Tioga Bentonites

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Tioga Ash Beds
Stratigraphic range: Lochkovian-Eifelian
~417.6–390.0  Ma
Type Geological formation
Unit of Helderberg Group, Onodaga Limestone and Marcellus Shale
Sub-unitsBald Hill, Sprout Brook, Tioga Middle Course Zone, and Tioga A-G
Lithology
Primary Tuff
Location
RegionFlag of Indiana.svg  Indiana, Flag of Illinois.svg  Illinois, Flag of Maryland.svg  Maryland, Flag of Michigan.svg  Michigan, Flag of New York.svg  New York, Flag of Ohio.svg  Ohio, Flag of Pennsylvania.svg  Pennsylvania, Flag of Tennessee.svg  Tennessee, Flag of Virginia.svg  Virginia and Flag of West Virginia.svg  West Virginia
CountryFlag of the United States.svg  United States
Extent Appalachian Basin, Illinois Basin and Michigan Basin of
eastern North America
Type section
Named for Tioga Gas Fields
Named byEbright, Fettke, and Ingham

The Tioga Bentonites are a series of ash bed layers occurring in three Sedimentary basins in the eastern and midwestern United States. The primary basin they are found in is the Appalachian Basin, as well as the Illinois Basin and the Michigan Basin. Due to an unconformity these ash beds are not present in the southern Appalachians. [1]

Description

There are 7–15 layers of ash depending on the location covering ~30 million years. These numerous layer are broken down into 4 clusters. The Bald Hill K-bentonites are located in the Kalkberg Formation or New Scotland Formation were deposited 417.6 million years ago. The Sprout Brook K-bentonites are located in the Esopus Formation or Needmore Shale deposited 408.3 million years ago. One cluster called the Tioga Middle Coarse Zone (MCZ) is located in the Onondaga Group deposited 391.4 million years ago. Finally Tioga A-G K-bentonites are located in the Onodaga Group and the Union Springs Member of the Marcellus Formation deposited 390.0 million years ago. [2]

The volcanic ash was deposited in sea water. [1] After sedimentation covered these beds the ash was slowly converted to a meta-Bentonite called Illite. [3] These layers are important because they allow very precise dating of the ash bed with K–Ar dating. Potassium 40 decays at a known rate into Argon 40. Argon is an inert gas. It is released from the rock once it is molten so once the rock or ash solidifies the clock is reset. So when the ratio between K40 and Ar40 is measured the more Ar40 trapped in the rock compared to K40 the older the rock is. [4]

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References

  1. 1 2 Dennison, J. M. (November 1, 1986). "Tioga Bentonite in the Appalachian basin: Final report".{{cite journal}}: Cite journal requires |journal= (help)
  2. Ver Straeten, Charles. "DEVONIAN STRATIGRAPHY AND K-BENTONITES IN THE CHERRY VALLEY – SCHOHARIE VALLEY REGION". Research Gate.{{cite web}}: CS1 maint: url-status (link)
  3. Keller, W.D.; Reynolds, R.C. (January 1986). "Morphology of clay minerals in the smectite-to-illite conversion series by scanning electron microscopy". Research Gate.{{cite web}}: CS1 maint: url-status (link)
  4. "Potassium-Argon Dating". web.archive.org. August 10, 2010. Retrieved February 22, 2023.