Chemical thermodynamics is the study of the interrelation of heat and work with chemical reactions or with physical changes of state within the confines of the laws of thermodynamics. Chemical thermodynamics involves not only laboratory measurements of various thermodynamic properties, but also the application of mathematical methods to the study of chemical questions and the spontaneity of processes.
Entropy is a scientific concept, as well as a measurable physical property, that is most commonly associated with a state of disorder, randomness, or uncertainty. The term and the concept are used in diverse fields, from classical thermodynamics, where it was first recognized, to the microscopic description of nature in statistical physics, and to the principles of information theory. It has found far-ranging applications in chemistry and physics, in biological systems and their relation to life, in cosmology, economics, sociology, weather science, climate change, and information systems including the transmission of information in telecommunication.
Physical chemistry is the study of macroscopic and microscopic phenomena in chemical systems in terms of the principles, practices, and concepts of physics such as motion, energy, force, time, thermodynamics, quantum chemistry, statistical mechanics, analytical dynamics and chemical equilibria.
In physics, statistical mechanics is a mathematical framework that applies statistical methods and probability theory to large assemblies of microscopic entities. It does not assume or postulate any natural laws, but explains the macroscopic behavior of nature from the behavior of such ensembles.
Thermodynamics is a branch of physics that deals with heat, work, and temperature, and their relation to energy, entropy, and the physical properties of matter and radiation. The behavior of these quantities is governed by the four laws of thermodynamics which convey a quantitative description using measurable macroscopic physical quantities, but may be explained in terms of microscopic constituents by statistical mechanics. Thermodynamics applies to a wide variety of topics in science and engineering, especially physical chemistry, biochemistry, chemical engineering and mechanical engineering, but also in other complex fields such as meteorology.
Le Chatelier's principle, also called Chatelier's principle, is a principle of chemistry used to predict the effect of a change in conditions on chemical equilibria. The principle is named after French chemist Henry Louis Le Chatelier, and sometimes also credited to Karl Ferdinand Braun, who discovered it independently. It can be stated as:
When a simple system in thermodynamic equilibrium is subjected to a change in concentration, temperature, volume, or pressure, (1) the system changes to a new equilibrium, and (2) this change partly counteracts the applied change.
In thermodynamics, the Gibbs free energy is a thermodynamic potential that can be used to calculate the maximum amount of non-volume expansion work that may be performed by a thermodynamically closed system at constant temperature and pressure. It also provides a necessary condition for processes such as chemical reactions that may occur under these conditions. The Gibbs free energy is expressed as where P is pressure, T is the temperature, U is the internal energy, V is volume, H is the enthalpy, and S is the entropy.
Thermodynamic equilibrium is an axiomatic concept of thermodynamics. It is an internal state of a single thermodynamic system, or a relation between several thermodynamic systems connected by more or less permeable or impermeable walls. In thermodynamic equilibrium, there are no net macroscopic flows of matter nor of energy within a system or between systems. In a system that is in its own state of internal thermodynamic equilibrium, no macroscopic change occurs.
A thermodynamic system is a body of matter and/or radiation, considered as separate from its surroundings, and studied using the laws of thermodynamics. Thermodynamic systems may be isolated, closed, or open. An isolated system exchanges no matter or energy with its surroundings, whereas a closed system does not exchange matter but may exchange heat and experience and exert forces. An open system can interact with its surroundings by exchanging both matter and energy. The physical condition of a thermodynamic system at a given time is described by its state, which can be specified by the values of a set of thermodynamic state variables. A thermodynamic system is in thermodynamic equilibrium when there are no macroscopically apparent flows of matter or energy within it or between it and other systems.
Non-equilibrium thermodynamics is a branch of thermodynamics that deals with physical systems that are not in thermodynamic equilibrium but can be described in terms of macroscopic quantities that represent an extrapolation of the variables used to specify the system in thermodynamic equilibrium. Non-equilibrium thermodynamics is concerned with transport processes and with the rates of chemical reactions.
George Nicholas Hatsopoulos was a Greek American mechanical engineer noted for his work in thermodynamics and for having founded Thermo Electron.
Foundations of Physics is a monthly journal "devoted to the conceptual bases and fundamental theories of modern physics and cosmology, emphasizing the logical, methodological, and philosophical premises of modern physical theories and procedures". The journal publishes results and observations based on fundamental questions from all fields of physics, including: quantum mechanics, quantum field theory, special relativity, general relativity, string theory, M-theory, cosmology, thermodynamics, statistical physics, and quantum gravity
In the history of thermodynamics, On the Equilibrium of Heterogeneous Substances is a 300-page paper written by American chemical physicist Willard Gibbs. It is one of the founding papers in thermodynamics, along with German physicist Hermann von Helmholtz's 1882 paper "Thermodynamik chemischer Vorgänge." Together they form the foundation of chemical thermodynamics as well as a large part of physical chemistry.
Temperature is a physical quantity that expresses quantitatively the perceptions of hotness and coldness. Temperature is measured with a thermometer.
The Journal of Thermal Analysis and Calorimetry is a bimonthly peer-reviewed scientific journal published by Springer Science+Business Media on behalf of Akadémiai Kiadó. It was established in 1969 as the Journal of Thermal Analysis, obtaining its current title in 1998. The journal covers all aspects of calorimetry, thermal analysis, and experimental thermodynamics. The editor-in-chief is I.M. Szilágyi.
The International Journal of Geometric Methods in Modern Physics is a peer-reviewed journal, published by World Scientific, covering mathematical physics. It was originally published bimonthly beginning in January 2004; as of 2006 it appears 8 times a year. Editorial policy for the journal specifies that "The journal publishes short communications, research and review articles devoted to the application of geometric methods to quantum field theory, non-perturbative quantum gravity, string and brane theory, quantum mechanics, semi-classical approximations in quantum theory, quantum thermodynamics and statistical physics, quantum computation and control theory."
Nature Physics is a monthly peer-reviewed scientific journal published by Nature Portfolio. It was first published in October 2005. The chief editor is Andrea Taroni, who is a full-time professional editor employed by this journal.
The Journal of Chemical Thermodynamics is a monthly peer-reviewed scientific journal covering experimental thermodynamics and thermophysics including bio-thermodynamics, calorimetry, phase equilibria, equilibrium thermodynamic properties and transport properties. It is published by Elsevier. The editors-in-chief are W.E. Acree Jr., N. Kishore, B. F. Woodfield.
Geochemical modeling or theoretical geochemistry is the practice of using chemical thermodynamics, chemical kinetics, or both, to analyze the chemical reactions that affect geologic systems, commonly with the aid of a computer. It is used in high-temperature geochemistry to simulate reactions occurring deep in the Earth's interior, in magma, for instance, or to model low-temperature reactions in aqueous solutions near the Earth's surface, the subject of this article.
Vladimir Nikolajevich Pokrovskii is a Russian scientist known for his original contributions to polymer physics and economic theory. He was the founder of the Altai school of dynamics of nonlinear fluids.
