Shale is a fine-grained, clastic sedimentary rock formed from mud that is a mix of flakes of clay minerals (hydrous aluminium phyllosilicates, e.g. kaolin, Al2Si2O5(OH)4) and tiny fragments (silt-sized particles) of other minerals, especially quartz and calcite. Shale is characterized by its tendency to split into thin layers (laminae) less than one centimeter in thickness. This property is called fissility. Shale is the most common sedimentary rock.
Oil shale is an organic-rich fine-grained sedimentary rock containing kerogen from which liquid hydrocarbons can be produced. In addition to kerogen, general composition of oil shales constitutes inorganic substance and bitumens. Based on their deposition environment, oil shales are classified as marine, lacustrine and terrestrial oil shales. Oil shales differ from oil-bearing shales, shale deposits that contain petroleum that is sometimes produced from drilled wells. Examples of oil-bearing shales are the Bakken Formation, Pierre Shale, Niobrara Formation, and Eagle Ford Formation. Accordingly, shale oil produced from oil shale should not be confused with tight oil, which is also frequently called shale oil.
Bituminous coal, or black coal, is a type of coal containing a tar-like substance called bitumen or asphalt. Its coloration can be black or sometimes dark brown; often there are well-defined bands of bright and dull material within the seams. It is typically hard but friable. Its quality is ranked higher than lignite and sub-bituminous coal, but lesser than anthracite. It is the most abundant rank of coal, with deposits found around the world, often in rocks of Carboniferous age. Bituminous coal is formed from sub-bituminous coal that is buried deeply enough to be heated to 85 °C (185 °F) or higher.
Diagenesis is the process that describes physical and chemical changes in sediments first caused by water-rock interactions, microbial activity, and compaction after their deposition. Increased pressure and temperature only start to play a role as sediments become buried much deeper in the Earth's crust. In the early stages, the transformation of poorly consolidated sediments into sedimentary rock (lithification) is simply accompanied by a reduction in porosity and water expulsion, while their main mineralogical assemblages remain unaltered. As the rock is carried deeper by further deposition above, its organic content is progressively transformed into kerogens and bitumens.
Petroleum geology is the study of origin, occurrence, movement, accumulation, and exploration of hydrocarbon fuels. It refers to the specific set of geological disciplines that are applied to the search for hydrocarbons.
Sedimentology encompasses the study of modern sediments such as sand, silt, and clay, and the processes that result in their formation, transport, deposition and diagenesis. Sedimentologists apply their understanding of modern processes to interpret geologic history through observations of sedimentary rocks and sedimentary structures.
Kerogen is solid, insoluble organic matter in sedimentary rocks. It consists of a variety of organic materials, including dead plants, algae, and other microorganisms, that have been compressed and heated by geological processes. All the kerogen on earth is estimated to contain 1016 tons of carbon. This makes it the most abundant source of organic compounds on earth, exceeding the total organic content of living matter 10,000-fold.
Inertinite refers to a group of partially oxidized organic materials or fossilized charcoals, all sharing the characteristic that they typically are inert when heated in the absence of oxygen. Inertinite is a common maceral in most types of coal. The main inertinite submacerals are fusinite, semifusinite, micrinite, macrinite and funginite, with semifusinite being the most common. From the perspective of coal combustion, inertinite can be burned to yield heat, but does not yield significant volatile fractions during coking.
A maceral is a component, organic in origin, of coal or oil shale. The term 'maceral' in reference to coal is analogous to the use of the term 'mineral' in reference to igneous or metamorphic rocks. Examples of macerals are inertinite, vitrinite, and liptinite.
Petroleum geochemistry is the branch of geochemistry which deals with the application of chemical principles in the study of the origin, generation, migration, accumulation, and alteration of petroleum...(John M. Hunt, 1979). Petroleum is generally considered oil and natural gases having various compounds composed of primarily hydrogen and carbon. They are usually generated from the decomposition and/or thermal maturation of organic matter. The organic matter originated from plants and algae. The organic matter is deposited after the death of the plant in sediments, where after considerable time, heat, and pressure the compounds in the plants and algae are altered to oil, gas, and kerogen. Kerogen can be thought of as the remaining solid material of the plant. The sediment - usually clay and/or calcareous (lime) ooze, hardens during this alteration process into rock i.e. shale and/or limestone. The shale or limestone rock containing the organic matter is called the source rock because it is the source, having generated the petroleum.
Organic-rich sedimentary rocks are a specific type of sedimentary rock that contains significant amounts (>3%) of organic carbon. The most common types include coal, lignite, oil shale, or black shale. The organic material may be disseminated throughout the rock giving it a uniform dark color, and/or it may be present as discrete occurrences of tar, bitumen, asphalt, petroleum, coal or carbonaceous material. Organic-rich sedimentary rocks may act as source rocks which generate hydrocarbons that accumulate in other sedimentary "reservoir" rocks. Potential source rocks are any type of sedimentary rock that the ability to dispel available carbon from within it. Good reservoir rocks are any sedimentary rock that has high pore-space availability. This allows the hydrocarbons to accumulate within the rock and be stored for long periods of time. Highly permeable reservoir rocks are also of interest to industry professionals, as they allow for the easy extraction of the hydrocarbons within. The hydrocarbon reservoir system is not complete however without a "cap rock". Cap rocks are rock units which have very low porosity and permeability, which trap the hydrocarbons within the units below as they try to migrate upwards.
