Columbite, also called niobite, niobite-tantalite and columbate, of general chemical formula (FeII,MnII)Nb2O6, is a black mineral group that is an ore of niobium. It has a submetallic luster and a high density and is a niobate of iron and manganese. This mineral group was first found in Haddam, Connecticut, in the United States. It forms a series with the tantalum-dominant analogue ferrotantalite and one with the manganese-dominant analogue manganocolumbite. The iron-rich member of the columbite group is ferrocolumbite. Some tin and tungsten may be present in the mineral. Yttrocolumbite is the yttrium-rich columbite with the formula (Y,U,Fe)(Nb,Ta)O
4. It is a radioactive mineral found in Mozambique.
Arsenopyrite is an iron arsenic sulfide (FeAsS). It is a hard metallic, opaque, steel grey to silver white mineral with a relatively high specific gravity of 6.1. When dissolved in nitric acid, it releases elemental sulfur. When arsenopyrite is heated, it produces sulfur and arsenic vapor. With 46% arsenic content, arsenopyrite, along with orpiment, is a principal ore of arsenic. When deposits of arsenopyrite become exposed to the atmosphere, the mineral slowly converts into iron arsenates. Arsenopyrite is generally an acid-consuming sulfide mineral, unlike iron pyrite which can lead to acid mine drainage.
Axinite is a brown to violet-brown, or reddish-brown bladed group of minerals composed of calcium aluminium boro-silicate, (Ca,Fe,Mn)3Al2BO3Si4O12OH. Axinite is pyroelectric and piezoelectric.
Ankerite is a calcium, iron, magnesium, manganese carbonate mineral of the group of rhombohedral carbonates with the chemical formula Ca(Fe,Mg,Mn)(CO3)2. In composition it is closely related to dolomite, but differs from this in having magnesium replaced by varying amounts of iron(II) and manganese. It forms a series with dolomite and kutnohorite.
Rhodonite is a manganese inosilicate, with the formula (Mn, Fe, Mg, Ca)SiO3, and member of the pyroxenoid group of minerals, crystallizing in the triclinic system. It commonly occurs as cleavable to compact masses with a rose-red color (its name comes from Ancient Greek ῥόδον (rhódon) 'rose'), often tending to brown due to surface oxidation. The rose-red hue is caused by the manganese cation (Mn2+).
The mineral group tantalite [(Fe, Mn)Ta2O6] is the primary source of the chemical element tantalum, a corrosion (heat and acid) resistant metal. It is chemically similar to columbite, and the two are often grouped together as a semi-singular mineral called coltan or "columbite-tantalite" in many mineral guides. However, tantalite has a much greater specific gravity than columbite (8.0+ compared to columbite's 5.2). Iron-rich tantalite is the mineral tantalite-(Fe) or ferrotantalite and manganese-rich is tantalite-(Mn) or manganotantalite.
Hausmannite is a complex oxide, or a mixed oxide, of manganese containing both di- and tri-valent manganese. Its chemical formula can be represented as MnIIMnIII2O4, or more simply noted as MnO·Mn2O3, or Mn3O4, as commonly done for magnetite, the corresponding iron oxide. It belongs to the spinel group and forms tetragonal crystals. Hausmannite is a brown to black metallic mineral with Mohs hardness of 5.5 and a specific gravity of 4.8.
Loellingite, also spelled löllingite, is an iron arsenide mineral with formula FeAs2. It is often found associated with arsenopyrite (FeAsS) from which it is hard to distinguish. Cobalt, nickel and sulfur substitute in the structure. The orthorhombic lollingite group includes the nickel iron arsenide rammelsbergite and the cobalt iron arsenide safflorite. Leucopyrite is an old synonym for loellingite.
Sperrylite is a platinum arsenide mineral with the chemical formula PtAs2 and is an opaque metallic tin white mineral which crystallizes in the isometric system with the pyrite group structure. It forms cubic, octahedral or pyritohedral crystals in addition to massive and reniform habits. It has a Mohs hardness of 6–7 and a very high specific gravity of 10.6.
