Petalite

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Petalite
Petalite.jpg
Petalite from Minas Gerais State, Brazil (size: 3x4 cm)
General
Category Tektosilicate
Formula
(repeating unit)
LiAlSi4O10
IMA symbol Ptl [1]
Strunz classification 9.EF.05
Crystal system Monoclinic
Crystal class Prismatic (2/m)
(same H-M symbol)
Space group P2/a
Unit cell a = 11.737 Å,
b = 5.171 Å,
c = 7.63 Å;
β = 112.54°; Z = 2
Identification
ColorColorless, grey, yellow, pink, to white
Crystal habit Tabular prismatic crystals and columnar masses
Twinning Common on {001}, lamellar
Cleavage Perfect on {001}, poor on {201} with 38.5° angle between the two
Fracture Subconchoidal
Tenacity Brittle
Mohs scale hardness6–6.5
Luster Vitreous, pearly on cleavages
Streak Colorless
Diaphaneity Transparent to translucent
Specific gravity 2.4
Optical propertiesBiaxial (+)
Refractive index nα = 1.504, nβ = 1.510, nγ = 1.516
Birefringence δ = 0.012
2V angle 82–84° measured
Melting point 1350 °C [2]
Fusibility 5
Solubility Insoluble
References [3] [4] [5] [6]

Petalite, also known as castorite, is a lithium aluminum tektosilicate mineral Li Al Si 4 O 10, crystallizing in the monoclinic system. Petalite occurs as colorless, pink, grey, yellow, yellow grey, to white tabular crystals and columnar masses. It occurs in lithium-bearing pegmatites with spodumene, lepidolite, and tourmaline. Petalite is an important ore of lithium, and is converted to spodumene and quartz by heating to ~500 °C and under 3 kbar of pressure in the presence of a dense hydrous alkali borosilicate fluid with a minor carbonate component. [7] Petalite (and secondary spodumene formed from it) is lower in iron than primary spodumene, making it a more useful source of lithium in, e.g., the production of glass. The colorless varieties are often used as gemstones. [ citation needed ]

Contents

Discovery and occurrence

Petalite from Paprok, Nuristan Province, Afghanistan (size: 7.3 x 2.9 x 2.4 cm) Petalite-mun05-92b.jpg
Petalite from Paprok, Nuristan Province, Afghanistan (size: 7.3 × 2.9 × 2.4 cm)

Petalite was discovered in 1800, by Brazilian naturalist and statesman Jose Bonifacio de Andrada e Silva. Type locality: Utö Island, Haninge, Stockholm, Sweden. The name is derived from the Greek word petalon, which means leaf, alluding to its perfect cleavage. [5] [8] [9]

Economic deposits of petalite are found near Kalgoorlie, Western Australia; Aracuai, Minas Gerais, Brazil; Karibib, Namibia; Manitoba, Canada; and Bikita, Zimbabwe.

The first important economic application for petalite was as a raw material for the glass-ceramic cooking ware CorningWare.[ citation needed ] It has been used as a raw material for ceramic glazes.

Related Research Articles

<span class="mw-page-title-main">Amblygonite</span>

Amblygonite is a fluorophosphate mineral, (Li,Na)AlPO4(F,OH), composed of lithium, sodium, aluminium, phosphate, fluoride and hydroxide. The mineral occurs in pegmatite deposits and is easily mistaken for albite and other feldspars. Its density, cleavage and flame test for lithium are diagnostic. Amblygonite forms a series with montebrasite, the low fluorine endmember. Geologic occurrence is in granite pegmatites, high-temperature tin veins, and greisens. Amblygonite occurs with spodumene, apatite, lepidolite, tourmaline, and other lithium-bearing minerals in pegmatite veins. It contains about 10% lithium, and has been utilized as a source of lithium. The chief commercial sources have historically been the deposits of California and France.

<span class="mw-page-title-main">Topaz</span> Silicate mineral

Topaz is a silicate mineral of aluminium and fluorine with the chemical formula Al2SiO4(F,OH)2. It is used as a gemstone in jewelry and other adornments. Common topaz in its natural state is colorless, though trace element impurities can make it pale blue or golden brown to yellow orange. Topaz is often treated with heat or radiation to make it a deep blue, reddish-orange, pale green, pink, or purple.

