Keilite

Last updated
Keilite
General
CategorySulfides
Formula
(repeating unit)
(Fe2+,Mg)S
IMA symbol Ke [1]
Strunz classification 2/C.15-15
Dana classification2.8.1.9
Crystal system Isometric
Crystal class Hexoctahedral
Space group Fm3m (No. 225)
Unit cell a = 5.1717(18)Å
Identification
Formula mass 81.91 gm
ColourGrey
Crystal habit Microscopic crystals
Cleavage Distinct/good
Tenacity Brittle
Luster Metallic
Diaphaneity Opaque
Specific gravity 3.958
Density 3.958

Keilite is an iron-magnesium sulfide mineral with the chemical formula (Fe,Mg)S) that is found in enstatite chondrites. [2] Keilite is the iron-dominant analog of niningerite. [3] [4] Keilite is named after Klaus Keil (born 1934). [3]

Occurrences

Examples of keilite occurrences are enstatite chondrites and the Zakłodzie meteorite. [4] It appears to be confined to impact-melt influenced enstatite chondrites that were quenched. There are also some meteorites interpreted as impact-melt breccias that do not contain keilite. This is explained as a deeper burial after impact, which slowed cooling and enabled retrograde reactions (diapthoresis) to take place. [5]

Related Research Articles

<span class="mw-page-title-main">Kamacite</span> Alloy of iron and nickel found in meteorites

Kamacite is an alloy of iron and nickel, which is found on Earth only in meteorites. According to the International Mineralogical Association (IMA) it is considered a proper nickel-rich variety of the mineral native iron. The proportion iron:nickel is between 90%:10% and 95%:5%; small quantities of other elements, such as cobalt or carbon may also be present. The mineral has a metallic luster, is gray and has no clear cleavage although its crystal structure is isometric-hexoctahedral. Its density is about 8 g/cm3 and its hardness is 4 on the Mohs scale. It is also sometimes called balkeneisen.

<span class="mw-page-title-main">Meteorite classification</span> Systems of grouping meteorites based on shared characteristics

In meteoritics, a meteorite classification system attempts to group similar meteorites and allows scientists to communicate with a standardized terminology when discussing them. Meteorites are classified according to a variety of characteristics, especially mineralogical, petrological, chemical, and isotopic properties.

<span class="mw-page-title-main">Chondrule</span> Round grain found in chondrites, stony meteorites

A chondrule is a round grain found in a chondrite. Chondrules form as molten or partially molten droplets in space before being accreted to their parent asteroids. Because chondrites represent one of the oldest solid materials within the Solar System and are believed to be the building blocks of the planetary system, it follows that an understanding of the formation of chondrules is important to understand the initial development of the planetary system.

<span class="mw-page-title-main">Chondrite</span> Class of stony meteorites made of round grains

A chondrite is a stony (non-metallic) meteorite that has not been modified, by either melting or differentiation of the parent body. They are formed when various types of dust and small grains in the early Solar System accreted to form primitive asteroids. Some such bodies that are captured in the planet's gravity well become the most common type of meteorite by arriving on a trajectory toward the planet's surface. Estimates for their contribution to the total meteorite population vary between 85.7% and 86.2%.

<span class="mw-page-title-main">Forsterite</span> Magnesium end-member of olivine, a nesosilicate mineral

Forsterite (Mg2SiO4; commonly abbreviated as Fo; also known as white olivine) is the magnesium-rich end-member of the olivine solid solution series. It is isomorphous with the iron-rich end-member, fayalite. Forsterite crystallizes in the orthorhombic system (space group Pbnm) with cell parameters a 4.75 Å (0.475 nm), b 10.20 Å (1.020 nm) and c 5.98 Å (0.598 nm).

<span class="mw-page-title-main">Enstatite</span> Pyroxene: magnesium-iron silicate with MgSiO3 and FeSiO3 end-members

Enstatite is a mineral; the magnesium endmember of the pyroxene silicate mineral series enstatite (MgSiO3) – ferrosilite (FeSiO3). The magnesium rich members of the solid solution series are common rock-forming minerals found in igneous and metamorphic rocks. The intermediate composition, (Mg,Fe)SiO
3
, has historically been known as hypersthene, although this name has been formally abandoned and replaced by orthopyroxene. When determined petrographically or chemically the composition is given as relative proportions of enstatite (En) and ferrosilite (Fs) (e.g., En80Fs20).

<span class="mw-page-title-main">Oldhamite</span> Rocksalt group, sulfide mineral

Oldhamite is a calcium magnesium sulfide mineral with the chemical formula (Ca,Mg)S. Ferrous iron may also be present in the mineral resulting in the chemical formula (Ca,Mg,Fe)S. It is a pale to dark brown accessory mineral in meteorites. It crystallizes in the cubic crystal system, but typically occurs as anhedral grains between other minerals.

<span class="mw-page-title-main">Moon rock</span> Rocks on or from the Moon

Moon rock or lunar rock is rock originating from Earth's Moon. This includes lunar material collected during the course of human exploration of the Moon, and rock that has been ejected naturally from the Moon's surface and landed on Earth as meteorites.

