Supercritical carbon dioxide blend

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Carbon dioxide phase diagram Carbon dioxide pressure-temperature phase diagram international.svg
Carbon dioxide phase diagram

Supercritical carbon dioxide blend (sCO2 blend) is an homogeneous mixture of CO2 with one or more fluids (dopant fluid) where it is held at or above its critical temperature and critical pressure. [1]

Contents

Carbon dioxide behaves as a supercritical fluid above its critical temperature (304.13 K, 31.0 °C, 87.8 °F) and critical pressure (7.3773 MPa, 72.8 atm, 1,070 psi, 73.8 bar), expanding to fill its container like a gas but with a density like that of a liquid. [2]

By combining CO2 with other fluids, the critical temperature and critical pressure of the mixture can be modified. The s-CO2 blend is usually designed to increase the mixture supercritical temperature to employ the s-CO2 in power cycles, obtaining increased energy conversion efficiency. [3]

Applications

Power generation

Steam turbine Westinghouse steam turbine 03.jpg
Steam turbine

Despite the development of new electricity generation technologies, most power plants are thermal power stations, meaning that they use a heat source (solar thermal, nuclear power, fossil fuel, biomass, Incineration, geothermal) to produce electricity. Although this process can be achieved directly by using the seebeck effect, the power conversion efficiency is greatly increased by using a power cycle. Traditionally, power plants are based on Rankine cycle and use steam turbines for electricity generation. The efficiency of the power cycle is limited by the temperature difference between the heat source and the heat sink. The greater the differential, the more electricity can be produced. Replacing steam by supercritical carbon dioxide allows reaching a higher temperature differential, therefore increasing the power efficiency of the power plant. [3]

Supercritical state facilitates the heat exchange at the heat source. Furthermore, supercritical carbon dioxide is twice as dense as steam, and the combination of high density and volumetric heat makes it a high energy dense fluid, meaning that the size of most components of the thermodynamic cycle can be reduced. Therefore, the ecological footprint of the plant and the capital expenditure are considerably reduced. In addition, sCO2 is non-flammable, non-toxic, non-explosive and cheap. [4] Efficiency can be further increased employing a combined cycle. [5]

One of the main limitations that has delayed the massive use of carbon dioxide in power cycles is the corrosion engineering. Materials for the fluid transport and power generation must display high resistance to high temperature, corrosion and creep.

Concentrated Solar Power

Solucar PS 10, the first commercial solar power tower plant. It is located in Sanlucar la Mayor, Seville, Spain. PS10 solar power tower 2.jpg
Solúcar PS 10, the first commercial solar power tower plant. It is located in Sanlúcar la Mayor, Seville, Spain.

Concentrated solar power (CSP) is a solar thermal technology that uses mirrors or lenses to concentrate sunlight into a receiver. [6] The receiver reaches very high temperatures, up to 1000 °C for commercial solar power towers, favouring high power conversion efficiency. However, electricity production is limited by the heat engine used. [3]

In the Concentrated Solar Power sector, using supercritical CO2 as the heating engine fluid can provide a significant cost reduction. The higher efficiency of the power block reduces the solar field size, decreasing the soil occupation and therefore the cost of this part of the plant. According to the available analyses, electricity production costs of conventional supercritical CO2 CSP are expected to be 9,5–10 $ cent/KWh in favorable conditions. [7] In addition, Concentrated Solar Power offers the possibility of directly recovering solar radiation without using any intermediate energy carrier. However, this poses challenges in the design of high pressure solar receivers, that must held pressures above the critical pressure of the fluid, as well as energy storage systems. [8]

Efficient supercritical CO2 power cycles requires that the compressor inlet temperature is close to, or even lower than, the critical temperature of the fluid (31 °C for pure carbon dioxide). When this target is reached, and the heat source is higher than 600–650 °C, then the sCO2 cycle outperforms any Rankine cycle running on water/steam with the same boundary conditions. [9]

Because of the weather conditions in arid sites where Concentrated Solar Power plants are usually located, with ambient temperatures above 35 °C, it is impossible to cool down CO2 enough to compress the fluid with low energy requirements. Accordingly, the rapid transition to an almost ideal behavior of carbon dioxide when temperature increases to 40 °C or above increases compression work and reduces the thermal efficiency of the power block, which can only be increased again through a large increase of turbine inlet temperature. To overcome these thermodynamic problems, a supercritical CO2 blend with a higher critical temperature could be employed. [10] The critical temperature of several sCO2 blends has been studied. For example, a mixture that reaches a critical temperature of 80 °C can provide high efficiency for heat sink temperatures up to 50 °C. [9]

