Carbon Recycling International

Last updated

Carbon Recycling International Inc.
Company type Private
Industry Renewable fuels
Founded2006 (2006)
Headquarters Reykjavík, Iceland
Key people
Lotte Rosenberg CEO
Bjork Kristjansdottir COO
Omar Sigurbjornsson
(Sales and Marketing)
ProductsRenewable methanol
Website Carbonrecycling.com

Carbon Recycling International (CRI) is an Icelandic limited liability company which has developed a technology designed to produce renewable methanol, also known as e-methanol, from carbon dioxide and hydrogen, using water electrolysis or, alternatively, hydrogen captured from industrial waste gases. The technology is trademarked by CRI as Emissions-to-Liquids (ETL) [1] [2] and the renewable methanol produced by CRI is trademarked as Vulcanol. [3] In 2011 CRI became the first company to produce and sell liquid renewable transport fuel produced using only carbon dioxide, water and electricity from renewable sources. [4]

Contents

History

CRI, incorporated in 2006, was founded by Fridrik Jonsson, Art Shulenberger, Oddur Ingolfsson, and KC Tran. [5] In addition to Icelandic individuals and funds, investors include Canadian multinational methanol supplier and distributor Methanex and Chinese multinational automotive manufacturing company Geely.

CRI's first commercial scale plant, the George Olah Plant (named after George Andrew Olah, [6] the 1994 Nobel Prize Laureate in chemistry), was completed in 2011. [7] CRI is currently working on several new projects in parallel, including in an EU Horizon 2020 research programme funded MefCO2 consortium [8] to build a renewable methanol demonstration plant in Germany and in the FreSME consortium [9] to build a renewable methanol demonstration plant in Sweden.

Renewable methanol

Renewable methanol can be used as a fuel, chemical feedstock (including various types of fuels) or blended with gasoline. Fuels which are produced partially or fully from methanol include biodiesel, dimethyl ether or oxymethylene ether, as well as synthetic gasoline from the Mobil methanol-to-gasoline (MTG) process. Gasoline blends range from 3% methanol, which is allowed in European standard gasoline, to 56% methanol, a blend for flexible fuel vehicles [10] which has the same energy density and oxygen content as E85 gasoline. CRI has run fleet tests with a range of lower blends and higher blend options in cars from different manufacturers, including 100% methanol in special flexible fuel vehicles manufactured by Geely. [11] [12] Renewable methanol is compatible with internal combustion engines as well as methanol fuel cells. Internal combustion engines that operate on 100% methanol are in production both for light vehicles, trucks and ships. Methanol fuel cells of varying energy density are available from multiple manufacturers in North America, Europe and Asia.

Production

CRI's first CSP, the GO Plant Carbon Recycling International GO Plant.jpg
CRI's first CSP, the GO Plant

Production of renewable methanol does not depend on agricultural resources, as hydrogen and carbon dioxide are the primary inputs. CRI's emissions-to-liquids production process is based on three main modules, carbon dioxide purification, hydrogen generation and the methanol synthesis and purification system. [13] The catalytic conversion process from hydrogen and carbon dioxide occurs in one step, while production of methanol from fossil fuels, such as natural gas or coal, involves several reforming steps to obtain syngas followed by the catalytic step. [14] Unlike some other power-to-fuel technologies, which use carbon dioxide and hydrogen as inputs, CRI's emissions-to-liquids process also does not require the carbon dioxide to be 'shifted' prior to the synthesis step.

Plants

George Olah plant

The George Olah Plant, or the GO Plant, has a name-plate capacity of 5 million liters per year. [15] It is located close to the Blue Lagoon spa facility and HS Orka's Svartsengi power station. The plant can capture and utilize around 10% of the carbon dioxide emitted by the Svartsengi power station. [16]

Shunli

CRI commissioned the world's largest CO₂-to-methanol plant in October 2022. The plant is based in Anyang city, Henan Province, China and utilizes carbon dioxide recovered from existing lime production emissions and hydrogen recovered from a nearby coking facility. The plant has an annual production capacity of 110,000 tons of low-carbon intensity methanol, recycling approximately 160,000 tons of CO2 per year. [17]

