Pressure retarded osmosis (PRO) is a technique to separate a solvent (for example, fresh water) from a solution that is more concentrated (e.g. sea water) and also pressurized. A semipermeable membrane allows the solvent to pass to the concentrated solution side by osmosis. [1] The technique can be used to generate power from the salinity gradient energy resulting from the difference in the salt concentration between sea and river water.
This method of generating power was invented by Prof. Sidney Loeb in 1973 at the Ben-Gurion University of the Negev, Beersheba, Israel. [2] [3]
Richard Norman submitted a manuscript describing the concept to Science in May 1974. [4] In that manuscript, Norman clearly indicated that he was unaware of any prior work on the topic. Loeb submitted a comment on Norman's cost analysis to Science in January 1975. [5] In that publication, Loeb proposed the term "pressure retarded osmosis". He further wrote "To facilitate examination of the concept in some detail, the United States-Israel Binational Science Foundation awarded a grant (No. 337) to our Research Authority in May 1974."
The ideal power production formula, which applies to an idealized situation, predicts that the optimal hydraulic pressure difference, is one-half the osmotic pressure difference between the saline and pure water streams . [4] [6] For a seawater to fresh water PRO system, the ideal case corresponds to an optimal power pressure of 26 bars. This pressure is equivalent to a column of water (hydraulic head) 270 meters high. [7]
In a real-world system, both the hydraulic pressure and the osmotic pressure will vary through the PRO system as a result of friction, water removal, and salt build up near the membranes. These factors reduce the achievable power below the ideal limit. The amount of membrane area that can be used is limited by cost and other practical considerations, and this factor limits achievable power production. [8] A significant portion of the electrical power generated by PRO must be used by the pumps that circulate water through the plant. [9] Appropriate membranes are also necessary. All these factors have limited the economic viability of PRO. [10]
PRO has the potential to extract osmotic power from waste streams, such as desalination plant brine discharge or treated wastewater effluent. The potential power output is proportional to the salinity difference between the fresh and saline water streams. Desalination yields very salty brine, while treated municipal wastewater has relatively little salt. Combining those streams could produce energy to power both facilities. However, powering an existing wastewater treatment plant by mixing treated wastewater with seawater in a mid-size city could require a membrane area of 2.5 million square meters. [11]
PRO uses a water–permeable membrane with an osmotic pressure difference to drive water flux from a low–concentration "diluate" stream, into a slightly pressurized higher–concentration. An energy recovery device on this stream provides the energy output, and must exceed the pumping pressure input for net power production.
The world's first osmotic plant with capacity of 10 kW was opened by Statkraft, a state-owned hydropower company, on 24 November 2009 in Tofte, Norway. [13] It had been estimated that PRO could generate 12 TWh annually in Norway, sufficient to meet 10% of Norway's total demand for electricity. [14]
In January 2014, Statkraft terminated their pressure-retarded osmosis pilot project [15] due to economic feasibility concerns.
Starting in 2021, SaltPower is building another commercial osmotic power plant in Denmark using very high salinity brine from a geothermal power plant. [16]
Brine is water with a high-concentration solution of salt. In diverse contexts, brine may refer to the salt solutions ranging from about 3.5% up to about 26%. Brine forms naturally due to evaporation of ground saline water but it is also generated in the mining of sodium chloride. Brine is used for food processing and cooking, for de-icing of roads and other structures, and in a number of technological processes. It is also a by-product of many industrial processes, such as desalination, so it requires wastewater treatment for proper disposal or further utilization.
Desalination is a process that removes mineral components from saline water. More generally, desalination is the removal of salts and minerals from a substance. One example is soil desalination. This is important for agriculture. It is possible to desalinate saltwater, especially sea water, to produce water for human consumption or irrigation. The by-product of the desalination process is brine. Many seagoing ships and submarines use desalination. Modern interest in desalination mostly focuses on cost-effective provision of fresh water for human use. Along with recycled wastewater, it is one of the few water resources independent of rainfall.
Semipermeable membrane is a type of biological or synthetic, polymeric membrane that allows certain molecules or ions to pass through it by osmosis. The rate of passage depends on the pressure, concentration, and temperature of the molecules or solutes on either side, as well as the permeability of the membrane to each solute. Depending on the membrane and the solute, permeability may depend on solute size, solubility, properties, or chemistry. How the membrane is constructed to be selective in its permeability will determine the rate and the permeability. Many natural and synthetic materials which are rather thick are also semipermeable. One example of this is the thin film on the inside of an egg.
Ultrafiltration (UF) is a variety of membrane filtration in which forces such as pressure or concentration gradients lead to a separation through a semipermeable membrane. Suspended solids and solutes of high molecular weight are retained in the so-called retentate, while water and low molecular weight solutes pass through the membrane in the permeate (filtrate). This separation process is used in industry and research for purifying and concentrating macromolecular (103–106 Da) solutions, especially protein solutions.
Forward osmosis (FO) is an osmotic process that, like reverse osmosis (RO), uses a semi-permeable membrane to effect separation of water from dissolved solutes. The driving force for this separation is an osmotic pressure gradient, such that a "draw" solution of high concentration, is used to induce a net flow of water through the membrane into the draw solution, thus effectively separating the feed water from its solutes. In contrast, the reverse osmosis process uses hydraulic pressure as the driving force for separation, which serves to counteract the osmotic pressure gradient that would otherwise favor water flux from the permeate to the feed. Hence significantly more energy is required for reverse osmosis compared to forward osmosis.
A physical plant, mechanical plant or industrial plant refers to the necessary infrastructure used in operation and maintenance of a given facility. The operation of these facilities, or the department of an organization which does so, is called "plant operations" or facility management. Industrial plant should not be confused with "manufacturing plant" in the sense of "a factory". This is a holistic look at the architecture, design, equipment, and other peripheral systems linked with a plant required to operate or maintain it.