Properties of different sCO2 blends. [10]
Dopant fluid (%molar)Molar weight (g/mol)Critical temperature (°C)Critical pressure (bar)
C6F6 (10)58.2180.28112.4
C6F6 (15)65.32102.1121.3
C6F6 (20)72.42121.9123.6
TiCl4 (15)65.8693.76190.9
TiCl4 (20)73.15149.6243.7

SCARABEUS project, which has received funding from the European Union, formulates a new conceptual approach to implement supercritical carbon dioxide blends in Concentrated Solar Power Plants to reduce operating and capital costs by increasing the power cycle efficiency. The SCARABEUS project is developed by a consortium of European universities ( Politecnico di Milano and Università degli Studi di Brescia from Italy, Technische Universität Wien from Austria, Universidad de Sevilla from Spain and University of London from United Kingdom) and private companies(Kelvion from Germany, Baker Hughes from United States and Abengoa from Spain) with experience in Concentrated Solar Power. [11] [12]

See also

Supercritical carbon dioxide

Concentrated solar power

Electricity generation

Thermodynamic cycle

Rankine cycle

Steam turbine

Carbon dioxide

Related Research Articles

<span class="mw-page-title-main">Electricity generation</span> Process of generating electrical power

Electricity generation is the process of generating electric power from sources of primary energy. For utilities in the electric power industry, it is the stage prior to its delivery to end users or its storage.

<span class="mw-page-title-main">Heat engine</span> System that converts heat or thermal energy to mechanical work

A heat engine is a system that converts heat to usable energy, particularly mechanical energy, which can then be used to do mechanical work. While originally conceived in the context of mechanical energy, the concept of the heat engine has been applied to various other kinds of energy, particularly electrical, since at least the late 19th century. The heat engine does this by bringing a working substance from a higher state temperature to a lower state temperature. A heat source generates thermal energy that brings the working substance to the higher temperature state. The working substance generates work in the working body of the engine while transferring heat to the colder sink until it reaches a lower temperature state. During this process some of the thermal energy is converted into work by exploiting the properties of the working substance. The working substance can be any system with a non-zero heat capacity, but it usually is a gas or liquid. During this process, some heat is normally lost to the surroundings and is not converted to work. Also, some energy is unusable because of friction and drag.

<span class="mw-page-title-main">Solar thermal energy</span> Technology using sunlight for heat

Solar thermal energy (STE) is a form of energy and a technology for harnessing solar energy to generate thermal energy for use in industry, and in the residential and commercial sectors.

<span class="mw-page-title-main">Combined cycle power plant</span> Assembly of heat engines that work in tandem from the same source of heat

A combined cycle power plant is an assembly of heat engines that work in tandem from the same source of heat, converting it into mechanical energy. On land, when used to make electricity the most common type is called a combined cycle gas turbine (CCGT) plant. The same principle is also used for marine propulsion, where it is called a combined gas and steam (COGAS) plant. Combining two or more thermodynamic cycles improves overall efficiency, which reduces fuel costs.

<span class="mw-page-title-main">Rankine cycle</span> Model that is used to predict the performance of steam turbine systems

The Rankine cycle is an idealized thermodynamic cycle describing the process by which certain heat engines, such as steam turbines or reciprocating steam engines, allow mechanical work to be extracted from a fluid as it moves between a heat source and heat sink. The Rankine cycle is named after William John Macquorn Rankine, a Scottish polymath professor at Glasgow University.

A supercritical fluid (SCF) is any substance at a temperature and pressure above its critical point, where distinct liquid and gas phases do not exist, but below the pressure required to compress it into a solid. It can effuse through porous solids like a gas, overcoming the mass transfer limitations that slow liquid transport through such materials. SCF are superior to gases in their ability to dissolve materials like liquids or solids. Also, near the critical point, small changes in pressure or temperature result in large changes in density, allowing many properties of a supercritical fluid to be "fine-tuned".

<span class="mw-page-title-main">Fossil fuel power station</span> Facility that burns fossil fuels to produce electricity

A fossil fuel power station is a thermal power station which burns a fossil fuel, such as coal or natural gas, to produce electricity. Fossil fuel power stations have machinery to convert the heat energy of combustion into mechanical energy, which then operates an electrical generator. The prime mover may be a steam turbine, a gas turbine or, in small plants, a reciprocating gas engine. All plants use the energy extracted from the expansion of a hot gas, either steam or combustion gases. Although different energy conversion methods exist, all thermal power station conversion methods have their efficiency limited by the Carnot efficiency and therefore produce waste heat.

