Ultra-high-pressure metamorphism refers to metamorphic processes at pressures high enough to stabilize coesite, the high-pressure polymorph of SiO2. It is important because the processes that form and exhume ultra-high-pressure (UHP) metamorphic rocks may strongly affect plate tectonics, the composition and evolution of Earth's crust. The discovery of UHP metamorphic rocks in 1984 [1] [2] revolutionized our understanding of plate tectonics. Prior to 1984 there was little suspicion that continental rocks could reach such high pressures.
The formation of many UHP terrains has been attributed to the subduction of microcontinents or continental margins and the exhumation of all UHP terrains has been ascribed principally to buoyancy caused by the low density of continental crust—even at UHP—relative to Earth's mantle. While the subduction proceeds at low thermal gradients of less than 10°C/km, the exhumation proceeds at elevated thermal gradients of 10-30°C/km.
Metamorphism of rocks at pressures ≥27kbar (2.7GPa) to stabilize coesite, the high-pressure polymorph of SiO2, recognized by either the presence of a diagnostic mineral (e.g., coesite or diamond [3] ), mineral assemblage (e.g., magnesite + aragonite [4] ), or mineral compositions.
Petrological indicators of UHP metamorphism are usually preserved in eclogite. The presence of metamorphic coesite, diamond, or majoritic garnet are diagnostic; other potential mineralogical indicators of UHP metamorphism, such as alpha-PbO2 structured TiO2, are not widely accepted. Mineral assemblages, rather than single minerals, can also be used to identify UHP rocks; these assemblages include magnesite + aragonite. [4] Because minerals change composition in response to changes in pressure and temperature, mineral compositions can be used to calculate pressure and temperature; for UHP eclogite the best geobarometers involve garnet + clinopyroxene + K-white mica and garnet + clinopyroxene + kyanite + coesite/quartz. [5] Most UHP rocks were metamorphosed at peak conditions of 800 °C and 3 GPa. [6] At least two UHP localities record higher temperatures: the Bohemian and Kokchetav Massifs reached 1000–1200 °C at pressures of at least 4 GPa. [7] [8] [9]
Most felsic UHP rocks have undergone extensive retrograde metamorphism and preserve little or no UHP record. Commonly, only a few eclogite enclaves or UHP minerals reveal that the entire terrain was subducted to mantle depths. Many granulite terrains and even batholithic rocks may have undergone UHP metamorphism that was subsequently obliterated [10] [11]
Geologists have identified UHP terrains at more than twenty localities around the globe in most well-studied Phanerozoic continental orogenic belts; most occur in Eurasia. [12] Coesite is relatively widespread, diamond less so, and majoritic garnet is known from only rare localities. The oldest UHP terrain is 620 Ma and is exposed in Mali; [13] the youngest is 8 Ma and exposed in the D'Entrecasteaux Islands of Papua New Guinea. [14] A modest number of continental orogens have undergone multiple UHP episodes. [15]
UHP terrains vary greatly in size, from the >30,000 km2 giant UHP terrains in Norway and China, to small kilometer-scale bodies. [16] The giant UHP terrains have a metamorphic history spanning tens of millions of years, whereas the small UHP terrains have a metamorphic history spanning millions of years. [17] All are dominated by quartzofeldspathic gneiss with a few percent mafic rock (eclogite) or ultramafic rock (garnet-bearing peridotite). Some include sedimentary or rift-volcanic sequences that have been interpreted as passive margins prior to metamorphism. [18] [19]
UHP rocks record pressures greater than those that prevail within Earth's crust. Earth's crust is a maximum of 70–80 km thickness, and pressures at the base are <2.7 GPa for typical crustal densities. UHP rocks therefore come from depths within Earth's mantle. UHP rocks of a wide variety of compositions have been identified as both regional metamorphic terrains and xenoliths.
UHP ultramafic xenoliths of mantle affinity provide information (e.g., mineralogy or deformation mechanisms) about processes active deep in Earth. UHP xenoliths of crustal affinity provide information about processes active deep in Earth, but also information about what kinds of crustal rocks reach great depth in Earth and how profound those depths are.
