1-Hexadecene

Last updated
1-Hexadecene
1-Hexadecene Structural Formula V1.svg
Names
Preferred IUPAC name
Hexadec-1-ene
Other names
1-Hexadecene; Cetene; 1-Cetene; Hexadecylene-1
Identifiers
3D model (JSmol)
ECHA InfoCard 100.010.097 OOjs UI icon edit-ltr-progressive.svg
PubChem CID
UNII
  • CCCCCCCCCCCCCCC=C
Properties
C16H32
Molar mass 224.432 g·mol−1
AppearanceColorless liquid
Density 0.781 g/cm3
Melting point 4 °C (39 °F; 277 K)
Boiling point 285 °C (545 °F; 558 K)
Hazards
Flash point 132 °C (270 °F; 405 K) [1] [2]
240 °C (464 °F; 513 K) [1] [2]
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

1-Hexadecene, also known as 1-cetene, is a long-chain hydrocarbon and an alkene with the molecular formula CH2=CH(CH2)13CH3. It is one of many isomers of hexadecene. Classified as an alpha-olefin, 1-hexadecene is a colorless liquid. [3] [4] [5]

1-Hexadecene is used as a surfactant in lubricating fluid, a drilling fluid in the boring and drilling industry, and in paper sizing. [2]

However, the high reactivity of 1-hexadecene means that exposure to air could cause oxidation of its surface layer, forming unwanted impurities. It is stored with the use of tank blanketing, and handled in a dry, inert atmosphere. [4]

Related Research Articles

Alkene Chemical compound

In chemistry, an alkene is a hydrocarbon containing a carbon–carbon double bond.

Ethylene Unsaturated hydrocarbon with formula C2H4

Ethylene (IUPAC name: ethene) is a hydrocarbon which has the formula C
2
H
4
or H2C=CH2. It is a colorless flammable gas with a faint "sweet and musky" odor when pure. It is the simplest alkene (a hydrocarbon with carbon-carbon double bonds).

Hydrocarbon Organic compound consisting entirely of hydrogen and carbon

In organic chemistry, a hydrocarbon is an organic compound consisting entirely of hydrogen and carbon. Hydrocarbons are examples of group 14 hydrides. Hydrocarbons are generally colourless and hydrophobic with only weak odours. Because of their diverse molecular structures, it is difficult to generalize further. Most anthropogenic emissions of hydrocarbons are from the burning of fossil fuels including fuel production and combustion. Natural sources of hydrocarbons such as ethylene, isoprene, and monoterpenes come from the emissions of vegetation.

Petroleum engineering Field of engineering concerned with the activities related to the production of hydrocarbons, which can be either crude oil or natural gas

Petroleum engineering is a field of engineering concerned with the activities related to the production of Hydrocarbons, which can be either crude oil or natural gas. Exploration and production are deemed to fall within the upstream sector of the oil and gas industry. Exploration, by earth scientists, and petroleum engineering are the oil and gas industry's two main subsurface disciplines, which focus on maximizing economic recovery of hydrocarbons from subsurface reservoirs. Petroleum geology and geophysics focus on provision of a static description of the hydrocarbon reservoir rock, while petroleum engineering focuses on estimation of the recoverable volume of this resource using a detailed understanding of the physical behavior of oil, water and gas within porous rock at very high pressure.

In chemistry isomerization or isomerisation is the process in which a molecule, ion or molecular fragment is transformed into an isomer with a different chemical structure. Enolization is an example of isomerization, as is tautomerization. When the isomerization occurs intramolecularly it may be called a rearrangement reaction.

Decane is an alkane hydrocarbon with the chemical formula C10H22. Although 75 structural isomers are possible for decane, the term usually refers to the normal-decane ("n-decane"), with the formula CH3(CH2)8CH3. All isomers, however, exhibit similar properties and little attention is paid to the composition. These isomers are flammable liquids. Decane is a component of gasoline (petrol) and kerosene. Like other alkanes, it is a nonpolar solvent, does not dissolve in water, and is readily combustible. Although it is a component of fuels, it is of little importance as a chemical feedstock, unlike a handful of other alkanes.

Cracking (chemistry) Process whereby complex organic molecules are broken down into simpler molecules

In petrochemistry, petroleum geology and organic chemistry, cracking is the process whereby complex organic molecules such as kerogens or long-chain hydrocarbons are broken down into simpler molecules such as light hydrocarbons, by the breaking of carbon-carbon bonds in the precursors. The rate of cracking and the end products are strongly dependent on the temperature and presence of catalysts. Cracking is the breakdown of a large alkane into smaller, more useful alkenes. Simply put, hydrocarbon cracking is the process of breaking a long chain of hydrocarbons into short ones. This process requires high temperatures.