Solar desalination is a desalination technique powered by solar energy. The two common methods are direct (thermal) and indirect (photovoltaic).
Osmotic power, salinity gradient power or blue energy is the energy available from the difference in the salt concentration between seawater and river water. Two practical methods for this are reverse electrodialysis (RED) and pressure retarded osmosis (PRO). Both processes rely on osmosis with membranes. The key waste product is brackish water. This byproduct is the result of natural forces that are being harnessed: the flow of fresh water into seas that are made up of salt water.
Thin-film composite membranes are semipermeable membranes manufactured to provide selectivity with high permeability. Most TFC's are used in water purification or water desalination systems. They also have use in chemical applications such as gas separations, dehumidification, batteries and fuel cells. A TFC membrane can be considered a molecular sieve constructed in the form of a film from two or more layered materials. The additional layers provide structural strength and a low-defect surface to support a selective layer that is thin enough to be selective but not so thick that it causes low permeability.
Menachem Elimelech is the Sterling Professor of Chemical and Environmental Engineering at Yale University. Elimelech is the only professor from an engineering department at Yale to be awarded the Sterling professorship since its establishment in 1920. Elimelech moved from the University of California, Los Angeles (UCLA) to Yale University in 1998 and founded Yale's Environmental Engineering program.
Nanofiltration is a membrane filtration process that uses nanometer sized pores through which particles smaller than about 1–10 nanometers pass through the membrane. Nanofiltration membranes have pore sizes of about 1–10 nanometers, smaller than those used in microfiltration and ultrafiltration, but a slightly bigger than those in reverse osmosis. Membranes used are predominantly polymer thin films. It is used to soften, disinfect, and remove impurities from water, and to purify or separate chemicals such as pharmaceuticals.
A solar-powered desalination unit produces potable water from saline water through direct or indirect methods of desalination powered by sunlight. Solar energy is the most promising renewable energy source due to its ability to drive the more popular thermal desalination systems directly through solar collectors and to drive physical and chemical desalination systems indirectly through photovoltaic cells.
Reverse electrodialysis (RED) is the salinity gradient energy retrieved from the difference in the salt concentration between seawater and river water. A method of utilizing the energy produced by this process by means of a heat engine was invented by Prof. Sidney Loeb in 1977 at the Ben-Gurion University of the Negev. --United States Patent US4171409
Membrane fouling is a process whereby a solution or a particle is deposited on a membrane surface or in membrane pores in a processes such as in a membrane bioreactor, reverse osmosis, forward osmosis, membrane distillation, ultrafiltration, microfiltration, or nanofiltration so that the membrane's performance is degraded. It is a major obstacle to the widespread use of this technology. Membrane fouling can cause severe flux decline and affect the quality of the water produced. Severe fouling may require intense chemical cleaning or membrane replacement. This increases the operating costs of a treatment plant. There are various types of foulants: colloidal, biological, organic and scaling.
Sidney Loeb (1917–2008) was an American-Israeli chemical engineer. Loeb made reverse osmosis (RO) practical by developing, together with Srinivasa Sourirajan, semi-permeable anisotropic membranes. The invention of the practical reverse osmosis membrane revolutionized water desalination. Loeb invented the power generating process pressure retarded osmosis (PRO)--making accessible a rich previously unknown source of green energy, and a method of producing power by a reverse electrodialysis (RED) heat engine, among other inventions in related fields. The production of energy by PRO and RED, among others, is sometimes called "osmotic power."
Reverse osmosis (RO) is a water purification process that uses a semi-permeable membrane to separate water molecules from other substances. RO applies pressure to overcome osmotic pressure that favors even distributions. RO can remove dissolved or suspended chemical species as well as biological substances, and is used in industrial processes and the production of potable water. RO retains the solute on the pressurized side of the membrane and the purified solvent passes to the other side. It relies on the relative sizes of the various molecules to decide what passes through. "Selective" membranes reject large molecules, while accepting smaller molecules.
Osmosis is the spontaneous net movement or diffusion of solvent molecules through a selectively-permeable membrane from a region of high water potential to a region of low water potential, in the direction that tends to equalize the solute concentrations on the two sides. It may also be used to describe a physical process in which any solvent moves across a selectively permeable membrane separating two solutions of different concentrations. Osmosis can be made to do work. Osmotic pressure is defined as the external pressure required to be applied so that there is no net movement of solvent across the membrane. Osmotic pressure is a colligative property, meaning that the osmotic pressure depends on the molar concentration of the solute but not on its identity.
Membrane distillation (MD) is a thermally driven separation process in which separation is driven by phase change. A hydrophobic membrane presents a barrier for the liquid phase, allowing the vapour phase to pass through the membrane's pores. The driving force of the process is a partial vapour pressure difference commonly triggered by a temperature difference.
Water shortages have become an increasingly pressing concern recently and with recent predictions of a high probability of the current drought turning into a megadrought occurring in the western United States, technologies involving water treatment and processing need to improve. Carbon nanotubes (CNT) have been the subject of extensive studies because they demonstrate a range of unique properties that existing technologies lack. For example, carbon nanotube membranes can demonstrate higher water flux with lower energy than current membranes. These membranes can also filter out particles that are too small for conventional systems which can lead to better water purification techniques and less waste. The largest obstacle facing CNT is processing as it is difficult to produce them in the large quantities that most of these technologies will require.
Robert L. McGinnis is an American scientist, technology entrepreneur, and inventor who has founded a number of technology companies including Prometheus Fuels, Mattershift and Oasys Water.
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