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<span class="mw-page-title-main">Federalism</span> Political concept

Federalism is a mode of government that combines a general level of government with a regional level of sub-unit governments, while dividing the powers of governing between the two levels of governments.

In physics, statistical mechanics is a mathematical framework that applies statistical methods and probability theory to large assemblies of microscopic entities. Sometimes called statistical physics or statistical thermodynamics, its applications include many problems in the fields of physics, biology, chemistry, neuroscience, computer science, information theory and sociology. Its main purpose is to clarify the properties of matter in aggregate, in terms of physical laws governing atomic motion.

<span class="mw-page-title-main">Thermodynamics</span> Physics of heat, work, and temperature

Thermodynamics deals with heat, work, and temperature, and their relation to energy, entropy, and the physical properties of matter and radiation. The behavior of these quantities is governed by the four laws of thermodynamics, which convey a quantitative description using measurable macroscopic physical quantities, but may be explained in terms of microscopic constituents by statistical mechanics. Thermodynamics plays a role in a wide variety of topics in science and engineering.

<span class="mw-page-title-main">Theoretical chemistry</span> Branch of chemistry

Theoretical chemistry is the branch of chemistry which develops theoretical generalizations that are part of the theoretical arsenal of modern chemistry: for example, the concepts of chemical bonding, chemical reaction, valence, the surface of potential energy, molecular orbitals, orbital interactions, and molecule activation.

Transition or transitional may refer to:

<span class="mw-page-title-main">Federation</span> Political union of partially self-governing territories under a national government

A federation is an entity characterized by a union of partially self-governing provinces, states, or other regions under a federal government (federalism). In a federation, the self-governing status of the component states, as well as the division of power between them and the central government, is constitutionally entrenched and may not be altered by a unilateral decision, neither by the component states nor the federal political body without constitutional amendment.

<span class="mw-page-title-main">Federated state</span> Territorial and constitutional community forming part of a federal union

A federated state is a territorial and constitutional community forming part of a federation. A federated state does not have international sovereignty since powers are divided between the other federated states and the federal government. Unlike international sovereign states, which have what is often referred to as Westphalian sovereignty, federated states operate under their domestic or federal law with relation to the rest of the world.

Thermodynamic equilibrium is an axiomatic concept of thermodynamics. It is an internal state of a single thermodynamic system, or a relation between several thermodynamic systems connected by more or less permeable or impermeable walls. In thermodynamic equilibrium, there are no net macroscopic flows of matter nor of energy within a system or between systems. In a system that is in its own state of internal thermodynamic equilibrium, not only is there an absence of macroscopic change, but there is an “absence of any tendency toward change on a macroscopic scale.”

<span class="mw-page-title-main">Thermodynamic system</span> Body of matter in a state of internal equilibrium

A thermodynamic system is a body of matter and/or radiation separate from its surroundings that can be studied using the laws of thermodynamics.

In thermodynamics, the particle number of a thermodynamic system is the number of constituent particles in that system. The particle number is a fundamental thermodynamic property which is conjugate to the chemical potential. Unlike most physical quantities, the particle number is a dimensionless quantity, specifically a countable quantity. It is an extensive property, as it is directly proportional to the size of the system under consideration and thus meaningful only for closed systems.

<span class="mw-page-title-main">Laws of thermodynamics</span> Observational basis of thermodynamics

The laws of thermodynamics are a set of scientific laws which define a group of physical quantities, such as temperature, energy, and entropy, that characterize thermodynamic systems in thermodynamic equilibrium. The laws also use various parameters for thermodynamic processes, such as thermodynamic work and heat, and establish relationships between them. They state empirical facts that form a basis of precluding the possibility of certain phenomena, such as perpetual motion. In addition to their use in thermodynamics, they are important fundamental laws of physics in general and are applicable in other natural sciences.

A state government is the government that controls a subdivision of a country in a federal form of government, which shares political power with the federal or national government. A state government may have some level of political autonomy, or be subject to the direct control of the federal government. This relationship may be defined by a constitution.

A polity is a group of people with a collective identity, who are organized by some form of political institutionalized social relations, and have a capacity to mobilize resources.

A political union is a type of political entity which is composed of, or created from, smaller polities, or the process which achieves this. These smaller polities are usually called federated states and federal territories in a federal government; and prefectures, regions, or provinces in the case of a centralised government. This form of government may be created through voluntary and mutual cession and is described as unionism by its constituent members and proponents. In other cases, it may arise from political unification, characterised by coercion and conquest. The unification of separate states which, in the past, had together constituted a single entity is known as reunification. Unlike a personal union or real union, the individual constituent entities may have devolution of powers but are subordinate to a central government or coordinated in some sort of organization. In a federalised system, the constituent entities usually have internal autonomy, for example in the setup of police departments, and share power with the federal government, for whom external sovereignty, military forces, and foreign affairs are usually reserved. The union is recognised internationally as a single political entity. A political union may also be called a legislative union or state union. A union may be effected in many forms, broadly categorized as:

The King-in-Council or the Queen-in-Council, depending on the gender of the reigning monarch, is a constitutional term in a number of states. In a general sense, it refers to the monarch exercising executive authority, usually in the form of approving orders, on the advice of the country's privy council or executive council.

Plasma or plasm may refer to:

A federacy is a form of government where one or several substate units enjoy considerably more independence than the majority of the substate units. To some extent, such an arrangement can be considered to be similar to asymmetric federalism.

In thermodynamics, the interpretation of entropy as a measure of energy dispersal has been exercised against the background of the traditional view, introduced by Ludwig Boltzmann, of entropy as a quantitative measure of disorder. The energy dispersal approach avoids the ambiguous term 'disorder'. An early advocate of the energy dispersal conception was Edward A. Guggenheim in 1949, using the word 'spread'.

<span class="mw-page-title-main">Temperature</span> Physical quantity of hot and cold

Temperature is a physical quantity that quantitatively expresses the attribute of hotness or coldness. Temperature is measured with a thermometer. It reflects the average kinetic energy of the vibrating and colliding atoms making up a substance.

<span class="mw-page-title-main">Law of Guernsey</span>

The Law of Guernsey originates in Norman customary law, overlaid with principles taken from English common law and French law, as well as from statute law enacted by the competent legislature(s) – usually, but not always, the States of Guernsey.