Carbon Recycling International

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Carbon Recycling International Inc.
Company type Private
Industry Renewable fuels
Founded2006 (2006)
Headquarters Reykjavík, Iceland
Key people
Lotte Rosenberg CEO
Bjork Kristjansdottir COO
Omar Sigurbjornsson
(Sales and Marketing)
ProductsRenewable methanol
Website Carbonrecycling.com

Carbon Recycling International (CRI) is an Icelandic limited liability company which has developed a technology designed to produce renewable methanol, also known as e-methanol, from carbon dioxide and hydrogen, using water electrolysis or, alternatively, hydrogen captured from industrial waste gases. The technology is trademarked by CRI as Emissions-to-Liquids (ETL) [1] [2] and the renewable methanol produced by CRI is trademarked as Vulcanol. [3] In 2011 CRI became the first company to produce and sell liquid renewable transport fuel produced using only carbon dioxide, water and electricity from renewable sources. [4]

Contents

History

CRI, incorporated in 2006, was founded by Fridrik Jonsson, Art Shulenberger, Oddur Ingolfsson, and KC Tran. [5] In addition to Icelandic individuals and funds, investors include Canadian multinational methanol supplier and distributor Methanex and Chinese multinational automotive manufacturing company Geely.

CRI's first commercial scale plant, the George Olah Plant (named after George Andrew Olah, [6] the 1994 Nobel Prize Laureate in chemistry), was completed in 2011. [7] CRI is currently working on several new projects in parallel, including in an EU Horizon 2020 research programme funded MefCO2 consortium [8] to build a renewable methanol demonstration plant in Germany and in the FreSME consortium [9] to build a renewable methanol demonstration plant in Sweden.

Renewable methanol

Renewable methanol can be used as a fuel, chemical feedstock (including various types of fuels) or blended with gasoline. Fuels which are produced partially or fully from methanol include biodiesel, dimethyl ether or oxymethylene ether, as well as synthetic gasoline from the Mobil methanol-to-gasoline (MTG) process. Gasoline blends range from 3% methanol, which is allowed in European standard gasoline, to 56% methanol, a blend for flexible fuel vehicles [10] which has the same energy density and oxygen content as E85 gasoline. CRI has run fleet tests with a range of lower blends and higher blend options in cars from different manufacturers, including 100% methanol in special flexible fuel vehicles manufactured by Geely. [11] [12] Renewable methanol is compatible with internal combustion engines as well as methanol fuel cells. Internal combustion engines that operate on 100% methanol are in production both for light vehicles, trucks and ships. Methanol fuel cells of varying energy density are available from multiple manufacturers in North America, Europe and Asia.

Production

CRI's first CSP, the GO Plant Carbon Recycling International GO Plant.jpg
CRI's first CSP, the GO Plant

Production of renewable methanol does not depend on agricultural resources, as hydrogen and carbon dioxide are the primary inputs. CRI's emissions-to-liquids production process is based on three main modules, carbon dioxide purification, hydrogen generation and the methanol synthesis and purification system. [13] The catalytic conversion process from hydrogen and carbon dioxide occurs in one step, while production of methanol from fossil fuels, such as natural gas or coal, involves several reforming steps to obtain syngas followed by the catalytic step. [14] Unlike some other power-to-fuel technologies, which use carbon dioxide and hydrogen as inputs, CRI's emissions-to-liquids process also does not require the carbon dioxide to be 'shifted' prior to the synthesis step.

Plants

The George Olah Plant, or the GO Plant, has a name-plate capacity of 5 million liters per year. [15] It is located close to the Blue Lagoon spa facility and HS Orka's Svartsengi power station. The plant can capture and utilize around 10% of the carbon dioxide emitted by the Svartsengi power station. [16]

Legislation

The European Union's renewable energy directive recognizes renewable methanol as a renewable transport fuel from non-biological sources, which means that it can be used as an advanced renewable transport fuel under the EU's renewable fuel blending mandates.