Regional metamorphic UHP terrains exposed on Earth's surface provide considerable information that is not available from xenoliths. Integrated study by structural geologists, petrologists, and geochronologists has provided considerable data on how the rocks deformed, the pressures and temperatures of metamorphism, and how the deformation and metamorphism varied as a function of space and time. It has been postulated that small UHP terrains that underwent short periods of metamorphism formed early during continent subduction, whereas giant UHP terrains that underwent long periods of metamorphism formed late during continent collision. [17]
Eclogite-facies HP to UHP metamorphic rocks are produced by subduction of crustal rocks to the lower crust to mantle depths for extreme metamorphism at the low thermal gradients of less than 10°C/km. [20] All of these rocks occur at convergent plate margins, and UHP rocks only occur in collisional orogens. There is general agreement that most well-exposed and well-studied UHP terrains were produced by the burial of crustal rocks to mantle depths of >80 km during subduction. Continental margin subduction is well documented in a number of collisional orogens, such as the Dabie orogen where South China Block passive-margin sedimentary and volcanic sequences are preserved, [21] in the Arabian continental margin beneath the Samail ophiolite (in the Al Hajar Mountains, Oman), [22] and in the Australian margin presently subducting beneath the Banda Arc. [23] Sediment subduction occurs beneath volcanoplutonic arcs around the world [24] and is recognized in the compositions of arc lavas. [25] Continental subduction may be underway beneath the Pamir. [26] Subduction erosion also occurs beneath volcanoplutonic arcs around the world, [24] carrying continental rocks to mantle depths at least locally. [27]
The specific processes by which UHP terrains were exhumed to Earth's surface appear to have been different in different locations.
If continental lithosphere is subducted because of its attachment to downgoing oceanic lithosphere, the downward slab pull force may exceed the strength of the slab at some time and location, and necking of the slab initiates. [28] The positive buoyancy of the continental slab—in opposition principally to ridge push—can then drive exhumation of the subducting crust at a rate and mode determined by plate geometry and the rheology of the crustal materials. The Norwegian Western Gneiss Region is the archetype for this exhumation mode, which has been termed 'eduction' or subduction inversion. [29]
If a plate undergoing subduction inversion begins to rotate in response to changing boundary conditions or body forces, the rotation may exhume UHP rocks toward crustal levels. This could occur if, for example, the plate is small enough that continental subduction markedly changes the orientation and magnitude of slab pull or if the plate is being consumed by more than one subduction zone pulling in different directions. [30] Such a model has also been proposed for the UHP terrain in eastern Papua New Guinea, where rotation of the Woodlark microplate is causing a rift in the Woodlark Basin). [31]
If a subducting plate consists of a weak buoyant layer atop a stronger negatively buoyant layer, the former will detach at the depth where the buoyancy force exceeds slab pull, and extrude upward as a semi-coherent sheet. This type of delamination and stacking was proposed to explain exhumation of UHP rocks in the Dora Maira massif in Piedmont, Italy, [32] in the Dabie orogen, [33] and in the Himalaya. [34] In addition it was demonstrated with analogue experiments. [35] This mechanism is different from flow in a subduction channel in that the exhuming sheet is strong and remains undeformed. A variant of this mechanism, in which the exhuming material undergoes folding, but not wholescale disruption, was suggested for the Dabie orogen, where exhumation-related stretching lineations and gradients in metamorphic pressure indicate rotation of the exhuming block; [36]
The buoyancy of a microcontinent locally slows the rollback of and steepens the dip of subducting mafic lithosphere. [37] If the mafic lithosphere on either side of the microcontinent continues to roll back, a buoyant portion of the microcontinent may detach, allowing the retarded portion of the mafic slab to roll quickly back, making room for the UHP continental crust to exhume and driving back-arc extension. This model was developed to explain repeated cycles of subduction and exhumation documented in the Aegean and Calabria–Apennine orogens. UHP exhumation by slab rollback has not yet been extensively explored numerically, but it has been reproduced in numerical experiments of Apennine-style collisions. [38]
If continental material is subducted within a confined channel, the material tends to undergo circulation driven by tractions along the base of the channel and the relative buoyancy of rocks inside the channel; [39] the flow can be complex, generating nappe-like or chaotically mixed bodies. [40] [41] [42] [43] [44] [45] The material within the channel can be exhumed if: [41] [42]
Buoyancy alone is unlikely to drive exhumation of UHP rocks to Earth's surface, except in oceanic subduction zones. [46] Arrest and spreading of UHP rocks at the Moho (if the overlying plate is continental) is likely unless other forces are available to force the UHP rocks upward. [11] Some UHP terrains might be coalesced material derived from subduction erosion. [47] [48] This model was suggested to explain the North Qaidam UHP terrain in western China. [49] Even subducted sediment may rise as diapirs from the subducting plate and accumulate to form UHP terrains. [50] [51]
Studies of numerical geodynamics suggest that both subducted sediment and crystalline rocks may rise through the mantle wedge diapirically to form UHP terranes. [47] [49] [50] Diapiric rise of a much larger subducted continental body has been invoked to explain the exhumation of the Papua New Guinea UHP terrain. [52] This mechanism was alo used to explain the exhumation of UHP rocks in Greenland. [53] However, the mantle wedge above continental subduction zones is cold like cratons, which do not allow for diapirically ascending of the crustal materials. Foundering of the gravitationally unstable portions of continental lithosphere locally carries quartzofeldspathic rocks into the mantle [54] and may be ongoing beneath the Pamir. [26]
Metamorphic rocks arise from the transformation of existing rock to new types of rock in a process called metamorphism. The original rock (protolith) is subjected to temperatures greater than 150 to 200 °C and, often, elevated pressure of 100 megapascals (1,000 bar) or more, causing profound physical or chemical changes. During this process, the rock remains mostly in the solid state, but gradually recrystallizes to a new texture or mineral composition. The protolith may be an igneous, sedimentary, or existing metamorphic rock.