<span class="mw-page-title-main">Tourmaline</span> Cyclosilicate mineral group

Tourmaline is a crystalline silicate mineral group in which boron is compounded with elements such as aluminium, iron, magnesium, sodium, lithium, or potassium. This gemstone comes in a wide variety of colors.

<span class="mw-page-title-main">Pegmatite</span> Igneous rock with very large interlocked crystals

A pegmatite is an igneous rock showing a very coarse texture, with large interlocking crystals usually greater in size than 1 cm (0.4 in) and sometimes greater than 1 meter (3 ft). Most pegmatites are composed of quartz, feldspar, and mica, having a similar silicic composition to granite. However, rarer intermediate composition and mafic pegmatites are known.

<span class="mw-page-title-main">Fluorite</span> Mineral form of calcium fluoride

Fluorite (also called fluorspar) is the mineral form of calcium fluoride, CaF2. It belongs to the halide minerals. It crystallizes in isometric cubic habit, although octahedral and more complex isometric forms are not uncommon.

<span class="mw-page-title-main">Lepidolite</span> Light micas with substantial lithium

Lepidolite is a lilac-gray or rose-colored member of the mica group of minerals with chemical formula K(Li,Al)3(Al,Si,Rb)4O10(F,OH)2. It is the most abundant lithium-bearing mineral and is a secondary source of this metal. It is the major source of the alkali metal rubidium.

<span class="mw-page-title-main">Spodumene</span> Pyroxene, inosilicate mineral rich in lithium

Spodumene is a pyroxene mineral consisting of lithium aluminium inosilicate, LiAl(SiO3)2, and is a commercially important source of lithium. It occurs as colorless to yellowish, purplish, or lilac kunzite (see below), yellowish-green or emerald-green hiddenite, prismatic crystals, often of great size. Single crystals of 14.3 m (47 ft) in size are reported from the Black Hills of South Dakota, United States.

<span class="mw-page-title-main">Cryolite</span> Halide mineral

Cryolite (Na3AlF6, sodium hexafluoroaluminate) is an uncommon mineral identified with the once-large deposit at Ivittuut on the west coast of Greenland, mined commercially until 1987.

<span class="mw-page-title-main">Nepheline</span> Silica-undersaturated aluminosilicate mineral

Nepheline, also called nephelite (from Ancient Greek νεφέλη (nephélē) 'cloud'), is a rock-forming mineral in the feldspathoid group – a silica-undersaturated aluminosilicate, Na3KAl4Si4O16, that occurs in intrusive and volcanic rocks with low silica, and in their associated pegmatites. It is used in glass and ceramic manufacturing and other industries, and has been investigated as an ore of aluminium.

<span class="mw-page-title-main">Nepheline syenite</span> Holocrystalline plutonic rock

Nepheline syenite is a holocrystalline plutonic rock that consists largely of nepheline and alkali feldspar. The rocks are mostly pale colored, grey or pink, and in general appearance they are not unlike granites, but dark green varieties are also known. Phonolite is the fine-grained extrusive equivalent.

<span class="mw-page-title-main">José Bonifácio de Andrada e Silva</span> Brazilian politician (1763–1838)

José Bonifácio de Andrada e Silva was a Brazilian statesman, naturalist, mineralist, professor and poet, born in Santos, São Paulo, then part of the Portuguese Empire.

<span class="mw-page-title-main">Diopside</span> Pyroxene mineral

Diopside is a monoclinic pyroxene mineral with composition MgCaSi
2
O
6
. It forms complete solid solution series with hedenbergite and augite, and partial solid solutions with orthopyroxene and pigeonite. It forms variably colored, but typically dull green crystals in the monoclinic prismatic class. It has two distinct prismatic cleavages at 87 and 93° typical of the pyroxene series. It has a Mohs hardness of six, a Vickers hardness of 7.7 GPa at a load of 0.98 N, and a specific gravity of 3.25 to 3.55. It is transparent to translucent with indices of refraction of nα=1.663–1.699, nβ=1.671–1.705, and nγ=1.693–1.728. The optic angle is 58° to 63°.

<span class="mw-page-title-main">Elbaite</span> Cyclosilicate, mineral

Elbaite, a sodium, lithium, aluminium boro-silicate, with the chemical composition Na(Li1.5Al1.5)Al6Si6O18(BO3)3(OH)4, is a mineral species belonging to the six-member ring cyclosilicate tourmaline group.