Impact

Carbon dioxide is a major cause of global warming. By removing carbon dioxide from industrial emissions and increasing the availability of energy derived from electricity or low-carbon intensity hydrogen, CRI's process helps to mitigate climate change. Renewable methanol burns cleanly as a fuel and substituting renewable methanol for gasoline and diesel fuels reduces urban emissions of particulate matter, sulphur oxides (SOx) and nitrous oxides (NOx). [17]

CRI's process can also be used to store energy in the form of methanol, especially in cases where the energy source is intermittent. For example, wind and solar power are intermittently available. By storing energy from these sources in liquid chemical form, the generation of electricity and utilization of electricity does not have to be linked in time and space.. Methanol is also a good energy carrier. As a liquid fuel it is easier and cheaper to store and transport than gaseous fuels such as hydrogen or methane.

Future projects

CRI plans to implement standardized CSPs (commercial scale plants), each with a capacity of at least 50,000 tons of methanol production per year. [18]

See also

Related Research Articles

<span class="mw-page-title-main">Methanol</span> CH3OH; simplest alcohol

Methanol is an organic chemical compound and the simplest aliphatic alcohol, with the chemical formula CH3OH. It is a light, volatile, colorless and flammable liquid with a distinctive alcoholic odour similar to that of ethanol . Methanol acquired the name wood alcohol because it was once produced chiefly by the destructive distillation of wood. Today, methanol is mainly produced industrially by hydrogenation of carbon monoxide.

<span class="mw-page-title-main">Biofuel</span> Type of biological fuel

Biofuel is a fuel that is produced over a short time span from biomass, rather than by the very slow natural processes involved in the formation of fossil fuels such as oil. Biofuel can be produced from plants or from agricultural, domestic or industrial biowaste. Biofuels are mostly used for transportation, but can also be used for heating and electricity. Biofuels are regarded as a renewable energy source. The use of biofuel has been subject to criticism regarding the "food vs fuel" debate, varied assessments of their sustainability, and possible deforestation and biodiversity loss as a result of biofuel production.

Syngas, or synthesis gas, is a mixture of hydrogen and carbon monoxide, in various ratios. The gas often contains some carbon dioxide and methane. It is principally used for producing ammonia or methanol. Syngas is combustible and can be used as a fuel. Historically, it has been used as a replacement for gasoline, when gasoline supply has been limited; for example, wood gas was used to power cars in Europe during WWII.

<span class="mw-page-title-main">Gasification</span> Form of energy conversion

Gasification is a process that converts biomass- or fossil fuel-based carbonaceous materials into gases, including as the largest fractions: nitrogen (N2), carbon monoxide (CO), hydrogen (H2), and carbon dioxide (CO2). This is achieved by reacting the feedstock material at high temperatures (typically >700 °C), without combustion, via controlling the amount of oxygen and/or steam present in the reaction. The resulting gas mixture is called syngas (from synthesis gas) or producer gas and is itself a fuel due to the flammability of the H2 and CO of which the gas is largely composed. Power can be derived from the subsequent combustion of the resultant gas, and is considered to be a source of renewable energy if the gasified compounds were obtained from biomass feedstock.

<span class="mw-page-title-main">Ethanol fuel</span> Type of biofuel

Ethanol fuel is fuel containing ethyl alcohol, the same type of alcohol as found in alcoholic beverages. It is most often used as a motor fuel, mainly as a biofuel additive for gasoline.

<span class="mw-page-title-main">Alternative fuel</span> Fuels from sources other than fossil fuels

Alternative fuels, also known as non-conventional and advanced fuels, are fuels derived from sources other than petroleum. Alternative fuels include gaseous fossil fuels like propane, natural gas, methane, and ammonia; biofuels like biodiesel, bioalcohol, and refuse-derived fuel; and other renewable fuels like hydrogen and electricity.

<span class="mw-page-title-main">Liquid fuel</span> Liquids that can be used to create energy

Liquid fuels are combustible or energy-generating molecules that can be harnessed to create mechanical energy, usually producing kinetic energy; they also must take the shape of their container. It is the fumes of liquid fuels that are flammable instead of the fluid. Most liquid fuels in widespread use are derived from fossil fuels; however, there are several types, such as hydrogen fuel, ethanol, and biodiesel, which are also categorized as a liquid fuel. Many liquid fuels play a primary role in transportation and the economy.

