Gugiaite | |
---|---|
General | |
Category | Sorosilicate |
Formula (repeating unit) | Ca2[BeSi2O7] |
IMA symbol | Gug [1] |
Strunz classification | 9.BB.10 |
Dana classification | 55.04.02.06 |
Crystal system | Tetragonal |
Crystal class | Scalenohedral (42m) H-M symbol: (4 2m) |
Space group | P421m |
Unit cell | a = 7.43, c = 5.024 [Å]; Z = 2 |
Identification | |
Color | Colorless |
Cleavage | Perfect on {010}, distinct {001}, indistinct on {110} |
Fracture | Uneven – Flat surfaces (not cleavage) fractured in an uneven pattern |
Mohs scale hardness | 5 |
Luster | Vitreous, glassy |
Streak | White |
Diaphaneity | Transparent |
Density | 3.03 |
Optical properties | uniaxial (+) |
Refractive index | nω = 1.664 nε = 1.672 |
Birefringence | δ = 0.008 |
Other characteristics | strongly piezoelectric |
References | [2] [3] [4] |
Gugiaite is a melilite mineral, named for the Chinese village of Gugia where it was first discovered. Its chemical formula is Ca 2 Be Si 2 O 7. It occurs mostly in skarns with melanite adjacent to an alkali syenite and has no economic value. Its crystals are small tetragonal tablets with vitreous luster and perfect cleavage. It is colorless and transparent with a density of three. The mineral belongs to space group P421m and is strongly piezoelectric.
Shortly after the discovery of gugiaite, it was noted that a new name was unnecessary as it could have been considered an end member of meliphanite, (Ca,Na)2Be(Si,Al)2(O,F)2 differing mainly in containing much less sodium and fluorine. [5] Recent data have confirmed that gugiaite differs from meliphanite optically and structurally. [6] Gugiaite is a melilite and is distinctly different from other beryllium minerals such as meliphanite and leucophanite. [6] Gugiaite is named for its locality near the village of Gugia, China. [7] Incongruent information exists regarding Gugia; consequently the actual location of this village within China is unclear (de Fourestier 2005). Gujia is most often referenced as being in either Jiangsu Province or Liaoning Province. [8] [9]
Gugiaite has an ideal chemical formula of Ca2BeSi2O7 and is a member of the melilite and sorosilicate (Si2O7) groups. [7] It is chemically similar to jeffreyite (Ca,Na)2[(Be,Al)Si2(O,OH)7], meliphanite (Ca,Na)2[Be(Si,Al)2O6(O,OH,F)], and leucophanite (Ca,Na)2[Be(Si,Al)2O6(O,F)] in that they all contain essential calcium, beryllium, and silicon. [10] Two chemical analyses gave similar results and one is as follows: SiO2 44.90, Al2O3 2.17, Fe2O3 0.11, MnO 0.07, MgO 0.38, CaO 40.09, BeO 9.49, Na2O 0.72, K2O} 0.20, H2O− 0.36, H2O+ 0.90, F 0.25, Cl 0.18, P2O5 0.08, TiO2 trace, -O=(F,Cl)2 0.15, sum 99.94, 99.79%. [5] Common impurities are Ti, Zr, Hf, Al, Fe, Mn, Mg, Na, K, F, Cl, and P. [5]
Gugiaite is usually found in skarn in contact with alkaline syenite with melanite, orthoclase, aegirine, titanite, apatite, vesuvianite, and prehnite. [7] It occurs as thin square tablets, to 3 mm, in small cavities in skarn and enclosed in melanite. [7] Skarns are often formed at the contact zone between granite intrusions and carbonate sedimentary rocks through metasomatism. Gugiaite has also been found in a miarolitic cavity in granite. [11] This type of cavity is crystal lined, irregular, and known for being a source of rare minerals, such as beryllium, that are not normally found in abundance in igneous rocks. [12] While initially found in Gugia, China, its localities have expanded to include Piedmont, Italy, Ehime Prefecture, Japan, Eastern Siberian Region, Russia, and most recently Telemark, Norway. [3]
Gugiaite is composed of infinite sheets of tetrahedra with Be-Si-Si linkages and interstitial Ca. [10] As shown in Figure 1, the oxygen atom bonds to a [4]-coordinated high-valence cation, Si, to produce a discontinuous polymerization of tetrahedra linked by interstitial Ca. [10] It is isostructural with akermanite (Ca2MgSi2O7) with Be occupying the Mg site of akermanite. [10] X-ray studies by the Weissenberg method show gugiaite to be tetragonal, space group P421m, (space group Nr. 113), and H-M Symbol 42m. [7] Cell dimensions are: a = b = 7.48(2) Ȧ, c = 5.044(3) Ȧ, V = 277.35 Ȧ, α = β = γ = 90◦, and Z = 2. [7] The axial ratio is a:c = 1:0.67617. [7] Structurally A is Ca2, T1 is BeO4, T2 is SiO4, and X is O7. [8] The three strongest lines of the X-ray powder data for gugiaite are 2.765(10), 1.485(7), and 1.709(7). [7]
The crystal form of gugiaite occurs as thin tetragonal tablets mostly 2–3 mm across and 0.3–0.5 mm thick, shown in Figure 2 below. [5] The cleavages are {010} perfect, {001} distinct, and {110} poor. [7] It is transparent, optically uniaxial (+), and strongly piezoelectric. [7] See Table for additional physical properties.