<span class="mw-page-title-main">Lithiophilite</span>

Lithiophilite is a mineral containing the element lithium. It is lithium manganese(II) phosphate with chemical formula LiMnPO4. It occurs in pegmatites often associated with triphylite, the iron end member in a solid solution series. The mineral with intermediate composition is known as sicklerite and has the chemical formula Li(Mn,Fe)PO4). The name lithiophilite is derived from the Greek philos (φιλός) "friend", as lithiophilite is usually found with lithium.

<span class="mw-page-title-main">Pollucite</span> Zeolite mineral

Pollucite is a zeolite mineral with the formula (Cs,Na)2Al2Si4O12·2H2O with iron, calcium, rubidium and potassium as common substituting elements. It is important as a significant ore of caesium and sometimes rubidium. It forms a solid solution series with analcime. It crystallizes in the isometric-hexoctahedral crystal system as colorless, white, gray, or rarely pink and blue masses. Well-formed crystals are rare. It has a Mohs hardness of 6.5 and a specific gravity of 2.9. It has a brittle fracture and no cleavage.

<span class="mw-page-title-main">Zabuyelite</span>

Zabuyelite is the natural mineral form of lithium carbonate, with a formula Li2CO3. It was discovered in 1987 at Lake Zabuye, Tibet, after which it is named. It forms colorless vitreous monoclinic crystals.

<span class="mw-page-title-main">Eucryptite</span>

Eucryptite is a lithium bearing aluminium silicate mineral with formula LiAlSiO4. It crystallizes in the trigonal – rhombohedral crystal system. It typically occurs as granular to massive in form and may pseudomorphically replace spodumene. It has a brittle to conchoidal fracture and indistinct cleavage. It is transparent to translucent and varies from colorless to white to brown. It has a Mohs hardness of 6.5 and a specific gravity of 2.67. Optically it is uniaxial positive with refractive index values of nω = 1.570 – 1.573 and nε = 1.583 – 1.587.

<span class="mw-page-title-main">Zektzerite</span>

The mineral zektzerite is a member of the tuhualite group and was first found in 1966 by Seattle mineralogist Benjamin Bartlett "Bart" Cannon. It was discovered in the Willow creek basin below Silver Star mountain in miarolitic cavities within the alkaline arfvedsonite granite phase of the Golden Horn batholith, Okanogan County, Washington. It is named for Jack Zektzer, mathematician and mineral collector of Seattle, Washington.

<span class="mw-page-title-main">Simpsonite</span>

Simpsonite has a general formula of Al4(Ta,Nb)3O13(OH). It occurs as euhedral to subhedral tabular to short and prismatic crystals, commonly in subparallel groups. Under the petrographic microscope it has a very high relief.

The Fregeneda–Almendra pegmatitic field is a geologic area in the Iberian Peninsula extending across the Portuguese district of Guarda and the Spanish province of Salamanca. Part of the Central Iberian Zone, it is located in the western part of a narrow E–W metamorphic belt. It consists of a variety of granitic pegmatites, where some rocks are rich in lithium. The Li minerals include spodumene, petalite, lithian muscovite and montebrasite.

References

  1. Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine. 85 (3): 291–320. Bibcode:2021MinM...85..291W. doi: 10.1180/mgm.2021.43 . S2CID   235729616.
  2. "Petalite". Digital Fire. Retrieved 23 October 2011.
  3. Anthony, John W.; Bideaux, Richard A.; Bladh, Kenneth W.; Nichols, Monte C. (2005). "Petalite" (PDF). Handbook of Mineralogy. Mineral Data Publishing. Retrieved 14 March 2022.
  4. Webmineral
  5. 1 2 Petalite, Mindat.org
    • Hurlbut, Cornelius S. and Klein, Cornelis, 1985, Manual of Mineralogy, Wiley, 20th ed., pp. 459–460 ISBN   0-471-80580-7
  6. Deer, W. A. (2004). Framework silicates: silica minerals, feldspathoids and the zeolites (2. ed.). London: Geological Soc. p. 296. ISBN   978-1-86239-144-4.
  7. D'Andraba (1800). "Des caractères et des propriétés de plusieurs nouveaux minérauxde Suède et de Norwège , avec quelques observations chimiques faites sur ces substances". Journal de Physique, de Chimie, d'Histoire Naturelle, et des Arts. 51: 239.
  8. Sowerby, James (1811). Exotic mineralogy: Or, Coloured figures of foreign minerals: As a supplement to British mineralogy.