Methanol fuel is an alternative biofuel for internal combustion and other engines, either in combination with gasoline or independently. Methanol (CH3OH) is less expensive to sustainably produce than ethanol fuel, although it is more toxic than ethanol and has a lower energy density than gasoline. Methanol is safer for the environment than gasoline, is an anti-freeze agent, prevents dirt and grime buildup within the engine, has a higher ignition temperature, and produces horsepower equivalent to that of super high-octane gasoline. It can readily be used in most modern engines. To prevent vapor lock due to being a simple, pure fuel, a small percentage of other fuel or certain additives can be included. Methanol may be made from fossil fuels or renewable resources, in particular natural gas and coal, or biomass respectively. In the case of the latter, it can be synthesized from CO2 (carbon dioxide) and hydrogen. The vast majority of methanol produced globally is currently made with gas and coal. However, projects, investments, and the production of green-methanol has risen steadily into 2023. Methanol fuel is currently used by racing cars in many countries and has seen increasing adoption by the maritime industry.

<span class="mw-page-title-main">Methanol economy</span>

The methanol economy is a suggested future economy in which methanol and dimethyl ether replace fossil fuels as a means of energy storage, ground transportation fuel, and raw material for synthetic hydrocarbons and their products. It offers an alternative to the proposed hydrogen economy or ethanol economy, although these concepts are not exclusive. Methanol can be produced from a variety of sources including fossil fuels as well as agricultural products and municipal waste, wood and varied biomass. It can also be made from chemical recycling of carbon dioxide.

Coal liquefaction is a process of converting coal into liquid hydrocarbons: liquid fuels and petrochemicals. This process is often known as "Coal to X" or "Carbon to X", where X can be many different hydrocarbon-based products. However, the most common process chain is "Coal to Liquid Fuels" (CTL).

<span class="mw-page-title-main">Synthetic fuel</span> Fuel from carbon monoxide and hydrogen

Synthetic fuel or synfuel is a liquid fuel, or sometimes gaseous fuel, obtained from syngas, a mixture of carbon monoxide and hydrogen, in which the syngas was derived from gasification of solid feedstocks such as coal or biomass or by reforming of natural gas.

<span class="mw-page-title-main">Biomass to liquid</span>

Biomass to liquid is a multi-step process of producing synthetic hydrocarbon fuels made from biomass via a thermochemical route.

<span class="mw-page-title-main">Gas to liquids</span> Conversion of natural gas to liquid petroleum products

Gas to liquids (GTL) is a refinery process to convert natural gas or other gaseous hydrocarbons into longer-chain hydrocarbons, such as gasoline or diesel fuel. Methane-rich gases are converted into liquid synthetic fuels. Two general strategies exist: (i) direct partial combustion of methane to methanol and (ii) Fischer–Tropsch-like processes that convert carbon monoxide and hydrogen into hydrocarbons. Strategy ii is followed by diverse methods to convert the hydrogen-carbon monoxide mixtures to liquids. Direct partial combustion has been demonstrated in nature but not replicated commercially. Technologies reliant on partial combustion have been commercialized mainly in regions where natural gas is inexpensive.

<span class="mw-page-title-main">Alcohol fuel</span>

Various alcohols are used as fuel for internal combustion engines. The first four aliphatic alcohols are of interest as fuels because they can be synthesized chemically or biologically, and they have characteristics which allow them to be used in internal combustion engines. The general chemical formula for alcohol fuel is CnH2n+1OH.

Renewable Fuels are fuels produced from renewable resources. Examples include: biofuels, Hydrogen fuel, and fully synthetic fuel produced from ambient carbon dioxide and water. This is in contrast to non-renewable fuels such as natural gas, LPG (propane), petroleum and other fossil fuels and nuclear energy. Renewable fuels can include fuels that are synthesized from renewable energy sources, such as wind and solar. Renewable fuels have gained in popularity due to their sustainability, low contributions to the carbon cycle, and in some cases lower amounts of greenhouse gases. The geo-political ramifications of these fuels are also of interest, particularly to industrialized economies which desire independence from Middle Eastern oil.