<span class="mw-page-title-main">Wadsleyite</span> Mineral thought to be abundant in the Earths mantle

Wadsleyite is an orthorhombic mineral with the formula β-(Mg,Fe)2SiO4. It was first found in nature in the Peace River meteorite from Alberta, Canada. It is formed by a phase transformation from olivine (α-(Mg,Fe)2SiO4) under increasing pressure and eventually transforms into spinel-structured ringwoodite (γ-(Mg,Fe)2SiO4) as pressure increases further. The structure can take up a limited amount of other bivalent cations instead of magnesium, but contrary to the α and γ structures, a β structure with the sum formula Fe2SiO4 is not thermodynamically stable. Its cell parameters are approximately a = 5.7 Å, b = 11.71 Å and c = 8.24 Å.

Niningerite is a magnesium-iron-manganese sulfide mineral with the chemical formula MgS that is found in enstatite chondrite meteorites. Niningerite is the magnesium-dominant analog of keilite. This mineral is named after Harvey H. Nininger.

<span class="mw-page-title-main">Brianite</span>

Brianite is a phosphate mineral with the chemical formula Na2CaMg(PO4)2. It was first identified in an iron meteorite. This mineral is named after Brian Harold Mason (1917–2009), a pioneer in meteoritics.

<span class="mw-page-title-main">Enstatite chondrite</span> Rare type of meteorite

Enstatite chondrites are a rare form of meteorite, rich in the mineral enstatite. Only about 200 E-Type chondrites are currently known, comprising about 2% of the chondrites that fall on Earth. There are two main subtypes: EH and EL, classified based on their iron content.

<span class="mw-page-title-main">Abee (meteorite)</span>

Abee is an enstatite chondrite meteorite that fell on 9 June 1952 in Alberta, Canada.

<span class="mw-page-title-main">Suessite</span>

Suessite is a rare iron silicide mineral with chemical formula: Fe3Si. The mineral was named after Professor Hans E. Suess. It was discovered in 1982 during the chemical analysis of The North Haig olivine pigeonite achondrite (ureilite). It is a cream white color in reflected light, and ranges in size from 1 μm "blebs" to elongated grains that can reach up to 0.45 cm in length. This mineral belongs in the isometric crystal class. The isometric class has crystallographic axes that are all the same length and each of the three axes perpendicular to the other two. It is isotropic, has a structural type of DO3 and a crystal lattice of BiF3.

<span class="mw-page-title-main">Sinoite</span>

Sinoite is rare mineral with the chemical formula Si2N2O. It was first found in 1905 in chondrite meteorites and identified as a distinct mineral in 1965. Sinoite crystallizes upon meteorite impact as grains smaller than 0.2 mm surrounded by Fe-Ni alloys and the mineral enstatite. It is named after its SiNO composition and can be prepared in the laboratory as a silicon oxynitride ceramic.

<span class="mw-page-title-main">Lodranite</span> Type of meteorites

Lodranites are a small group of primitive achondrite meteorites that consists of meteoric iron and silicate minerals. Olivine and pyroxene make up most of the silicate minerals. Like all primitive achondrites lodranites share similarities with chondrites and achondrites.

Winonaites are a group of primitive achondrite meteorites. Like all primitive achondrites, winonaites share similarities with chondrites and achondrites. They show signs of metamorphism, partial melting, brecciation and relic chondrules. Their chemical and mineralogical composition lies between H and E chondrites.

<span class="mw-page-title-main">Zaklodzie meteorite</span>

The Zakłodzie meteorite is a stony-iron meteorite found in Poland in 1998. Its mass is 8.68 kilograms (19.1 lb). It is composed predominantly from enstatite and meteoric iron. Currently classified as an ungrouped enstatite achondrite its classification is still an ongoing scientific debate.

The Itqiy meteorite is an enstatite-rich stony-iron meteorite. It is classified as an enstatite chondrite of the EH group that was nearly melted and is therefore very unusual for that group. Other classifications have been proposed and are an ongoing scientific debate.

<span class="mw-page-title-main">Perryite</span> Mineral found in meteorites

Perryite is a nickel silicide mineral. It is found in extremely silicon-rich meteorites. The type material is housed at the National Museum of Natural History in Washington. It was first found in Horse Creek and described in 1963 by Fredriksson and Wickman. It was named after Stuart Hoffman Perry, and American meteorite collector. The mineral is typically found intermixed with troilite, an iron sulfide. It is a minor constituent of metal enstatite chondrite meteorites.

References

  1. Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine. 85 (3): 291–320. Bibcode:2021MinM...85..291W. doi: 10.1180/mgm.2021.43 . S2CID   235729616.
  2. "Keilite Mineral Data". WebMineral. Retrieved 15 February 2021.
  3. 1 2 "Keilite" (PDF). Handbook of Mineralogy. Archived from the original (PDF) on 3 March 2016. Retrieved 15 February 2021.
  4. 1 2 Shimizu M, Yoshida H, Mandarino JA (2002). "The New Mineral Species Keilite, (Fe,Mg)S, The Iron-Dominant Analogue of Niningerite" (PDF). The Canadian Mineralogist. 40 (6): 1687–1692. doi:10.2113/gscanmin.40.6.1687. S2CID   93381076.
  5. Keil, Klaus (30 April 2007). "Occurrence and origin of keilite, (Fe>0.5,Mg<0.5)S, in enstatite chondrite impact-melt rocks and impact-melt breccias". Chemie der Erde - Geochemistry. 67 (1): 37–54. Bibcode:2007ChEG...67...37K. doi:10.1016/j.chemer.2006.05.002.