The methanol has been used to replace diesel fuel in heavy-duty trucks, produced by Geely Auto, and to light the flame of the Asian Games in Hangzhou in 2023. The USD 90 million project created 80 jobs and was celebrated as milestone in the development of Chinese industry towards circular value chains. [18]

Sailboat

The Sailboat CO₂-to-methanol plant is located in the Shenghong Petrochemical Industrial Park in Lianyungang, Jiangsu province, China. The plant recycles approximately 150,000 tons of carbon dioxide and 20,000 tons of hydrogen from waste streams at the nearby petrochemical complex, producing 100,000 tons of low-carbon methanol annually. This methanol produced at this facility is used to manufacture polymers and plastics, including EVA coatings for solar panels and plexiglass. The plant began operation in September 2023. [19] [20]

EU Horizon 2020 Research and Innovation Program

MefCO2

Funded under the EU Horizon 2020 Framework Program, MefCO2 was a technology development project that ran from 2014-2019. The project demonstrated the application of CRI’s ETL technology, which produced methanol from CO2 emissions from a thermal power plant and electrolytic hydrogen generated from surplus renewable energy. [21]

The CO2-to-methanol production unit was integrated into the RWE Niederaussem thermal power plant and began production in early May 2019. The system successfully demonstrated the technology’s ability to operate with intermittent and fluctuating renewable energy supply as well as heterogeneous CO2 sources. The plant delivered 1 ton of methanol per day to a wastewater treatment facility upon the project’s completion. [21]

CirclEnergy

The CirclEnergy project, funded by the EU Horizon 2020 program, aimed to address the challenges of integrating renewable power into the European power network such as the oversupply of energy caused by the intermittent nature of solar and wind power.The project looked at using CRI’s ETL technology can convert surplus power from intermittent renewable energy sources into renewable methanol. The project demonstrated renewable methanol use as an effective storage and carrier of renewable energy. [22]

FReSMe

CRI was awarded an 11 million EUR grant to implement CRI’s ETL technology in the Swerea MEFOS facility in Luleå, Sweden. The project ran from 2019-2020 and adapted the system module used in the previous MefCO2 project to convert residual blast furnace gases from steel manufacturing into methanol. [23]

This project demonstrated the versatility of CRI’s ETL technology by utilizing CO₂ and hydrogen recovered from diverse waste streams. The low-carbon methanol, produced periodically in 2020, was utilized by Stena, a Swedish ferry operator and consortium partner that operated the world's first methanol-fueled passenger ferry, the Stena Germanica. [23]

Gamer

The GAMER project received funding of 3 million EUR with the aim of advancing high-temperature electrolysis technology. CRI was part of the consortium that worked on developing a new type of high-efficiency electrolyser with a novel solid electrolyte.

The project aimed to overcome challenges with electrolysis technologies including instability and thermal stress. The Proton Ceramic Electrolyser was designed to be thermally coupled with waste heat sources in industrial plants, enabling the system to achieve significantly higher combined electrical and heat efficiency. The project was successfully completed in 2022. [24]

Legislation

The European Union's renewable energy directive recognizes renewable methanol as a renewable transport fuel from non-biological sources, which means that it can be used as an advanced renewable transport fuel under the EU's renewable fuel blending mandates.

Impact

Carbon dioxide is a major cause of global warming. By removing carbon dioxide from industrial emissions and increasing the availability of energy derived from electricity or low-carbon intensity hydrogen, CRI's process helps to mitigate climate change. Renewable methanol burns cleanly as a fuel and substituting renewable methanol for gasoline and diesel fuels reduces urban emissions of particulate matter, sulphur oxides (SOx) and nitrous oxides (NOx). [25]

CRI's process can also be used to store energy in the form of methanol, especially in cases where the energy source is intermittent. For example, wind and solar power are intermittently available. By storing energy from these sources in liquid chemical form, the generation of electricity and utilization of electricity does not have to be linked in time and space.. Methanol is also a good energy carrier. As a liquid fuel it is easier and cheaper to store and transport than gaseous fuels such as hydrogen or methane.

