-stage hydrothermal formation process. The Sarabau Mine is a gold and antimony mine. Sarabauite can be found there in mineral veins through altered limestone containing quartz, wollastonite, calcite, stibnite and senarmonite. [6] Both temperature and fluids are responsible for its formation through a two-stage hydrothermal mineralization process. First, wollastonite, diopside, and epidote form at temperatures over 400 °C. In the second stage, at over 377 °C, sarabauite and native gold develop. Calcite, stibnite, and senarmontite also form during the second stage as the mineralization cools further to 377–194 °C. Sarabauite's formation makes it the only hypogene antimony mineral whose fluid inclusions can be studied in thin section under normal light. [4]

Related Research Articles

<span class="mw-page-title-main">Strontianite</span> Rare carbonate mineral and raw material for the extraction of strontium

Strontianite (SrCO3) is an important raw material for the extraction of strontium. It is a rare carbonate mineral and one of only a few strontium minerals. It is a member of the aragonite group.

<span class="mw-page-title-main">Birefringence</span> Optical phenomenon

Birefringence is the optical property of a material having a refractive index that depends on the polarization and propagation direction of light. These optically anisotropic materials are said to be birefringent. The birefringence is often quantified as the maximum difference between refractive indices exhibited by the material. Crystals with non-cubic crystal structures are often birefringent, as are plastics under mechanical stress.

<span class="mw-page-title-main">Stilbite</span>

Stilbite is the name of a series of tectosilicate minerals of the zeolite group. Prior to 1997, stilbite was recognized as a mineral species, but a reclassification in 1997 by the International Mineralogical Association changed it to a series name, with the mineral species being named:

<span class="mw-page-title-main">Alstonite</span>

Alstonite, also known as bromlite, is a low temperature hydrothermal mineral that is a rare double carbonate of calcium and barium with the formula BaCa(CO
3
)
2
, sometimes with some strontium. Barytocalcite and paralstonite have the same formula but different structures, so these three minerals are said to be trimorphous. Alstonite is triclinic but barytocalcite is monoclinic and paralstonite is trigonal. The species was named Bromlite by Thomas Thomson in 1837 after the Bromley-Hill mine, and alstonite by August Breithaupt of the Freiberg Mining Academy in 1841, after Alston, Cumbria, the base of operations of the mineral dealer from whom the first samples were obtained by Thomson in 1834. Both of these names have been in common use.

<span class="mw-page-title-main">Barytocalcite</span>

Barytocalcite is an anhydrous barium calcium carbonate mineral with the chemical formula BaCa(CO3)2. It is trimorphous with alstonite and paralstonite, that is to say the three minerals have the same formula but different structures. Baryte and quartz pseudomorphs after barytocalcite have been observed.

<span class="mw-page-title-main">Leadhillite</span> Lead sulfate carbonate hydroxide mineral

Leadhillite is a lead sulfate carbonate hydroxide mineral, often associated with anglesite. It has the formula Pb4SO4(CO3)2(OH)2. Leadhillite crystallises in the monoclinic system, but develops pseudo-hexagonal forms due to crystal twinning. It forms transparent to translucent variably coloured crystals with an adamantine lustre. It is quite soft with a Mohs hardness of 2.5 and a relatively high specific gravity of 6.26 to 6.55.

<span class="mw-page-title-main">Vauxite</span>

Vauxite is a phosphate mineral with the chemical formula Fe2+Al2(PO4)2(OH)2·6(H2O). It belongs to the laueite – paravauxite group, paravauxite subgroup, although Mindat puts it as a member of the vantasselite Al4(PO4)3(OH)3·9H2O group. There is no similarity in structure between vauxite and paravauxite Fe2+Al2(PO4)2(OH)2·8H2O or metavauxite Fe3+Al2(PO4)2(OH)2·8H2O, even though they are closely similar chemically, and all minerals occur together as secondary minerals. Vauxite was named in 1922 for George Vaux Junior (1863–1927), an American attorney and mineral collector.

<span class="mw-page-title-main">Optical mineralogy</span> Optical properties of rocks and minerals

Optical mineralogy is the study of minerals and rocks by measuring their optical properties. Most commonly, rock and mineral samples are prepared as thin sections or grain mounts for study in the laboratory with a petrographic microscope. Optical mineralogy is used to identify the mineralogical composition of geological materials in order to help reveal their origin and evolution.

<span class="mw-page-title-main">Langite</span>

Langite is a rare hydrated copper sulfate mineral, with hydroxyl, found almost exclusively in druses of small crystals. It is formed from the oxidation of copper sulfides, and was first described in specimens from Cornwall, United Kingdom. It is dimorphous with wroewolfeite. Langite was discovered in 1864 and named after the physicist and crystallographer Viktor von Lang (1838–1921), who was Professor of Physics at the University of Vienna, Austria.

<span class="mw-page-title-main">Marrite</span>

Marrite (mar'-ite) is a mineral with the chemical formula PbAgAsS3. It is the arsenic equivalent of freieslebenite (PbAgSbS3), but also displays close polyhedral characteristics with sicherite and diaphorite. Marrite was named in honor of geologist John Edward Marr (1857–1933) of Cambridge, England.

<span class="mw-page-title-main">Hagendorfite</span>

Hagendorfite is an iron phosphate mineral with the chemical formula of (Na,Ca)MnFe2(PO4)3 and is named after where the mineral was discovered, Hagendorf-Süd, Bavaria, Germany.