Second-generation biofuels, also known as advanced biofuels, are fuels that can be manufactured from various types of non-food biomass. Biomass in this context means plant materials and animal waste used especially as a source of fuel.

<span class="mw-page-title-main">Electrofuel</span> Carbon-neutral drop-in replacement fuel

Electrofuels, also known as e-fuels, a class of synthetic fuels, are a type of drop-in replacement fuel. They are manufactured using captured carbon dioxide or carbon monoxide, together with hydrogen obtained from water split by sustainable electricity sources such as wind, solar and nuclear power.

Carbon-neutral fuel is fuel which produces no net-greenhouse gas emissions or carbon footprint. In practice, this usually means fuels that are made using carbon dioxide (CO2) as a feedstock. Proposed carbon-neutral fuels can broadly be grouped into synthetic fuels, which are made by chemically hydrogenating carbon dioxide, and biofuels, which are produced using natural CO2-consuming processes like photosynthesis.

E-diesel is a synthetic diesel fuel created by Audi for use in automobiles. Currently, e-diesel is created by an Audi research facility in partnership with a company named Sunfire. The fuel is created from carbon dioxide, water, and electricity with a process powered by renewable energy sources to create a liquid energy carrier called blue crude which is then refined to generate e-diesel. E-diesel is considered to be a carbon-neutral fuel as it does not extract new carbon and the energy sources to drive the process are from carbon-neutral sources. As of April 2015, an Audi A8 driven by Federal Minister of Education and Research in Germany is using the e-diesel fuel.

<span class="mw-page-title-main">Carbon capture and utilization</span>

Carbon capture and utilization (CCU) is the process of capturing carbon dioxide (CO2) from industrial processes and transporting it via pipelines to where one intends to use it in industrial processes.

References

  1. "ETL-Technology". CRI - Carbon Recycling International. Archived from the original on October 26, 2018. Retrieved October 25, 2018.
  2. US 8198338,"Process for producing liquid fuel from carbon dioxide and water",issued 2012-06-12 2007-03-20
  3. "Vulcanol". CRI - Carbon Recycling International. Retrieved October 25, 2018.
  4. "Framleiðsla hafin á nýju vistvænu eldsneyti". Morgunblaðið. Retrieved July 24, 2012.
  5. "About Us". Carbon Recycling International. Archived from the original on September 29, 2013. Retrieved 11 July 2012.
  6. Matthew Knight (July 13, 2012). "Electric car concept drives progress with extended 500-mile range". CNN. Retrieved July 24, 2012.
  7. "First Commercial Plant". Carbon Recycling International. Archived from the original on July 3, 2013. Retrieved 11 July 2012.
  8. "MefCO₂". www.mefco2.eu. Retrieved December 5, 2019.
  9. "FReSMe". www.fresme.eu. Retrieved December 5, 2019.
  10. "Products". Carbon Recycling International. Archived from the original on July 29, 2013. Retrieved July 13, 2012.
  11. "Eldsneyti úr útblæstri". RÚV. February 27, 2012. Retrieved July 24, 2012.
  12. "Methanol car fleet test yields positive results". CRI - Carbon Recycling International. Retrieved October 25, 2018.
  13. "ETL-Technology". CRI - Carbon Recycling International. Archived from the original on October 26, 2018. Retrieved October 25, 2018.
  14. Ingham, Alan (October 1, 2017). "Reducing the Carbon Intensity of Methanol for Use as a Transport Fuel". Johnson Matthey Technology Review. 61 (4): 297–307. doi: 10.1595/205651317x696216 . ISSN   2056-5135.
  15. "First Commercial Plant". Carbon Recycling International. Archived from the original on July 3, 2013. Retrieved 11 July 2012.
  16. Paul Fontaine (February 28, 2012). "Carbon Recycling In Effect Near Blue Lagoon". The Reykjavík Grapevine. Retrieved July 24, 2012.
  17. "Methanol Fuels". methanolfuels.org. Retrieved October 25, 2018.
  18. "Commercial Scale Plants". CRI - Carbon Recycling International. Archived from the original on October 26, 2018. Retrieved October 25, 2018.