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Magnetic resonance is a process by which a physical excitation (resonance) is set up via magnetism.
This process was used to develop magnetic resonance imaging (MRI) and nuclear magnetic resonance spectroscopy (NMRS) technology.
It is also being used to develop nuclear magnetic resonance quantum computers.
The first observation of electron-spin resonance was in 1944 by Y. K. Zavosky, a Soviet physicist then teaching at Kazan State University (now Kazan Federal University). Nuclear magnetic resonance was first observed in 1946 in the US by a team led by Felix Bloch at the same time as a separate team led by Edward Mills Purcell, the two of whom would later be the 1952 Nobel Laureates in Physics. [1] [2] [3]
A natural way to measure the separation between two energy levels is to find a measurable quantity defined by this separation and measure it. However, the precision of this method is limited by measurement precision and thus may be poor.
Alternatively, we can set up an experiment in which the system's behavior depends on the energy level. If we apply an external field of controlled frequency, we can measure the level separation by noting at which frequency a qualitative change happens: that would mean that at this frequency, the transition between two states has a high probability. An example of such an experiment is a variation of Stern–Gerlach experiment, in which magnetic moment is measured by finding resonance frequency for the transition between two spin states. [4] [5]
Condensed matter physics is the field of physics that deals with the macroscopic and microscopic physical properties of matter, especially the solid and liquid phases which arise from electromagnetic forces between atoms. More generally, the subject deals with condensed phases of matter: systems of many constituents with strong interactions among them. More exotic condensed phases include the superconducting phase exhibited by certain materials at extremely low cryogenic temperature, the ferromagnetic and antiferromagnetic phases of spins on crystal lattices of atoms, and the Bose–Einstein condensate found in ultracold atomic systems. Condensed matter physicists seek to understand the behavior of these phases by experiments to measure various material properties, and by applying the physical laws of quantum mechanics, electromagnetism, statistical mechanics, and other physics theories to develop mathematical models.
The electron is a subatomic particle with a negative one elementary electric charge. Electrons belong to the first generation of the lepton particle family, and are generally thought to be elementary particles because they have no known components or substructure. The electron's mass is approximately 1/1836 that of the proton. Quantum mechanical properties of the electron include an intrinsic angular momentum (spin) of a half-integer value, expressed in units of the reduced Planck constant, ħ. Being fermions, no two electrons can occupy the same quantum state, per the Pauli exclusion principle. Like all elementary particles, electrons exhibit properties of both particles and waves: They can collide with other particles and can be diffracted like light. The wave properties of electrons are easier to observe with experiments than those of other particles like neutrons and protons because electrons have a lower mass and hence a longer de Broglie wavelength for a given energy.
A Penning trap is a device for the storage of charged particles using a homogeneous magnetic field and a quadrupole electric field. It is mostly found in the physical sciences and related fields of study as a tool for precision measurements of properties of ions and stable subatomic particles, like for example mass, fission yields and isomeric yield ratios. One initial object of study were the so-called geonium atoms, which represent a way to measure the electron magnetic moment by storing a single electron. These traps have been used in the physical realization of quantum computation and quantum information processing by trapping qubits. Penning traps are in use in many laboratories worldwide, including CERN, to store and investigate anti-particles such as antiprotons. The main advantages of Penning traps are the potentially long storage times and the existence of a multitude of techniques to manipulate and non-destructively detect the stored particles. This makes Penning traps versatile tools for the investigation of stored particles, but also for their selection, preparation or mere storage.
Molecular physics is the study of the physical properties of molecules and molecular dynamics. The field overlaps significantly with physical chemistry, chemical physics, and quantum chemistry. It is often considered as a sub-field of atomic, molecular, and optical physics. Research groups studying molecular physics are typically designated as one of these other fields. Molecular physics addresses phenomena due to both molecular structure and individual atomic processes within molecules. Like atomic physics, it relies on a combination of classical and quantum mechanics to describe interactions between electromagnetic radiation and matter. Experiments in the field often rely heavily on techniques borrowed from atomic physics, such as spectroscopy and scattering.
Dynamic nuclear polarization (DNP) results from transferring spin polarization from electrons to nuclei, thereby aligning the nuclear spins to the extent that electron spins are aligned. Note that the alignment of electron spins at a given magnetic field and temperature is described by the Boltzmann distribution under the thermal equilibrium. It is also possible that those electrons are aligned to a higher degree of order by other preparations of electron spin order such as: chemical reactions, optical pumping and spin injection. DNP is considered one of several techniques for hyperpolarization. DNP can also be induced using unpaired electrons produced by radiation damage in solids.
In atomic physics, the electron magnetic moment, or more specifically the electron magnetic dipole moment, is the magnetic moment of an electron resulting from its intrinsic properties of spin and electric charge. The value of the electron magnetic moment is −9.2847647043(28)×10−24 J⋅T−1. In units of the Bohr magneton (μB), it is −1.00115965218059(13) μB, a value that was measured with a relative accuracy of 1.3×10−13.
Electron paramagnetic resonance (EPR) or electron spin resonance (ESR) spectroscopy is a method for studying materials that have unpaired electrons. The basic concepts of EPR are analogous to those of nuclear magnetic resonance (NMR), but the spins excited are those of the electrons instead of the atomic nuclei. EPR spectroscopy is particularly useful for studying metal complexes and organic radicals. EPR was first observed in Kazan State University by Soviet physicist Yevgeny Zavoisky in 1944, and was developed independently at the same time by Brebis Bleaney at the University of Oxford.