Grandreefite is a rare secondary lead sulfate-fluoride mineral with a general chemical formula, Pb2SO4F2. It is named for the location in which it was discovered in 1989, the Grand Reef Mine in Graham County, Arizona.

<span class="mw-page-title-main">Devilline</span> Sulfate mineral

Devilline is a sulfate mineral with the chemical formula CaCu4(SO4)2(OH)6•3H2O. The name originates from the French chemist's name, Henri Etienne Sainte-Claire Deville (1818–1881).

<span class="mw-page-title-main">Keyite</span>

Keyite is a mineral with the chemical formula Cu2+3Zn4Cd2(AsO4)6 · 2H2O. The name comes from Charles Locke Key, an American mineral dealer who furnished its first specimens. Keyite is monoclinic-prismatic, meaning its crystal form has three unequal axes, two of which have 90° angles between them and one with an angle less than 90°. Keyite belongs to the biaxial optical class, meaning it has more than one axis of anisotropy, in which light travels with zero birefringence, and three indices of refraction, nα = 1.800, nβ, and nγ = 1.870. Being a very rare cadmium copper arsenate, keyite is only found in Tsumeb, Namibia in the Tsumeb mine, a world-famous copper mine known for its abundance of rare and unusual minerals.

<span class="mw-page-title-main">Kröhnkite</span>

Kröhnkite ( Na2Cu(SO4)2•2H2O ) is a rare copper sulfate mineral named after B. Kröhnke who first researched it. Kröhnkite may be replaced by Saranchinaite, the anhydrous form of the mineral, if heated to temperatures above 200 °C (392 °F).

<span class="mw-page-title-main">Tsumcorite</span>

Tsumcorite is a rare hydrated lead arsenate mineral that was discovered in 1971, and reported by Geier, Kautz and Muller. It was named after the TSUMeb CORporation mine at Tsumeb, in Namibia, in recognition of the Corporation's support for mineralogical investigations of the orebody at its Mineral Research Laboratory.

<span class="mw-page-title-main">Pearceite</span>

Pearceite is one of the four so-called "ruby silvers", pearceite Cu(Ag,Cu)6Ag9As2S11, pyrargyrite Ag3SbS3, proustite Ag3AsS3 and miargyrite AgSbS2. It was discovered in 1896 and named after Dr Richard Pearce (1837–1927), a Cornish–American chemist and metallurgist from Denver, Colorado.

<span class="mw-page-title-main">Köttigite</span>

Köttigite is a rare hydrated zinc arsenate which was discovered in 1849 and named by James Dwight Dana in 1850 in honour of Otto Friedrich Köttig (1824–1892), a German chemist from Schneeberg, Saxony, who made the first chemical analysis of the mineral. It has the formula Zn3(AsO4)2·8H2O and it is a dimorph of metaköttigite, which means that the two minerals have the same formula, but a different structure: köttigite is monoclinic and metaköttigite is triclinic. There are several minerals with similar formulae but with other cations in place of the zinc. Iron forms parasymplesite Fe2+3(AsO4)2·8H2O; cobalt forms the distinctively coloured pinkish purple mineral erythrite Co3(AsO4)2·8H2O and nickel forms annabergite Ni3(AsO4)2·8H2O. Köttigite forms series with all three of these minerals and they are all members of the vivianite group.

<span class="mw-page-title-main">Mottramite</span>

Mottramite is an orthorhombic anhydrous vanadate hydroxide mineral, PbCu(VO4)(OH), at the copper end of the descloizite subgroup. It was formerly called cuprodescloizite or psittacinite (this mineral characterized in 1868 by Frederick Augustus Genth). Duhamelite is a calcium- and bismuth-bearing variety of mottramite, typically with acicular habit.

<span class="mw-page-title-main">Talmessite</span>

Talmessite is a hydrated calcium magnesium arsenate, often with significant amounts of cobalt or nickel. It was named in 1960 for the type locality, the Talmessi mine, Anarak district, Iran. It forms a series with β-Roselite, where cobalt replaces some of the magnesium, and with gaitite, where zinc replaces the magnesium. All these minerals are members of the fairfieldite group. Talmessite is dimorphic with wendwilsonite.

References

  1. Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine. 85 (3): 291–320. Bibcode:2021MinM...85..291W. doi: 10.1180/mgm.2021.43 . S2CID   235729616.
  2. 1 2 3 4 5 “Sarabauite” on Mindat.org Accessed 3 December 2010.
  3. 1 2 “Sarabauite Mineral Data” on Webmineral.com Accessed 3 December 2010.
  4. 1 2 3 4 Dill, H.G., and Horn, E.E. (1996) The origin of a hypogene sarabauite-calcite mineralization at the Lucky Hill Au-Sb mine Sarawak, Malaysia. Journal of Southeast Asian Earth Sciences, 14, 29-35.
  5. Handbook of Mineralogy
  6. 1 2 3 Nakai, I., Adachi, H., Akira Kato, S.M., and Nagashima, K. (1978) 'Sarabauite a new oxide sulfide mineral from the Sarabau mine, Sarawak, Malaysia. American Mineralogist, 63, 715-719.
  7. 1 2 Klein, C., and Dutrow, B. (2007) The 23 Edition of the Manual of Mineral Science, 675 p. John Wiley and Sons, Inc. Hoboken, New Jersey, U.S.A.