Orogeny is a mountain-building process that takes place at a convergent plate margin when plate motion compresses the margin. An orogenic belt or orogen develops as the compressed plate crumples and is uplifted to form one or more mountain ranges. This involves a series of geological processes collectively called orogenesis. These include both structural deformation of existing continental crust and the creation of new continental crust through volcanism. Magma rising in the orogen carries less dense material upwards while leaving more dense material behind, resulting in compositional differentiation of Earth's lithosphere. A synorogenic process or event is one that occurs during an orogeny.
The Alps form part of a Cenozoic orogenic belt of mountain chains, called the Alpide belt, that stretches through southern Europe and Asia from the Atlantic all the way to the Himalayas. This belt of mountain chains was formed during the Alpine orogeny. A gap in these mountain chains in central Europe separates the Alps from the Carpathians to the east. Orogeny took place continuously and tectonic subsidence has produced the gaps in between.
Subduction is a geological process in which the oceanic lithosphere and some continental lithosphere is recycled into the Earth's mantle at convergent boundaries. Where the oceanic lithosphere of a tectonic plate converges with the less dense lithosphere of a second plate, the heavier plate dives beneath the second plate and sinks into the mantle. A region where this process occurs is known as a subduction zone, and its surface expression is known as an arc-trench complex. The process of subduction has created most of the Earth's continental crust. Rates of subduction are typically measured in centimeters per year, with rates of convergence as high as 11 cm/year.
A convergent boundary is an area on Earth where two or more lithospheric plates collide. One plate eventually slides beneath the other, a process known as subduction. The subduction zone can be defined by a plane where many earthquakes occur, called the Wadati–Benioff zone. These collisions happen on scales of millions to tens of millions of years and can lead to volcanism, earthquakes, orogenesis, destruction of lithosphere, and deformation. Convergent boundaries occur between oceanic-oceanic lithosphere, oceanic-continental lithosphere, and continental-continental lithosphere. The geologic features related to convergent boundaries vary depending on crust types.
Coesite is a form (polymorph) of silicon dioxide (SiO2) that is formed when very high pressure (2–3 gigapascals), and moderately high temperature (700 °C, 1,300 °F), are applied to quartz. Coesite was first synthesized by Loring Coes, Jr., a chemist at the Norton Company, in 1953.
Eclogite is a metamorphic rock containing garnet (almandine-pyrope) hosted in a matrix of sodium-rich pyroxene (omphacite). Accessory minerals include kyanite, rutile, quartz, lawsonite, coesite, amphibole, phengite, paragonite, zoisite, dolomite, corundum and, rarely, diamond. The chemistry of primary and accessory minerals is used to classify three types of eclogite. The broad range of eclogitic compositions has led to a longstanding debate on the origin of eclogite xenoliths as subducted, altered oceanic crust.
An orogenic belt, orogen, or mobile belt, is a zone of Earth's crust affected by orogeny. An orogenic belt develops when a continental plate crumples and is uplifted to form one or more mountain ranges; this involves a series of geological processes collectively called orogenesis.
In geology, continental collision is a phenomenon of plate tectonics that occurs at convergent boundaries. Continental collision is a variation on the fundamental process of subduction, whereby the subduction zone is destroyed, mountains produced, and two continents sutured together. Continental collision is only known to occur on Earth.
