Tetravinyltin

Last updated
Tetravinyltin
Tetravinyltin.png
Names
IUPAC name
tetrakis(ethenyl)stannane
Other names
tetravinylstannane
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.012.903 OOjs UI icon edit-ltr-progressive.svg
EC Number
  • 214-193-6
PubChem CID
  • InChI=1S/4C2H3.Sn/c4*1-2;/h4*1H,2H2;
    Key: MZIYQMVHASXABC-UHFFFAOYSA-N
  • C=C[Sn](C=C)(C=C)C=C
Properties
C8H12Sn
Molar mass 226.894 g·mol−1
AppearanceColorless liquid
Density 1.246 g/mL
Boiling point 160–163 °C (320–325 °F; 433–436 K)
Hazards
Occupational safety and health (OHS/OSH):
Main hazards
Flammable, Toxic
GHS labelling:
GHS-pictogram-flamme.svg GHS-pictogram-skull.svg
Danger
H226, H301, H311, H331
P210, P233, P240, P241, P242, P243, P261, P264, P270, P271, P280, P301+P310, P302+P352, P303+P361+P353, P304+P340, P311, P312, P321, P322, P330, P361, P363, P370+P378, P403+P233, P403+P235, P405, P501
Flash point 105 °F
Safety data sheet (SDS)
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Tetravinyltin (also known as tetravinylstannane) is an organotin compound with a chemical formula of C8H12Sn. [1]

Contents

Uses

Upon heating, a mixture of tetravinyltin and tin tetrachloride undergo disproportionation to form divinyltin dichloride, vinyltin trichloride, and trivinyltin chloride in high yields. [2] A study about this can be found in the Journal of American Chemical Society. [3]

Tetravinyltin cannot be used for therapeutic or diagnostic purposes and must only be used for research. [4] It can also be used for thin film deposition. [5]

Hazards

According to the European Chemicals Agency, tetravinyltin is flammable in liquid and gas form. It is also toxic when in contact with skin, inhaled, and swallowed. [6] Therefore, personal protective equipment must be used in handling and proper caution applied during use.

References

  1. ↑ PubChem. "Tetravinyltin". pubchem.ncbi.nlm.nih.gov. Retrieved 2021-04-21.
  2. ↑ "Tetravinyltin | Tetravinylstannane | Sn(CH=CH2)4". Ereztech. Retrieved 2021-04-21.
  3. ↑ Rosenberg, Sanders D.; Gibbons, Ambrose J. (1957-05-01). "The Disproportionation of Tetravinyltin with Tin Tetrachloride and the Cleavage of Some Vinyltin Compounds with Bromine" . Journal of the American Chemical Society. 79 (9): 2138–2140. doi:10.1021/ja01566a029. ISSN   0002-7863.
  4. ↑ "Tetravinyltin | CAS 1112-56-7". www.scbt.com. Retrieved 2021-04-21.
  5. ↑ Elements, American. "Tetravinyltin". American Elements. Retrieved 2021-04-21.
  6. ↑ "Tetravinylstannane - Substance Information - ECHA". echa.europa.eu. Retrieved 2021-04-21.
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