Trimethylolpropane triacrylate

Last updated
Trimethylolpropane triacrylate
Trimethylolpropane triacrylate.svg
Names
Preferred IUPAC name
2-Ethyl-2-{[(prop-2-enoyl)oxy]methyl}propane-1,3-diyl di(prop-2-enoate)
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.036.077 OOjs UI icon edit-ltr-progressive.svg
PubChem CID
UNII
  • InChI=1S/C15H20O6/c1-5-12(16)19-9-15(8-4,10-20-13(17)6-2)11-21-14(18)7-3/h5-7H,1-3,8-11H2,4H3
    Key: DAKWPKUUDNSNPN-UHFFFAOYSA-N
  • InChI=1/C15H20O6/c1-5-12(16)19-9-15(8-4,10-20-13(17)6-2)11-21-14(18)7-3/h5-7H,1-3,8-11H2,4H3
    Key: DAKWPKUUDNSNPN-UHFFFAOYAU
  • CCC(COC(=O)C=C)(COC(=O)C=C)COC(=O)C=C
Properties
C15H20O6
Molar mass 296.319 g·mol−1
Density 1.06
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Trimethylolpropane triacrylate (TMPTA) is a trifunctional acrylate ester monomer derived from trimethylolpropane, used in the manufacture of plastics, adhesives, acrylic glue, anaerobic sealants, and ink. It is useful for its low volatility and fast cure response. It has the properties of weather, chemical and water resistance, as well as good abrasion resistance. End products include alkyd coatings, [1] compact discs, hardwood floors, concrete and cementitious applications, [2] [3] [4] Dental composites, photolithography, letterpress, screen printing, elastomers, automobile headlamps, acrylics and plastic components for the medical industry.

Contents

Other uses

As the molecule has acrylic functionality, it is capable of doing the Michael reaction with an amine. This allows its use in epoxy chemistry where its use speeds up the cure time considerably [5] [6]

See also

Related Research Articles

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<span class="mw-page-title-main">Trimethylolpropane triglycidyl ether</span> Chemical compound

Trimethylolpropane triglycidyl ether (TMPTGE) is an organic chemical in the glycidyl ether family. It has the formula C15H26O6 and the IUPAC name is 2-[2,2-bis(oxiran-2-ylmethoxymethyl)butoxymethyl]oxirane, and the CAS number 3454-29-3. It also has another CAS number of 30499-70-8 A key use is as a modifier for epoxy resins as a reactive diluent.

<span class="mw-page-title-main">Trimethylolethane triglycidyl ether</span> Chemical compound

Trimethylolethane triglycidyl ether (TMETGE) is an organic chemical in the glycidyl ether family. It has the formula C14H24O6 and the IUPAC name is 2-({2-methyl-3-[(oxiran-2-yl)methoxy]-2-{[(oxiran-2-yl)methoxy]methyl}propoxy}methyl)oxirane. The CAS number is 68460-21-9. A key use is as a modifier for epoxy resins as a reactive diluent.

<span class="mw-page-title-main">Hydroxyethyl acrylate</span> Organic chemical-monomer

Hydroxyethyl acrylate is an organic chemical and a aliphatic compound. It has the formula C5H8O3 and the CAS Registry Number 818-61-1. It is REACH registered with an EU number of 212-454-9. It has dual functionality containing a polymerizable acrylic group and a terminal hydroxy group. It is used to make emulsion polymers along with other monomers and the resultant resins are used in coatings, sealants, adhesives and elastomers and other applications.

References

  1. Wang, Qianhe (January 2019). "PhD Dissertation Acrylated Alkyds". University of Akron.
  2. Rengaraju, Sripriya; Al-Tabbaa, Abir (2023). "Life Cycle Assessment (LCA) of Microcapsule based self-healing in concrete". MATEC Web of Conferences. 378: 06004. doi: 10.1051/matecconf/202337806004 . ISSN   2261-236X.
  3. Lin, Xiuju; Liao, Bing; Zhang, Jingfei; Li, Simin; Huang, Jianheng; Pang, Hao (2019-06-20). "Synthesis and characterization of high-performance cross-linked polycarboxylate superplasticizers". Construction and Building Materials. 210: 162–171. doi:10.1016/j.conbuildmat.2019.03.185. ISSN   0950-0618.
  4. Ma, Yihan; Lei, Lei; Sha, Shengnan; Liu, Yi; Shi, Caijun (2023-06-01). "Synthesis of a cross-linked polycarboxylate ether superplasticizer and its effects on the properties of cement paste containing montmorillonite". Cement and Concrete Research. 168: 107136. doi:10.1016/j.cemconres.2023.107136. ISSN   0008-8846.
  5. "Epoxy Polyacrylate Resins". www.hexion.com. Retrieved 2020-02-12.
  6. "Low Viscosity, Fast Curing Epoxy Acrylate Oligomers". www.pcimag.com. Retrieved 2020-02-12.