Future projects

CRI plans to implement standardized CSPs (commercial scale plants), each with a capacity of at least 50,000 tons of methanol production per year. [26]

See also

Related Research Articles

<span class="mw-page-title-main">Methanol</span> CH3OH; simplest possible alcohol

Methanol is an organic chemical compound and the simplest aliphatic alcohol, with the chemical formula CH3OH. It is a light, volatile, colorless and flammable liquid with a distinctive alcoholic odor similar to that of ethanol, but is more acutely toxic than the latter. Methanol acquired the name wood alcohol because it was once produced chiefly by the destructive distillation of wood. Today, methanol is mainly produced industrially by hydrogenation of carbon monoxide.

<span class="mw-page-title-main">Steelmaking</span> Process for producing steel from iron ore and scrap

Steelmaking is the process of producing steel from iron ore and/or scrap. In steelmaking, impurities such as nitrogen, silicon, phosphorus, sulfur, and excess carbon are removed from the sourced iron, and alloying elements such as manganese, nickel, chromium, carbon, and vanadium are added to produce different grades of steel.

Syngas, or synthesis gas, is a mixture of hydrogen and carbon monoxide, in various ratios. The gas often contains some carbon dioxide and methane. It is principally used for producing ammonia or methanol. Syngas is combustible and can be used as a fuel. Historically, it has been used as a replacement for gasoline, when gasoline supply has been limited; for example, wood gas was used to power cars in Europe during WWII.

<span class="mw-page-title-main">Gasification</span> Form of energy conversion

Gasification is a process that converts biomass- or fossil fuel-based carbonaceous materials into gases, including as the largest fractions: nitrogen (N2), carbon monoxide (CO), hydrogen (H2), and carbon dioxide (CO2). This is achieved by reacting the feedstock material at high temperatures (typically >700 °C), without combustion, via controlling the amount of oxygen and/or steam present in the reaction. The resulting gas mixture is called syngas (from synthesis gas) or producer gas and is itself a fuel due to the flammability of the H2 and CO of which the gas is largely composed. Power can be derived from the subsequent combustion of the resultant gas, and is considered to be a source of renewable energy if the gasified compounds were obtained from biomass feedstock.

<span class="mw-page-title-main">Alternative fuel</span> Fuels from sources other than fossil fuels

Alternative fuels, also known as non-conventional and advanced fuels, are fuels derived from sources other than petroleum. Alternative fuels include gaseous fossil fuels like propane, natural gas, methane, and ammonia; biofuels like biodiesel, bioalcohol, and refuse-derived fuel; and other renewable fuels like hydrogen and electricity.

<span class="mw-page-title-main">Liquid fuel</span> Liquids that can be used to create energy

Liquid fuels are combustible or energy-generating molecules that can be harnessed to create mechanical energy, usually producing kinetic energy; they also must take the shape of their container. It is the fumes of liquid fuels that are flammable instead of the fluid. Most liquid fuels in widespread use are derived from fossil fuels; however, there are several types, such as hydrogen fuel, ethanol, and biodiesel, which are also categorized as a liquid fuel. Many liquid fuels play a primary role in transportation and the economy.

Methanol fuel is an alternative biofuel for internal combustion and other engines, either in combination with gasoline or independently. Methanol (CH3OH) is less expensive to sustainably produce than ethanol fuel, although it is more toxic than ethanol and has a lower energy density than gasoline. Methanol is safer for the environment than gasoline, is an anti-freeze agent, prevents dirt and grime buildup within the engine, has a higher ignition temperature, and produces horsepower equivalent to that of super high-octane gasoline. It can readily be used in most modern engines. To prevent vapor lock due to being a simple, pure fuel, a small percentage of other fuel or certain additives can be included. Methanol may be made from fossil fuels or renewable resources, in particular natural gas and coal, or biomass respectively. In the case of the latter, it can be synthesized from CO2 (carbon dioxide) and hydrogen. The vast majority of methanol produced globally is currently made with gas and coal. However, projects, investments, and the production of green-methanol has risen steadily into 2023. Methanol fuel is currently used by racing cars in many countries and has seen increasing adoption by the maritime industry.