Abiogenic petroleum origin is a fringe science which propose that petroleum and natural gas deposits are mostly formed by inorganic means, rather than by the decomposition of organisms. Thomas Gold's deep gas hypothesis states that some natural gas deposits were formed out of hydrocarbons deep in the Earth's mantle. Theories explaining the origin of petroleum as abiotic are generally not well accepted by the scientific community, and are rejected by most researchers and scientific theories on the subject.

Propene, also known as propylene, is an unsaturated organic compound with the chemical formula . It has one double bond, and is the second simplest member of the alkene class of hydrocarbons. It is a colorless gas with a faint petroleum-like odor.

Butene, also known as butylene, is an alkene with the formula C4H8. The word butene may refer to any of the individual compounds. They are colourless gases that are present in crude oil as a minor constituent in quantities that are too small for viable extraction. Butene is therefore obtained by catalytic cracking of long-chain hydrocarbons left during refining of crude oil. Cracking produces a mixture of products, and the butene is extracted from this by fractional distillation.

The Fischer–Tropsch process is a collection of chemical reactions that converts a mixture of carbon monoxide and hydrogen or water gas into liquid hydrocarbons. These reactions occur in the presence of metal catalysts, typically at temperatures of 150–300 °C (302–572 °F) and pressures of one to several tens of atmospheres. The process was first developed by Franz Fischer and Hans Tropsch at the Kaiser-Wilhelm-Institut für Kohlenforschung in Mülheim an der Ruhr, Germany, in 1925.

Isobutylene Chemical compound

Isobutylene (or 2-methylpropene) is a hydrocarbon with the formula (CH3)2C=CH2. It is a four-carbon branched alkene (olefin), one of the four isomers of butylene. It is a colorless flammable gas, and is of considerable industrial value.

Pentene Chemical compound

Pentenes are alkenes with the chemical formula C
5
H
10
. Each contains one double bond within its molecular structure. Six different compounds are in this class, differing from each other by whether the carbon atoms are attached linearly or in a branched structure, and whether the double bond has a cis or trans form.

Alpha-olefin

Alpha-olefins are a family of organic compounds which are alkenes with a chemical formula CxH2x, distinguished by having a double bond at the primary or alpha (α) position. This location of a double bond enhances the reactivity of the compound and makes it useful for a number of applications.

Linear alpha olefin

Linear alpha olefins (LAO) or normal alpha olefins (NAO) are olefins or alkenes with a chemical formula CxH2x, distinguished from other mono-olefins with a similar molecular formula by linearity of the hydrocarbon chain and the position of the double bond at the primary or alpha position.

1-Butene Chemical compound

1-Butene (or 1-Butylene) is the organic compound with the formula CH3CH2CH=CH2. It is a colorless gas that is easily condensed to give a colorless liquid. It is classified as a linear alpha-olefin. It is one of the isomers of butene (butylene). It is a precursor to diverse products.

1-Octene Chemical compound

1-Octene is an organic compound with a formula CH2CHC6H13. The alkene is classified as a higher olefin and alpha-olefin, meaning that the double bond is located at the alpha (primary) position, endowing this compound with higher reactivity and thus useful chemical properties. 1-Octene is one of the important linear alpha olefins in industry. It is a colourless liquid.

1-Octadecene Chemical compound

1-Octadecene is a long-chain hydrocarbon and an alkene with the molecular formula CH2=CH(CH2)15CH3. It is one of many isomers of octadecene. Classified as an alpha-olefin, 1-octadecene is the longest alkene that is liquid at room temperature.

Decene is an alkene with the formula C
10
H
20
. Decene contains a chain of ten carbon atoms with one double bond. There are many isomers of decene depending on the position and geometry of the double bond. Dec-1-ene is the only isomer of industrial importance. As an alpha olefin, it is used as a comonomer in copolymers and is an intermediate in the production of epoxides, amines, oxo alcohols, synthetic lubricants, synthetic fatty acids and alkylated aromatics.

References

  1. 1 2 "1-Hexadecene for synthesis. CAS 629-73-2, chemical formula CH
    3
    (CH
    2
    )
    13
    CH
    =CH
    2
    "
    . merckmillipore.com. Retrieved 2021-02-14.
  2. 1 2 3 "AlphaPlus 1-Hexadecene Safety Data Sheet" (PDF). Archived from the original (PDF) on 2019-09-24.
  3. Griesbaum, Karl; Behr, Arno; Biedenkapp, Dieter; Voges, Heinz-Werner; Garbe, Dorothea; Paetz, Christian; Collin, Gerd; Mayer, Dieter; Höke (2000). "Hydrocarbons". Ullmann's Encyclopedia of Industrial Chemistry . Weinheim: Wiley-VCH. doi:10.1002/14356007.a13_227.
  4. 1 2 "1-Hexacedene (Alpha Olefin C16)". Archived from the original on 2017-08-25. Retrieved 2017-07-07.
  5. "1-HEXADECENE (ALPHA-OLEFIN C16)". chemicalland21.com. Retrieved 2021-02-14.