The rock cycle is a basic concept in geology that describes transitions through geologic time among the three main rock types: sedimentary, metamorphic, and igneous. Each rock type is altered when it is forced out of its equilibrium conditions. For example, an igneous rock such as basalt may break down and dissolve when exposed to the atmosphere, or melt as it is subducted under a continent. Due to the driving forces of the rock cycle, plate tectonics and the water cycle, rocks do not remain in equilibrium and change as they encounter new environments. The rock cycle explains how the three rock types are related to each other, and how processes change from one type to another over time. This cyclical aspect makes rock change a geologic cycle and, on planets containing life, a biogeochemical cycle.
The North China Craton is a continental crustal block with one of Earth's most complete and complex records of igneous, sedimentary and metamorphic processes. It is located in northeast China, Inner Mongolia, the Yellow Sea, and North Korea. The term craton designates this as a piece of continent that is stable, buoyant and rigid. Basic properties of the cratonic crust include being thick, relatively cold when compared to other regions, and low density. The North China Craton is an ancient craton, which experienced a long period of stability and fitted the definition of a craton well. However, the North China Craton later experienced destruction of some of its deeper parts (decratonization), which means that this piece of continent is no longer as stable.
In geology ultrahigh-temperature metamorphism (UHT) is extreme crustal metamorphism with metamorphic temperatures exceeding 900 °C. Granulite-facies rocks metamorphosed at very high temperatures were identified in the early 1980s, although it took another decade for the geoscience community to recognize UHT metamorphism as a common regional phenomenon. Petrological evidence based on characteristic mineral assemblages backed by experimental and thermodynamic relations demonstrated that Earth's crust can attain and withstand very high temperatures (900–1000 °C) with or without partial melting.
Eclogitization is the tectonic process in which the high-pressure, metamorphic facies, eclogite, is formed. This leads to an increase in the density of regions of Earth's crust, which leads to changes in plate motion at convergent boundaries.
High pressure terranes along the ~1200 km long east-west trending Bangong-Nujiang suture zone (BNS) on the Tibetan Plateau have been extensively mapped and studied. Understanding the geodynamic processes in which these terranes are created is key to understanding the development and subsequent deformation of the BNS and Eurasian deformation as a whole.
Paired metamorphic belts are sets of parallel linear rock units that display contrasting metamorphic mineral assemblages. These paired belts develop along convergent plate boundaries where subduction is active. Each pair consists of one belt with a low-temperature, high-pressure metamorphic mineral assemblage, and another characterized by high-temperature, low-pressure metamorphic minerals.
A subduction zone is a region of the Earth's crust where one tectonic plate moves under another tectonic plate; oceanic crust gets recycled back into the mantle and continental crust gets created by the formation of arc magmas. Arc magmas account for more than 20% of terrestrially produced magmas and are produced by the dehydration of minerals within the subducting slab as it descends into the mantle and are accreted onto the base of the overriding continental plate. Subduction zones host a unique variety of rock types created by the high-pressure, low-temperature conditions a subducting slab encounters during its descent. The metamorphic conditions the slab passes through in this process creates and destroys water bearing (hydrous) mineral phases, releasing water into the mantle. This water lowers the melting point of mantle rock, initiating melting. Understanding the timing and conditions in which these dehydration reactions occur, is key to interpreting mantle melting, volcanic arc magmatism, and the formation of continental crust.
In geology, the term exhumation refers to the process by which a parcel of rock, approaches Earth's surface.
The South China Craton or South China Block is one of the Precambrian continental blocks in China. It is traditionally divided into the Yangtze Block in the NW and the Cathaysia Block in the SE. The Jiangshan–Shaoxing Fault represents the suture boundary between the two sub-blocks. Recent study suggests that the South China Block possibly has one more sub-block which is named the Tolo Terrane. The oldest rocks in the South China Block occur within the Kongling Complex, which yields zircon U–Pb ages of 3.3–2.9 Ga.
Clare Warren is a British geologist who is Professor of Earth Sciences at the Open University. Her research considers metamorphic petrology and how deeply buried rocks record information about their burial and exhumation. She was awarded the Geological Society of London Dewey Medal in 2022.
The geology of the Kimberley, a region of Western Australia, is a rock record of the early Proterozoic eon that includes tectonic plate collision, mountain-building (orogeny) and the joining (suturing) of the Kimberley and Northern Australia cratons, followed by sedimentary basin formation.