Supercritical fluid extraction (SFE) is the process of separating one component (the extractant) from another (the matrix) using supercritical fluids as the extracting solvent. Extraction is usually from a solid matrix, but can also be from liquids. SFE can be used as a sample preparation step for analytical purposes, or on a larger scale to either strip unwanted material from a product (e.g. decaffeination) or collect a desired product (e.g. essential oils). These essential oils can include limonene and other straight solvents. Carbon dioxide (CO2) is the most used supercritical fluid, sometimes modified by co-solvents such as ethanol or methanol. Extraction conditions for supercritical carbon dioxide are above the critical temperature of 31 °C and critical pressure of 74 bar. Addition of modifiers may slightly alter this. The discussion below will mainly refer to extraction with CO2, except where specified.

<span class="mw-page-title-main">Thermal power station</span> Power plant that generates electricity from heat energy

A thermal power station is a type of power station in which heat energy is converted to electrical energy. In a steam-generating cycle heat is used to boil water in a large pressure vessel to produce high-pressure steam, which drives a steam turbine connected to an electrical generator. The low-pressure exhaust from the turbine enters a steam condenser where it is cooled to produce hot condensate which is recycled to the heating process to generate more high pressure steam. This is known as a Rankine cycle.

<span class="mw-page-title-main">Supercritical water reactor</span> Concept nuclear reactor whose water operates at supercritical pressure

The supercritical water reactor (SCWR) is a concept Generation IV reactor, designed as a light water reactor (LWR) that operates at supercritical pressure. The term critical in this context refers to the critical point of water, and should not be confused with the concept of criticality of the nuclear reactor.

<span class="mw-page-title-main">Supercritical carbon dioxide</span> Carbon dioxide above its critical point

Supercritical carbon dioxide is a fluid state of carbon dioxide where it is held at or above its critical temperature and critical pressure.

<span class="mw-page-title-main">Steam-electric power station</span>

The steam-electric power station is a power station in which the electric generator is steam driven. Water is heated, turns into steam and spins a steam turbine which drives an electrical generator. After it passes through the turbine, the steam is condensed in a condenser. The greatest variation in the design of steam-electric power plants is due to the different fuel sources.

<span class="mw-page-title-main">Transcritical cycle</span> Closed thermodynamic cycle involving fluid

A transcritical cycle is a closed thermodynamic cycle where the working fluid goes through both subcritical and supercritical states. In particular, for power cycles the working fluid is kept in the liquid region during the compression phase and in vapour and/or supercritical conditions during the expansion phase. The ultrasupercritical steam Rankine cycle represents a widespread transcritical cycle in the electricity generation field from fossil fuels, where water is used as working fluid. Other typical applications of transcritical cycles to the purpose of power generation are represented by organic Rankine cycles, which are especially suitable to exploit low temperature heat sources, such as geothermal energy, heat recovery applications or waste to energy plants. With respect to subcritical cycles, the transcritical cycle exploits by definition higher pressure ratios, a feature that ultimately yields higher efficiencies for the majority of the working fluids. Considering then also supercritical cycles as a valid alternative to the transcritical ones, the latter cycles are capable of achieving higher specific works due to the limited relative importance of the work of compression work. This evidences the extreme potential of transcritical cycles to the purpose of producing the most power with the least expenditure.

<span class="mw-page-title-main">Organic Rankine cycle</span> Variation on the Rankine thermodynamic cycle

In thermal engineering, the organic Rankine cycle (ORC) is a type of thermodynamic cycle. It is a variation of the Rankine cycle named for its use of an organic, high-molecular-mass fluid whose vaporization temperature is lower than that of water. The fluid allows heat recovery from lower-temperature sources such as biomass combustion, industrial waste heat, geothermal heat, solar ponds etc. The low-temperature heat is converted into useful work, that can itself be converted into electricity.

<span class="mw-page-title-main">Concentrated solar power</span> Use of mirror or lens assemblies to heat a working fluid for electricity generation

Concentrated solar power systems generate solar power by using mirrors or lenses to concentrate a large area of sunlight into a receiver. Electricity is generated when the concentrated light is converted to heat, which drives a heat engine connected to an electrical power generator or powers a thermochemical reaction.