Gugiaite does not appear to have any political significance or economic value. From a historical perspective, gugiaite was the first beryllium mineral found in skarn systems at contacts between alkaline rocks and limestones. [7] Also, thermodynamic equilibrium studies involving gugiaite have been conducted to determine the distribution of beryllium between gaseous and solid phases as a function of temperature in attempts to deduce the processes that formed the solar system. [13]
Creedite is a calcium aluminium sulfate fluoro hydroxide mineral with formula: Ca3Al2SO4(F,OH)10·2(H2O). Creedite forms colorless to white to purple monoclinic prismatic crystals. It often occurs as acicular radiating sprays of fine prisms. It is translucent to transparent with indices of refraction of nα = 1.461 nβ = 1.478 nγ = 1.485. It has a Mohs hardness of 3.5 to 4 and a specific gravity of 2.7.
A mantle is a layer inside a planetary body bounded below by a core and above by a crust. Mantles are made of rock or ices, and are generally the largest and most massive layer of the planetary body. Mantles are characteristic of planetary bodies that have undergone differentiation by density. All terrestrial planets, a number of asteroids, and some planetary moons have mantles.
Silicate minerals are rock-forming minerals made up of silicate groups. They are the largest and most important class of minerals and make up approximately 90 percent of Earth's crust.
Lamproite is an ultrapotassic mantle-derived volcanic or subvolcanic rock. It has low CaO, Al2O3, Na2O, high K2O/Al2O3, a relatively high MgO content and extreme enrichment in incompatible elements.
Clinozoisite is a complex calcium aluminium sorosilicate mineral with formula: Ca2Al3(Si2O7)(SiO4)O(OH). It forms a continuous solid solution series with epidote by substitution of iron(III) in the aluminium (m3 site) and is also called aluminium epidote.
Melilite refers to a mineral of the melilite group. Minerals of the group are solid solutions of several endmembers, the most important of which are gehlenite and åkermanite. A generalized formula for common melilite is (Ca,Na)2(Al,Mg,Fe2+)[(Al,Si)SiO7]. Discovered in 1793 near Rome, it has a yellowish, greenish-brown color. The name derives from the Greek words meli (μέλι) "honey" and lithos (λίθους) "stone".The name refers to a group of minerals (melilite group) with chemically similar composition, nearly always minerals in åkermanite-gehlenite series.
Frank Christopher Hawthorne is an English-born Canadian mineralogist, crystallographer and spectroscopist. He works at the University of Manitoba and is currently distinguished professor emeritus. By combining graph theory, bond-valence theory and the moments approach to the electronic energy density of solids he has developed bond topology as a rigorous approach to understanding the atomic arrangements, chemical compositions and paragenesis of complex oxide and oxysalt minerals.
In inorganic chemistry, mineral hydration is a reaction which adds water to the crystal structure of a mineral, usually creating a new mineral, commonly called a hydrate.