<span class="mw-page-title-main">Methanol economy</span> Economic theory

The methanol economy is a suggested future economy in which methanol and dimethyl ether replace fossil fuels as a means of energy storage, ground transportation fuel, and raw material for synthetic hydrocarbons and their products. It offers an alternative to the proposed hydrogen economy or ethanol economy, although these concepts are not exclusive. Methanol can be produced from a variety of sources including fossil fuels as well as agricultural products and municipal waste, wood and varied biomass. It can also be made from chemical recycling of carbon dioxide.

Coal liquefaction is a process of converting coal into liquid hydrocarbons: liquid fuels and petrochemicals. This process is often known as "Coal to X" or "Carbon to X", where X can be many different hydrocarbon-based products. However, the most common process chain is "Coal to Liquid Fuels" (CTL).

<span class="mw-page-title-main">Synthetic fuel</span> Fuel from carbon monoxide and hydrogen

Synthetic fuel or synfuel is a liquid fuel, or sometimes gaseous fuel, obtained from syngas, a mixture of carbon monoxide and hydrogen, in which the syngas was derived from gasification of solid feedstocks such as coal or biomass or by reforming of natural gas.

<span class="mw-page-title-main">Biomass to liquid</span>

Biomass to liquid is a multi-step process of producing synthetic hydrocarbon fuels made from biomass via a thermochemical route.

<span class="mw-page-title-main">Waste-to-energy</span> Process of generating energy from the primary treatment of waste

Waste-to-energy (WtE) or energy-from-waste (EfW) is the process of generating energy in the form of electricity and/or heat from the primary treatment of waste, or the processing of waste into a fuel source. WtE is a form of energy recovery. Most WtE processes generate electricity and/or heat directly through combustion, or produce a combustible fuel commodity, such as methane, methanol, ethanol or synthetic fuels, often derived from the product syngas.

Renewable fuels are fuels produced from renewable resources. Examples include: biofuels, Hydrogen fuel, and fully synthetic fuel produced from ambient carbon dioxide and water. This is in contrast to non-renewable fuels such as natural gas, LPG (propane), petroleum and other fossil fuels and nuclear energy. Renewable fuels can include fuels that are synthesized from renewable energy sources, such as wind and solar. Renewable fuels have gained in popularity due to their sustainability, low contributions to the carbon cycle, and in some cases lower amounts of greenhouse gases. The geo-political ramifications of these fuels are also of interest, particularly to industrialized economies which desire independence from Middle Eastern oil.

Second-generation biofuels, also known as advanced biofuels, are fuels that can be manufactured from various types of non-food biomass. Biomass in this context means plant materials and animal waste used especially as a source of fuel.

<span class="mw-page-title-main">Reformed methanol fuel cell</span> Fuel Cell Type

Reformed Methanol Fuel Cell (RMFC) or Indirect Methanol Fuel Cell (IMFC) systems are a subcategory of proton-exchange fuel cells where, the fuel, methanol (CH3OH), is reformed, before being fed into the fuel cell.

<span class="mw-page-title-main">Electrofuel</span> Carbon-neutral drop-in replacement fuel

Electrofuels, also known as e-fuels, are a marketing term for a class of synthetic fuels, which function as drop-in replacement fuels for internal combustion engines. They are manufactured using captured carbon dioxide or carbon monoxide, together with hydrogen obtained from water split. Electrolysis is possible with both traditional fossil fuel energy sources, as well as low-carbon electricity sources such as wind, solar and nuclear power.

Carbon-neutral fuel is fuel which produces no net-greenhouse gas emissions or carbon footprint. In practice, this usually means fuels that are made using carbon dioxide (CO2) as a feedstock. Proposed carbon-neutral fuels can broadly be grouped into synthetic fuels, which are made by chemically hydrogenating carbon dioxide, and biofuels, which are produced using natural CO2-consuming processes like photosynthesis.

Power-to-gas is a technology that uses electric power to produce a gaseous fuel. When using surplus power from wind generation, the concept is sometimes called windgas.

E-diesel is a synthetic diesel fuel for use in automobiles. Currently, e-diesel is created at two sites: by an Audi research facility Germany in partnership with a company named Sunfire, and in Texas. The fuel is created from carbon dioxide, water, and electricity with a process powered by renewable energy sources to create a liquid energy carrier called blue crude which is then refined to generate e-diesel. E-diesel is considered to be a carbon-neutral fuel as it does not extract new carbon and the energy sources to drive the process are from carbon-neutral sources.