Sugilite ( SOO-gə-lyte, -jee-) is a relatively rare pink to purple cyclosilicate mineral with the complex chemical formula KNa2(Fe, Mn, Al)2Li3Si12O30. Sugilite crystallizes in the hexagonal system with prismatic crystals. The crystals are rarely found and the form is usually massive. It has a Mohs hardness of 5.5–6.5 and a specific gravity of 2.75–2.80. It is mostly translucent. Sugilite was first described in 1944 by the Japanese petrologist Ken-ichi Sugi (1901–1948) for an occurrence on Iwagi Islet, Japan, where it is found in an aegirine syenite intrusive stock. It is found in a similar environment at Mont Saint-Hilaire, Quebec, Canada. In the Wessels mine in Northern Cape Province of South Africa, sugilite is mined from a strata-bound manganese deposit. It is also reported from Liguria and Tuscany, Italy; New South Wales, Australia and Madhya Pradesh, India.
Beryllonite is a rare sodium beryllium phosphate mineral with formula NaBePO4. The tabular to prismatic monoclinic crystals vary from colorless to white or pale yellowish, and are transparent with a vitreous luster. Twinning is common and occurs in several forms. It exhibits perfect cleavage in one direction. The hardness is 5.5 to 6 and the specific gravity is 2.8. Refractive indices are nα = 1.552, nβ = 1.558 and nγ = 1.561. A few crystals have been cut and faceted, but, as the refractive index is no higher than that of quartz, they do not make very brilliant gemstones.
Chloritoid is a silicate mineral of metamorphic origin. It is an iron magnesium manganese alumino-silicate hydroxide with formula (Fe, Mg, Mn)
2Al
4Si
2O
10(OH)
4. It occurs as greenish grey to black platy micaceous crystals and foliated masses. Its Mohs hardness is 6.5, unusually high for a platy mineral, and it has a specific gravity of 3.52 to 3.57. It typically occurs in phyllites, schists and marbles.
Zircophyllite is a complex mineral, formula (K,Na)3(Mn,Fe)2+7(Zr,Ti,Nb)2Si8O24(OH,F)7. It crystallizes in the triclinic – pinacoidal crystal class as dark brown to black micaceous plates. It has perfect 001 cleavage, a Mohs hardness of 4 to 4.5 and a specific gravity of 3.34. Its indices of refraction are nα=1.708 nβ=1.738 nγ=1.747 and it has a 2V optical angle of 62°.
Tantite is a rare tantalum oxide mineral with formula: Ta2O5. Tantite forms transparent microscopic colorless triclinic - pedial crystals with an adamantine luster. It has a Mohs hardness of 7 and a high specific gravity of 8.45. Chemical analyses show minor inclusion (1.3%) of niobium oxide.
Microlite was once known as a pale-yellow, reddish-brown, or black isometric mineral composed of sodium calcium tantalum oxide with a small amount of fluorine. Its chemical formula is(Na,Ca)2Ta2O6(O,OH,F). Today it is a name of a group of oxide minerals of a similar stoichiometry having tantalum prevailing over titanium and niobium. The microlite group belongs to a large pyrochlore supergroup that occurs in pegmatites and constitutes an ore of tantalum. It has a Mohs hardness of 5.5 and a variable specific gravity of 4.2 to 6.4. It occurs as disseminated microscopic subtranslucent to opaque octahedral crystals with a refractive index of 2.0 to 2.2. Microlite is also called djalmaite, but both names are now obsolete.
Simpsonite has a general formula of Al4(Ta,Nb)3O13(OH). It occurs as euhedral to subhedral tabular to short and prismatic crystals, commonly in subparallel groups. Under the petrographic microscope it has a very high relief.
Whiteite is a rare hydrated hydroxyphosphate mineral.
Ixiolite is an accessory oxide mineral found in granitic pegmatites. It is an oxide with the general chemical formula (Ta,Nb,Sn,Mn,Fe)4O8 or (Ta,Mn,Nb)O2.
Szklaryite is an extremely rare mineral with the formula []Al6BAs33+O15. It is essentially vacant ("[]"), arsenic-dominant member of dumortierite supergroup, giving a name of szklaryite group. It is one of three quite recently found minerals of this group, the other two being nioboholtite and titanoholtite, all coming from the Szklary village near Ząbkowice Śląskie in Poland. They occur in a unique pegmatite of probable anatectic origin.
Achalaite ((Fe2+, Mn)(Ti, Fe3+, Ta)(Nb, Ta)2O8) is a black mineral of the wodginite group, first discovered in 2013.
Crystal structure of tapiolite
