A Carnot battery is a type of energy storage system that stores electricity in thermal energy storage. During the charging process, electricity is converted into heat and kept in heat storage. During the discharging process, the stored heat is converted back into electricity. [1] [2]
Fritz Marguerre patented the concept of this technology 100 years ago, [3] but its development was recently revitalized, given the increased use of renewable energies and the need to increase the total recovered energy delivered from such sources. In this context, Andre Thess coined the term "Carnot battery" in 2018, prior to the first International Workshop on Carnot Batteries. [4]
The term "Carnot battery" is derived from Carnot's theorem, which describes the maximum efficiency of conversion of heat energy into mechanical energy. The word "battery" indicates that the purpose of this technology is to store electricity. The discharge efficiency of Carnot batteries is limited by the Carnot efficiency. The concept of Carnot batteries covers technologies such as pumped thermal energy storage and liquid air energy storage. [5] [6]
In the transition to low-carbon energy systems, the penetration of variable renewable energy in electrical energy systems increases, and this also increases the need for energy storage. Currently, most of the new installed energy storage capacity comes from electrochemical batteries, such as lithium-ion batteries. This type of battery is suitable for short-term storage but may not be economical for longer durations due to its high energy capacity costs. [7] Thermal energy storage can store energy in inexpensive materials, such as water, rocks, and salts. Therefore, the cost for large-scale systems (e.g. gigawatt hours) can be lower than the cost of electrochemical batteries. [8]
The German Aerospace Center (DLR) and University of Stuttgart have been working on the concept of Carnot batteries that store electricity in high-temperature heat storage since 2014. [8] In 2018, the name "Carnot battery" was used at the Hannover Messe, [9] one of the world's largest trade fairs, by DLR. [8]
A Carnot battery system can be divided into three parts: Power to Thermal (P2T), Thermal Energy Storage (TES), and Thermal to Power (T2P).
Electricity can be converted into heat through the use of various technologies. [1]
According to the mechanism to store heat, thermal energy storage can be divided into three types: sensible heat storage, latent heat storage, and thermochemical storage. The storage materials that have been used for Carnot batteries are:
Heat can be converted into power through thermodynamic cycles, such as the Rankine cycle or Brayton cycle. Some technologies use the property of semiconductor materials to convert heat into electricity, and those are not considered a Carnot battery because there are no thermodynamic cycles involved in the conversion process, such as thermoelectric materials and the "Sun in a box". [13] The typical technologies are:
The Carnot battery is known by several other names such as Pumped Thermal Electricity Storage (PTES) or Pumped Heat Electricity Storage (PHES). [15] This relatively new technology has become one of the most promising large-scale energy storage technologies.
The main advantages of the Carnot battery are: [16]
The major drawback of this technology is: [17]
Carnot batteries can be used as grid energy storage to store excess power from variable renewable energy sources and to produce electricity when needed.
Some Carnot battery systems can use the stored heat or cold for other applications, such as district heating and cooling for data centers.
Carnot batteries have been proposed as a solution to convert existing coal-fired power plants into a fossil fuel-free generation system by replacing the coal fueled boiler. [19] [20] The existing facilities in power plants such as power generation systems and transmission systems can be used.
Although the term Carnot battery is new, many existing technologies can be classified as Carnot batteries. [7]
A heat engine is a system that converts heat to usable energy, particularly mechanical energy, which can then be used to do mechanical work. While originally conceived in the context of mechanical energy, the concept of the heat engine has been applied to various other kinds of energy, particularly electrical, since at least the late 19th century. The heat engine does this by bringing a working substance from a higher state temperature to a lower state temperature. A heat source generates thermal energy that brings the working substance to the higher temperature state. The working substance generates work in the working body of the engine while transferring heat to the colder sink until it reaches a lower temperature state. During this process some of the thermal energy is converted into work by exploiting the properties of the working substance. The working substance can be any system with a non-zero heat capacity, but it usually is a gas or liquid. During this process, some heat is normally lost to the surroundings and is not converted to work. Also, some energy is unusable because of friction and drag.
Energy storage is the capture of energy produced at one time for use at a later time to reduce imbalances between energy demand and energy production. A device that stores energy is generally called an accumulator or battery. Energy comes in multiple forms including radiation, chemical, gravitational potential, electrical potential, electricity, elevated temperature, latent heat and kinetic. Energy storage involves converting energy from forms that are difficult to store to more conveniently or economically storable forms.
Solar energy is the radiant energy from the Sun's light and heat, which can be harnessed using a range of technologies such as solar electricity, solar thermal energy and solar architecture. It is an essential source of renewable energy, and its technologies are broadly characterized as either passive solar or active solar depending on how they capture and distribute solar energy or convert it into solar power. Active solar techniques include the use of photovoltaic systems, concentrated solar power, and solar water heating to harness the energy. Passive solar techniques include designing a building for better daylighting, selecting materials with favorable thermal mass or light-dispersing properties, and organize spaces that naturally circulate air.
A compressed-air car is a compressed-air vehicle powered by pressure vessels filled with compressed air. It is propelled by the release and expansion of the air within a motor adapted to compressed air. The car might be powered solely by air, or combined with other fuels such as gasoline, diesel, or an electric plant with regenerative braking.