Wadsleyite is an orthorhombic mineral with the formula β-(Mg,Fe)2SiO4. It was first found in nature in the Peace River meteorite from Alberta, Canada. It is formed by a phase transformation from olivine (α-(Mg,Fe)2SiO4) under increasing pressure and eventually transforms into spinel-structured ringwoodite (γ-(Mg,Fe)2SiO4) as pressure increases further. The structure can take up a limited amount of other bivalent cations instead of magnesium, but contrary to the α and γ structures, a β structure with the sum formula Fe2SiO4 is not thermodynamically stable. Its cell parameters are approximately a = 5.7 Å, b = 11.71 Å and c = 8.24 Å.
A melt inclusion is a small parcel or "blobs" of melt(s) that is entrapped by crystals growing in magma and eventually forming igneous rocks. In many respects it is analogous to a fluid inclusion within magmatic hydrothermal systems. Melt inclusions tend to be microscopic in size and can be analyzed for volatile contents that are used to interpret trapping pressures of the melt at depth.
Eudialyte group is a group of complex trigonal zircono- and, more rarely, titanosilicate minerals with general formula [N(1)N(2)N(3)N(4)N(5)]3[M(1a)M(1b)]3M(2)3M(4)Z3[Si24O72]O'4X2, where N(1) and N(2) and N(3) and N(5) = Na+ and more rarely H3O+ or H2O, N(4) = Na+, Sr2+, Mn2+ and more rarely H3O+ or H2O or K+ or Ca2+ or REE3+ (rare earth elements), M(1) and M(1b) = Ca2+, M(1a) = Ca2+ or Mn2+ or Fe2+, M(2) = Fe (both II and III), Mn and rarely Na+, K+ or Zr4+, M(3) = Si, Nb and rarely W, Ti and [] (vacancy), M(4) = Si and or rarely [], Z Zr4+ and or rarely Ti4+, and X = OH−, Cl− and more rarely CO32− or F−. Some of the eudialyte-like structures can even be more complex, however, in general, its typical feature is the presence of [Si3O9]6− and [Si9O27]18− ring silicate groups. Space group is usually R3m or R-3m but may be reduced to R3 due to cation ordering. Like other zirconosilicates, the eudialyte group minerals possess alkaline ion-exchange properties, as microporous materials.
Almarudite is an extremely rare alkaline manganese beryllium silicate mineral of the cyclosilicates class, with the chemical formula K([ ],Na)2(Mn2+,Fe2+,Mg)2(Be,Al)3[Si12O30], from the volcanic environment of the Eifel Mountains in Germany.
Tobermorite is a calcium silicate hydrate mineral with chemical formula: Ca5Si6O16(OH)2·4H2O or Ca5Si6(O,OH)18·5H2O.
Edenite or edenitic hornblende is a double chain silicate mineral of the amphibole group with the general chemical composition NaCa2Mg5(Si7Al)O22(OH)2. Edenite is named for the locality of Edenville, Orange County, New York, where it was first described.
This list gives an overview of the classification of minerals (silicates) and includes mostly International Mineralogical Association (IMA) recognized minerals and its groupings. This list complements the List of minerals recognized by the International Mineralogical Association series of articles and List of minerals. Rocks, ores, mineral mixtures, non-IMA approved minerals and non-named minerals are mostly excluded.
Cuspidine is a fluorine bearing calcium silicate mineral (sorosilicate) with formula: Ca4(Si2O7)(F,OH)2. Cuspidine crystallizes in the monoclinic crystal system and occurs as acicular to spear shaped pale red to light brown crystals. It is a member of the wöhlerite group.
Lamprophyllite is a rare, but widespread mineral Ti-silicate mineral usually found in intrusive agpasitic igneous rocks. Yellow, reddish brown, Vitreous, Pearly.
Coupled substitution is the geological process by which two elements simultaneous substitute into a crystal in order to maintain overall electrical neutrality and keep the charge constant. In forming a solid solution series, ionic size is more important than ionic charge, as this can be compensated for elsewhere in the structure.
The silicate carbonates are double salts that contain both silicate and carbonate in their formula. Most compounds are natural minerals containing calcium or rare earth elements. However, some have been made experimentally. Silicate carbonate minerals can be formed in limestone metamorphosed by heating from igneous intrusions. Scawtite forms where the activity of calcium is high compared to H+. Spurrite forms in a limited range of calcium activity and high silica activity. In magma, a carbonate rich melt is imiscible with a silicate melt.