<span class="mw-page-title-main">Mojave Solar Project</span>

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<span class="mw-page-title-main">Hygroscopic cycle</span> Thermodynamic cycle converting thermal energy into mechanical power

The Hygroscopic cycle is a thermodynamic cycle converting thermal energy into mechanical power by the means of a steam turbine. It is similar to the Rankine cycle using water as the motive fluid but with the novelty of introducing salts and their hygroscopic properties for the condensation. The salts are desorbed in the boiler or steam generator, where clean steam is released and superheated in order to be expanded and generate power through the steam turbine. Boiler blowdown with the concentrated hygroscopic compounds is used thermally to pre-heat the steam turbine condensate, and as reflux in the steam-absorber.

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<span class="mw-page-title-main">Non ideal compressible fluid dynamics</span>

Non ideal compressible fluid dynamics (NICFD), or non ideal gas dynamics, is a branch of fluid mechanics studying the dynamic behavior of fluids not obeying ideal-gas thermodynamics. It is for example the case of dense vapors, supercritical flows and compressible two-phase flows. With the term dense vapors, we indicate all fluids in the gaseous state characterized by thermodynamic conditions close to saturation and the critical point. Supercritical fluids feature instead values of pressure and temperature larger than their critical values, whereas two-phase flows are characterized by the simultaneous presence of both liquid and gas phases.

The Allam Cycle or Allam-Fetvedt Cycle is a process for converting carbonaceous fuels into thermal energy, while capturing the generated carbon dioxide and water. This zero emissions cycle was validated at a 50 MWth natural gas fed test facility in La Porte, Texas in May 2018. This industrial plant is owned and operated by NET Power LLC, a privately held technology licensing company. NET Power is owned by Constellation Energy Corporation, Occidental Petroleum Corporation (Oxy) Low Carbon Ventures, Baker Hughes Company and 8 Rivers Capital, the company holding the patents for the technology. The key inventors behind the process are English engineer Rodney John Allam, American engineer Jeremy Eron Fetvedt, American scientist Dr. Miles R Palmer, and American businessperson and innovator G. William Brown, Jr. The Allam-Fetvedt Cycle was recognized by MIT Technology Review on the 2018 list of 10 Breakthrough Technologies.

References

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  5. "Combined cycles – techouse". Archived from the original on December 15, 2022. Retrieved December 15, 2022.
  6. Kraemer, Susan (June 11, 2018). "How CSP Works: Tower, Trough, Fresnel or Dish". SolarPACES. Retrieved December 7, 2022.
  7. María, Sánchez Martínez, David Tomás Sánchez Lencero, Tomás Manuel Universidad de Sevilla. Departamento de Ingeniería Energética Crespi, Francesco (February 11, 2020). Thermo-economic assessment of supercritical CO2 power cycles for concentrated solar power plants. OCLC   1240072375.{{cite book}}: CS1 maint: multiple names: authors list (link)
  8. Marchionni, Matteo; Bianchi, Giuseppe; Tassou, Savvas A. (March 11, 2020). "Review of supercritical carbon dioxide (sCO2) technologies for high-grade waste heat to power conversion". SN Applied Sciences. 2 (4): 611. doi: 10.1007/s42452-020-2116-6 . hdl: 11584/361939 . ISSN   2523-3971. S2CID   216291655.
  9. 1 2 Crespi, Francesco; Sánchez, David; Martínez, Gonzalo S.; Sánchez-Lencero, Tomás; Jiménez-Espadafor, Francisco (July 22, 2020). "Potential of Supercritical Carbon Dioxide Power Cycles to Reduce the Levelised Cost of Electricity of Contemporary Concentrated Solar Power Plants". Applied Sciences. 10 (15): 5049. doi: 10.3390/app10155049 . ISSN   2076-3417.
  10. 1 2 F. Crespi, G. S. Martínez, P. Rodriguez de Arriba, D. Sánchez, F. Jiménez-Espadafor (2021). "Influence of Working Fluid Composition on the Optimum Characteristics of Blended Supercritical Carbon Dioxide Cycles". Volume 10: Supercritical CO2. ASME Turbo Expo 2021: Turbomachinery Technical Conference and Exposition. doi:10.1115/gt2021-60293. ISBN   978-0-7918-8504-8. S2CID   239400871 . Retrieved December 15, 2022.{{cite book}}: |website= ignored (help)CS1 maint: location (link) CS1 maint: location missing publisher (link) CS1 maint: multiple names: authors list (link)
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