Torbanite, also known historically as boghead coal or kerosene shale, is a variety of fine-grained black oil shale. It usually occurs as lenticular masses, often associated with deposits of Permian coals. Torbanite is classified as lacustrine type oil shale. A similar mineral, cannel coal, is classified as being a terrestrial form of oil shale, not a lacustrine type.
Oil shale geology is a branch of geologic sciences which studies the formation and composition of oil shales–fine-grained sedimentary rocks containing significant amounts of kerogen, and belonging to the group of sapropel fuels. Oil shale formation takes place in a number of depositional settings and has considerable compositional variation. Oil shales can be classified by their composition or by their depositional environment. Much of the organic matter in oil shales is of algal origin, but may also include remains of vascular land plants. Three major type of organic matter (macerals) in oil shale are telalginite, lamalginite, and bituminite. Some oil shale deposits also contain metals which include vanadium, zinc, copper, and uranium.
The Bend Arch–Fort Worth Basin Province is a major petroleum producing geological system which is primarily located in North Central Texas and southwestern Oklahoma. It is officially designated by the United States Geological Survey (USGS) as Province 045 and classified as the Barnett-Paleozoic Total Petroleum System (TPS).
In petroleum geology, source rock is rock which has generated hydrocarbons or which could generate hydrocarbons. Source rocks are one of the necessary elements of a working petroleum system. They are organic-rich sediments that may have been deposited in a variety of environments including deep water marine, lacustrine and deltaic. Oil shale can be regarded as an organic-rich but immature source rock from which little or no oil has been generated and expelled. Subsurface source rock mapping methodologies make it possible to identify likely zones of petroleum occurrence in sedimentary basins as well as shale gas plays.
The Foraminiferal Colouration Index (FCI) is a tool for assessing the thermal alteration of organic matter buried in sedimentary rock. It uses temperature-controlled colour changes in the organic cement of agglutinated foraminifera (microfossils) to estimate thermal alteration. The method is empirical and based on determination of colour by visual comparison of fossil specimens to the Geological Society of America Rock-Color Chart under a binocular microscope.
Pyrobitumen is a type of solid, amorphous organic matter. Pyrobitumen is mostly insoluble in carbon disulfide and other organic solvents as a result of molecular cross-linking, which renders previously soluble organic matter insoluble. Not all solid bitumens are pyrobitumens, in that some solid bitumens are soluble in common organic solvents, including CS
2, dichloromethane, and benzene-methanol mixtures.
Bituminite is an autochthonous maceral that is a part of the liptinite group in lignite, that occurs in petroleum source rocks originating from organic matter such as algae which has undergone alteration or degradation from natural processes such as burial. It occurs as fine-grained groundmass, laminae or elongated structures that appear as veinlets within horizontal sections of lignite and bituminous coals, and also occurs in sedimentary rocks. Its occurrence in sedimentary rocks is typically found surrounding alginite, and parallel along bedding planes. Bituminite is not considered to be bitumen because its properties are different from most bitumens. It is described to have no definite shape or form when present in bedding and can be identified using different kinds of visible and fluorescent lights. There are three types of bituminite: type I, type II and type III, of which type I is the most common. The presence of bituminite in oil shales, other oil source rocks and some coals plays an important factor when determining potential petroleum-source rocks.
Funginite is a maceral, a component, organic in origin, of coal or oil shale, that exhibits several different physical properties and characteristics under particular conditions, and its dimensions are based upon its source and place of discovery. Furthermore, it is primarily part of a group of macerals that naturally occur in rocks containing mostly carbon constituents, specifically coal. Due to its nature, research into the chemical structure and formula of funginite is considered limited and lacking. According to Chen et al. referencing ICCP, 2001, alongside the maceral secretinite, they "are both macerals of the inertinite group, which is more commonly known as fossilized charcoal, and were previously jointly classified as the maceral sclerotinite". In the scientific community, the discernment between the two does not remain entirely clear, but there are slight particular and specific differences in regards to the composition between both. It is also the product of fungal development on these carbon rich sedimentary rocks.
The Arkoma Basin is a peripheral foreland basin that extends from central west Arkansas to south eastern Oklahoma. The basin lies in between the Ozark Uplift and Oklahoma Platform to the north and Ouachita Mountains to the south and with an area of approximately 33,800 mi2. Along the southern edge of the basin, the Choctaw Fault is the boundary that separates the mountains from the basin itself. This basin is one of seven that lie along the front of the Ouachita and Appalachian mountain systems. This basin is Oklahoma's fourth largest in terms of natural gas production. Oil has been extracted locally, but not on a commercial scale. Coal was the first natural resource used commercially within the basin. Surface mapping of coal seams in the early part of the 20th century lead to the discovery of sub-surface features that indicated the presence of natural gas. Mansfield, Arkansas was the site of the first natural gas discovery in 1902.