Quantum mechanics is the study of matter and its interactions with energy on the scale of atomic and subatomic particles. By contrast, classical physics explains matter and energy only on a scale familiar to human experience, including the behavior of astronomical bodies such as the moon. Classical physics is still used in much of modern science and technology. However, towards the end of the 19th century, scientists discovered phenomena in both the large (macro) and the small (micro) worlds that classical physics could not explain. The desire to resolve inconsistencies between observed phenomena and classical theory led to a revolution in physics, a shift in the original scientific paradigm: the development of quantum mechanics.
In MRI and NMR spectroscopy, an observable nuclear spin polarization (magnetization) is created by a homogeneous magnetic field. This field makes the magnetic dipole moments of the sample precess at the resonance (Larmor) frequency of the nuclei. At thermal equilibrium, nuclear spins precess randomly about the direction of the applied field. They become abruptly phase coherent when they are hit by radiofrequency (RF) pulses at the resonant frequency, created orthogonal to the field. The RF pulses cause the population of spin-states to be perturbed from their thermal equilibrium value. The generated transverse magnetization can then induce a signal in an RF coil that can be detected and amplified by an RF receiver. The return of the longitudinal component of the magnetization to its equilibrium value is termed spin-latticerelaxation while the loss of phase-coherence of the spins is termed spin-spin relaxation, which is manifest as an observed free induction decay (FID).
Yevgeny Konstantinovich Zavoisky was a Soviet physicist known for discovery of electron paramagnetic resonance in 1944. He likely observed nuclear magnetic resonance in 1941, well before Felix Bloch and Edward Mills Purcell, but dismissed the results as not reproducible. Zavoisky is also credited with design of luminescence camera for detection of nuclear processes in 1952 and discovery of magneto-acoustic resonance in plasma in 1958.
The history of quantum mechanics is a fundamental part of the history of modern physics. The major chapters of this history begin with the emergence of quantum ideas to explain individual phenomena -- blackbody radiation, the photoelectric effect, solar emission spectra -- an era called the Old or Older quantum theories. The invention of wave mechanics by Schrodinger and expanded by many others triggers the "modern" era beginning around 1925. Dirac's relativistic quantum theory work lead him to explore quantum theories of radiation, culminating in quantum electrodynamics, the first quantum field theory. The history of quantum mechanics continues in the history of quantum field theory. The history of quantum chemistry, theoretical basis of chemical structure, reactivity, and bonding, interlaces with the events discussed in this article.
Quantum electrodynamics (QED), a relativistic quantum field theory of electrodynamics, is among the most stringently tested theories in physics. The most precise and specific tests of QED consist of measurements of the electromagnetic fine-structure constant, α, in various physical systems. Checking the consistency of such measurements tests the theory.
The timeline of quantum mechanics is a list of key events in the history of quantum mechanics, quantum field theories and quantum chemistry.
Nuclear magnetic resonance (NMR) is a physical phenomenon in which nuclei in a strong constant magnetic field are perturbed by a weak oscillating magnetic field and respond by producing an electromagnetic signal with a frequency characteristic of the magnetic field at the nucleus. This process occurs near resonance, when the oscillation frequency matches the intrinsic frequency of the nuclei, which depends on the strength of the static magnetic field, the chemical environment, and the magnetic properties of the isotope involved; in practical applications with static magnetic fields up to ca. 20 tesla, the frequency is similar to VHF and UHF television broadcasts (60–1000 MHz). NMR results from specific magnetic properties of certain atomic nuclei. Nuclear magnetic resonance spectroscopy is widely used to determine the structure of organic molecules in solution and study molecular physics and crystals as well as non-crystalline materials. NMR is also routinely used in advanced medical imaging techniques, such as in magnetic resonance imaging (MRI).
Electrically detected magnetic resonance (EDMR) is a materials characterisation technique that improves upon electron spin resonance. It involves measuring the change in electrical resistance of a sample when exposed to certain microwave frequencies. It can be used to identify very small numbers of impurities in semiconductors.
Acoustic paramagnetic resonance (APR) is a phenomenon of resonant absorption of sound by a system of magnetic particles placed in an external magnetic field. It occurs when the energy of the sound wave quantum becomes equal to the splitting of the energy levels of the particles, the splitting being induced by the magnetic field. APR is a variation of electron paramagnetic resonance (EPR) where the acoustic rather than electromagnetic waves are absorbed by the studied sample. APR was theoretically predicted in 1952, independently by Semen Altshuler and Alfred Kastler, and was experimentally observed by W. G. Proctor and W. H. Tanttila in 1955.
Semyon Alexandrovich Altshuler was a Soviet physicist known for his work in resonance spectroscopy and in particular for theoretical prediction of acoustic paramagnetic resonance in 1952.
The index of physics articles is split into multiple pages due to its size.
The I. I. Rabi Prize in Atomic, Molecular, and Optical Physics is given by the American Physical Society to recognize outstanding work by mid-career researchers in the field of atomic, molecular, and optical physics. The award was endowed in 1989 in honor of the physicist I. I. Rabi and has been awarded biannually since 1991.