| Octahedrite | |
|---|---|
| — Structural class — | |
 Octahedrite from Toluca | |
| Compositional type | Iron |
 A phase diagram showing the link between structural and chemical classification. | |
Octahedrites are the most common structural class of iron meteorites. The structures occur because the meteoric iron has a certain nickel concentration that leads to the exsolution of kamacite out of taenite while cooling.
Octahedrites derive their name from the crystal structure paralleling an octahedron. Opposite faces are parallel so, although an octahedron has 8 faces, there are only 4 sets of kamacite plates.
Due to a long cooling time in the interior of the parent asteroids, these alloys have crystallized into intermixed millimeter-sized bands (from about 0.2 mm to 5 cm). [1] When polished and acid etched the classic Widmanstätten patterns of intersecting lines of lamellar kamacite, are visible.
In gaps between the kamacite and taenite lamellae, a fine-grained mixture called plessite is often found. An iron nickel phosphide, schreibersite, is present in most nickel-iron meteorites, as well as an iron-nickel-cobalt carbide, cohenite. Graphite and troilite occur in rounded nodules up to several cm in size. [2]
Octahedrites can be grouped by the dimensions of kamacite lamellae in the Widmanstätten pattern, which are related to the nickel content: [3]
Octahedrite is an obsolete synonym for anatase, one of the three known titanium dioxide minerals.[ citation needed ]
Kamacite is an alloy of iron and nickel, which is found on Earth only in meteorites. According to the International Mineralogical Association (IMA) it is considered a proper nickel-rich variety of the mineral native iron. The proportion iron:nickel is between 90%:10% and 95%:5%; small quantities of other elements, such as cobalt or carbon may also be present. The mineral has a metallic luster, is gray and has no clear cleavage although its crystal structure is isometric-hexoctahedral. Its density is about 8 g/cm3 and its hardness is 4 on the Mohs scale. It is also sometimes called balkeneisen.
Terrestrial rocks are formed by three main mechanisms:
Widmanstätten patterns, also known as Thomson structures, are figures of long nickel–iron crystals, found in the octahedrite iron meteorites and some pallasites. They consist of a fine interleaving of kamacite and taenite bands or ribbons called lamellae. Commonly, in gaps between the lamellae, a fine-grained mixture of kamacite and taenite called plessite can be found. Widmanstätten patterns describe features in modern steels, titanium, and zirconium alloys.
Meteoric iron, sometimes meteoritic iron, is a native metal and early-universe protoplanetary-disk remnant found in meteorites and made from the elements iron and nickel, mainly in the form of the mineral phases kamacite and taenite. Meteoric iron makes up the bulk of iron meteorites but is also found in other meteorites. Apart from minor amounts of telluric iron, meteoric iron is the only naturally occurring native metal of the element iron on the Earth's surface.
Ataxites are a structural class of iron meteorites with a high nickel content and show no Widmanstätten patterns upon etching.
Hexahedrites are a structural class of iron meteorite. They are composed almost exclusively of the nickel–iron alloy kamacite and are lower in nickel content than the octahedrites. The nickel concentration in hexahedrites is always below 5.8% and only rarely below 5.3%.
Taenite is a mineral found naturally on Earth mostly in iron meteorites. It is an alloy of iron and nickel, with a chemical formula of Fe,Ni and nickel proportions of 20% up to 65%.
Plessite is a meteorite texture consisting of a fine-grained mixture of the minerals kamacite and taenite found in the octahedrite iron meteorites. It occurs in gaps between the larger bands of kamacite and taenite which form Widmanstätten patterns.
Neumann lines, or Neumann bands, are fine patterns of parallel lines seen in cross-sections of many hexahedrite iron meteorites in the kamacite phase, although they may appear also in octahedrites provided the kamacite phase is about 30 micrometres wide. They can be seen after a polished meteorite cross-section is treated with acid. The lines are indicative of a shock-induced deformation of the kamacite crystal, and are thought to be due to impact events on the parent body of the meteorite.
Iron meteorites, also called siderites or ferrous meteorites, are a type of meteorite that consist overwhelmingly of an iron–nickel alloy known as meteoric iron that usually consists of two mineral phases: kamacite and taenite. Most iron meteorites originate from cores of planetesimals, with the exception of the IIE iron meteorite group
Antitaenite is a meteoritic metal alloy mineral composed of iron (Fe) and 20–40% nickel (Ni), that has a face centered cubic crystal structure.
Haxonite is an iron nickel carbide mineral found in iron meteorites and carbonaceous chondrites. It has a chemical formula of (Fe,Ni)23C6, crystallises in the cubic crystal system and has a Mohs hardness of 5+1⁄2 - 6.
Lac Dodon is an iron meteorite discovered by Roland Octerneau of Montreal on rural private property near Lac Dodon, Saint-Calixte, Quebec.
Elbogen, also the Loket Iron, is an iron meteorite that fell in the village of Loket, Karlovy Vary Region, Kingdom of Bohemia, about the year 1400. Also known during the Middle Ages as the "bewitched burgrave" of Elbogen, due to a cursed Count at the Elbogen castle, it is the oldest of 15 recorded falls in the Czech Republic. It has not survived to our time in its original size, having been cut for scientific purposes and its pieces sent to museums all around the world.
IAB meteorites are a group of iron meteorites according to their overall composition and a group of primitive achondrites because of silicate inclusions that show a strong affinity to winonaites and chondrites.
IVB meteorites are a group of ataxite iron meteorites classified as achondrites. The IVB group has the most extreme chemical compositions of all iron meteorites, meaning that examples of the group are depleted in volatile elements and enriched in refractory elements compared to other iron meteorites.
Daubréelite is a rare sulfide mineral. It crystallizes with cubic symmetry and has chemical composition of Fe2+Cr3+2S4. It usually occurs as black platy aggregates.
Tetrataenite is a native metal alloy composed of chemically-ordered L10-type FeNi, recognized as a mineral in 1980. The mineral is named after its tetragonal crystal structure and its relation to the iron-nickel alloy, taenite. It is one of the mineral phases found in meteoric iron.
This is a glossary of terms used in meteoritics, the science of meteorites.
IIAB meteorites are a group of iron meteorites. Their structural classification ranges from hexahedrites to octahedrites. IIABs have the lowest concentration of nickel of all iron meteorite groups. Most iron meteorites are derived from the metallic planetary cores of their respective parent bodies, but in the case of the IIABs the metallic magma separated to form not only this meteorite group but also the IIG group.