<span class="mw-page-title-main">Direct air capture</span> Method of carbon capture from carbon dioxide in air

Direct air capture (DAC) is the use of chemical or physical processes to extract carbon dioxide directly from the ambient air. If the extracted CO2 is then sequestered in safe long-term storage, the overall process will achieve carbon dioxide removal and be a "negative emissions technology" (NET).

References

  1. "ETL-Technology". CRI - Carbon Recycling International. Archived from the original on October 26, 2018. Retrieved October 25, 2018.
  2. US 8198338,"Process for producing liquid fuel from carbon dioxide and water",issued 2012-06-12 2007-03-20
  3. "Vulcanol". CRI - Carbon Recycling International. Retrieved October 25, 2018.
  4. "Framleiðsla hafin á nýju vistvænu eldsneyti". Morgunblaðið. Retrieved July 24, 2012.
  5. "About Us". Carbon Recycling International. Archived from the original on September 29, 2013. Retrieved 11 July 2012.
  6. Matthew Knight (July 13, 2012). "Electric car concept drives progress with extended 500-mile range". CNN. Retrieved July 24, 2012.
  7. "First Commercial Plant". Carbon Recycling International. Archived from the original on July 3, 2013. Retrieved 11 July 2012.
  8. "MefCO₂". www.mefco2.eu. Retrieved December 5, 2019.
  9. "FReSMe". www.fresme.eu. Retrieved December 5, 2019.
  10. "Products". Carbon Recycling International. Archived from the original on July 29, 2013. Retrieved July 13, 2012.
  11. "Eldsneyti úr útblæstri". RÚV. February 27, 2012. Retrieved July 24, 2012.
  12. "Methanol car fleet test yields positive results". CRI - Carbon Recycling International. Retrieved October 25, 2018.
  13. "ETL-Technology". CRI - Carbon Recycling International. Archived from the original on October 26, 2018. Retrieved October 25, 2018.
  14. Ingham, Alan (October 1, 2017). "Reducing the Carbon Intensity of Methanol for Use as a Transport Fuel". Johnson Matthey Technology Review. 61 (4): 297–307. doi: 10.1595/205651317x696216 . ISSN   2056-5135.
  15. "First Commercial Plant". Carbon Recycling International. Archived from the original on July 3, 2013. Retrieved 11 July 2012.
  16. Paul Fontaine (February 28, 2012). "Carbon Recycling In Effect Near Blue Lagoon". The Reykjavík Grapevine. Retrieved July 24, 2012.
  17. "WORLD'S LARGEST CO₂-TO-METHANOL PLANT STARTS PRODUCTION". CRI - Carbon Recycling International. Retrieved July 18, 2024.
  18. "The Shunli CO2-to-Methanol Production Plant". CRI - Carbon Recycling International. Retrieved July 18, 2024.
  19. "CRI AND JIANGSU SAILBOAT START UP WORLD'S MOST EFFICIENT CO₂-TO-METHANOL PLANT". CRI - Carbon Recycling International. Retrieved July 18, 2024.
  20. "Jiangsu Sailboat - Chemical Products from Recycled CO2". CRI - Carbon Recycling International. Retrieved July 18, 2024.
  21. 1 2 "MefCO2: CO2 to Methanol Production in Germany". CRI - Carbon Recycling International. Retrieved July 18, 2024.
  22. "CirclEnergy: Promote a more Sustainable, Circular Economy". CRI - Carbon Recycling International. Retrieved July 18, 2024.
  23. 1 2 "FReSMe: Implementing CRI's Emissions-to-Liquids Technology". CRI - Carbon Recycling International. Retrieved July 18, 2024.
  24. "GAMER: Conquering Fossil-Based Hydrogen". CRI - Carbon Recycling International. Retrieved July 18, 2024.
  25. "Methanol Fuels". methanolfuels.org. Retrieved October 25, 2018.
  26. "Commercial Scale Plants". CRI - Carbon Recycling International. Archived from the original on October 26, 2018. Retrieved October 25, 2018.