A combined cycle power plant is an assembly of heat engines that work in tandem from the same source of heat, converting it into mechanical energy. On land, when used to make electricity the most common type is called a combined cycle gas turbine (CCGT) plant, which is a kind of gas-fired power plant. The same principle is also used for marine propulsion, where it is called a combined gas and steam (COGAS) plant. Combining two or more thermodynamic cycles improves overall efficiency, which reduces fuel costs.
The Rankine cycle is an idealized thermodynamic cycle describing the process by which certain heat engines, such as steam turbines or reciprocating steam engines, allow mechanical work to be extracted from a fluid as it moves between a heat source and heat sink. The Rankine cycle is named after William John Macquorn Rankine, a Scottish polymath professor at Glasgow University.
Grid energy storage is a collection of methods used for energy storage on a large scale within an electrical power grid. Electrical energy is stored during times when electricity is plentiful and inexpensive or when demand is low, and later returned to the grid when demand is high, and electricity prices tend to be higher.
Thermal energy storage (TES) is the storage of thermal energy for later reuse. Employing widely different technologies, it allows surplus thermal energy to be stored for hours, days, or months. Scale both of storage and use vary from small to large – from individual processes to district, town, or region. Usage examples are the balancing of energy demand between daytime and nighttime, storing summer heat for winter heating, or winter cold for summer cooling. Storage media include water or ice-slush tanks, masses of native earth or bedrock accessed with heat exchangers by means of boreholes, deep aquifers contained between impermeable strata; shallow, lined pits filled with gravel and water and insulated at the top, as well as eutectic solutions and phase-change materials.
Microgeneration is the small-scale production of heat or electric power from a "low carbon source," as an alternative or supplement to traditional centralized grid-connected power.
Renewable heat is an application of renewable energy referring to the generation of heat from renewable sources; for example, feeding radiators with water warmed by focused solar radiation rather than by a fossil fuel boiler. Renewable heat technologies include renewable biofuels, solar heating, geothermal heating, heat pumps and heat exchangers. Insulation is almost always an important factor in how renewable heating is implemented.
Solar air conditioning, or "solar-powered air conditioning", refers to any air conditioning (cooling) system that uses solar power.
A gas-fired power plant, sometimes referred to as gas-fired power station, natural gas power plant, or methane gas power plant, is a thermal power station that burns natural gas to generate electricity. Gas-fired power plants generate almost a quarter of world electricity and are significant sources of greenhouse gas emissions. However, they can provide seasonal, dispatchable energy generation to compensate for variable renewable energy deficits, where hydropower or interconnectors are not available. In the early 2020s batteries became competitive with gas peaker plants.
In thermal engineering, the organic Rankine cycle (ORC) is a type of thermodynamic cycle. It is a variation of the Rankine cycle named for its use of an organic, high-molecular-mass fluid whose vaporization temperature is lower than that of water. The fluid allows heat recovery from lower-temperature sources such as biomass combustion, industrial waste heat, geothermal heat, solar ponds etc. The low-temperature heat is converted into useful work, that can itself be converted into electricity.
Concentrated solar power systems generate solar power by using mirrors or lenses to concentrate a large area of sunlight into a receiver. Electricity is generated when the concentrated light is converted to heat, which drives a heat engine connected to an electrical power generator or powers a thermochemical reaction.
A waste heat recovery unit (WHRU) is an energy recovery heat exchanger that transfers heat from process outputs at high temperature to another part of the process for some purpose, usually increased efficiency. The WHRU is a tool involved in cogeneration. Waste heat may be extracted from sources such as hot flue gases from a diesel generator, steam from cooling towers, or even waste water from cooling processes such as in steel cooling.
Photovoltaic thermal collectors, typically abbreviated as PVT collectors and also known as hybrid solar collectors, photovoltaic thermal solar collectors, PV/T collectors or solar cogeneration systems, are power generation technologies that convert solar radiation into usable thermal and electrical energy. PVT collectors combine photovoltaic solar cells, which convert sunlight into electricity, with a solar thermal collector, which transfers the otherwise unused waste heat from the PV module to a heat transfer fluid. By combining electricity and heat generation within the same component, these technologies can reach a higher overall efficiency than solar photovoltaic (PV) or solar thermal (T) alone.
The following outline is provided as an overview of and topical guide to solar energy:
Renewable thermal energy is the technology of gathering thermal energy from a renewable energy source for immediate use or for storage in a thermal battery for later use.
Power-to-X are electricity conversion, energy storage, and reconversion pathways from surplus renewable energy. Power-to-X conversion technologies allow for the decoupling of power from the electricity sector for use in other sectors, possibly using power that has been provided by additional investments in generation. The term is widely used in Germany and may have originated there.
The Lamm-Honigmann process is a storage and heat to power conversion process that consists of using the effect of vapor pressure depression of a working fluid mixture compared to a pure working fluid of that mixture. This process is named after their independent inventors Emile Lamm and Moritz Honigmann. Both inventors envisioned and realized the same process principle for usage as energy storage in so-called Fireless locomotive but with different working fluid pairs: Emile Lamm used ammonia and water, Moritz Honigmann used water and caustic soda.