Indium(III) nitrate

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Indium(III) nitrate
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.033.979 OOjs UI icon edit-ltr-progressive.svg
EC Number
  • anhydrous:237-393-5
PubChem CID
RTECS number
  • anhydrous:NL1750000
UNII
  • InChI=1S/In.3NO3/c;3*2-1(3)4/q+3;3*-1
    Key: LKRFCKCBYVZXTC-UHFFFAOYSA-N
  • monohydrate:InChI=1S/In.3NO3.H2O/c;3*2-1(3)4;/h;;;;1H2/q+3;3*-1;
    Key: YZZFBYAKINKKFM-UHFFFAOYSA-N
  • trihydrate:InChI=1S/In.3NO3.3H2O/c;3*2-1(3)4;;;/h;;;;3*1H2/q+3;3*-1;;;
    Key: HVDZMISZAKTZFP-UHFFFAOYSA-N
  • tetrahydrate:InChI=1S/In.3NO3.4H2O/c;3*2-1(3)4;;;;/h;;;;4*1H2/q+3;3*-1;;;;
    Key: ZYYDOSLSINDXIQ-UHFFFAOYSA-N
  • anhydrous:[N+](=O)([O-])[O-].[N+](=O)([O-])[O-].[N+](=O)([O-])[O-].[In+3]
  • monohydrate:[N+](=O)([O-])O[In](O[N+](=O)[O-])O[N+](=O)[O-].O
  • trihydrate:[N+](=O)([O-])O[In](O[N+](=O)[O-])O[N+](=O)[O-].O.O.O
  • tetrahydrate:[N+](=O)([O-])O[In](O[N+](=O)[O-])O[N+](=O)[O-].O.O.O.O
Properties
In(NO3)3
Molar mass 300.83 g/mol
AppearanceWhite solid
Density 2.43 g/cm3 (pentahydrate) [1]
Melting point 100 °C (212 °F; 373 K) (decomposes, hydrate)
Soluble
Structure [1]
Monoclinic
C2/c
a = 10.35 Å, b = 9.17 Å, c = 11.25 Å
α = 90°, β = 91.05°, γ = 90°
1068 Å3
Hazards
GHS labelling:
GHS-pictogram-rondflam.svg GHS-pictogram-exclam.svg
Warning
H272, H315, H319, H335
P210, P220, P221, P261, P264, P271, P280, P302+P352, P304+P340, P305+P351+P338, P312, P321, P332+P313, P337+P313, P362, P370+P378, P403+P233, P405, P501
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Indium(III) nitrate is a nitrate salt of indium which forms various hydrates. Only the pentahydrate has been crystallographically verified. Other hydrates are also reported in literature, such as the trihydrate. [1] [2] [3]

Contents

Production and reactions

Indium(III) nitrate hydrate is produced by the dissolution of indium metal in concentrated nitric acid followed by evaporation of the solution: [1] [2] [3]

In + 4 HNO3 → In(NO3)3 + NO + 2 H2O

The hydrate first decomposes to a basic salt and then to indium(III) oxide at 240 °C. Anhydrous indium(III) nitrate is claimed to be produced by the reaction of anhydrous indium(III) chloride and dinitrogen pentoxide. [2] [4]

In the presence of excess nitrate ions, indium(III) nitrate converts to the [In(NO3)4] ion. [1] [2]

The hydrolysis of indium(III) nitrate yields indium(III) hydroxide. It also reacts with sodium tungstate to form In(OH)WO4, [In(OH)2]2WO4, NaInWO4 or In2(WO4)3 depending on pH. [5] [6]

Structure

Only the pentahydrate has been structurally elucidated. The pentahydrate consists of octahedral [In(NO3)(H2O)5]2+ centers as well as two nitrates and is monoclinic. [1]

Related Research Articles

<span class="mw-page-title-main">Copper(II) nitrate</span> Chemical compound

Copper(II) nitrate describes any member of the family of inorganic compounds with the formula Cu(NO3)2(H2O)x. The hydrates are blue solids. Anhydrous copper nitrate forms blue-green crystals and sublimes in a vacuum at 150-200 °C. Common hydrates are the hemipentahydrate and trihydrate.

In chemistry, water(s) of crystallization or water(s) of hydration are water molecules that are present inside crystals. Water is often incorporated in the formation of crystals from aqueous solutions. In some contexts, water of crystallization is the total mass of water in a substance at a given temperature and is mostly present in a definite (stoichiometric) ratio. Classically, "water of crystallization" refers to water that is found in the crystalline framework of a metal complex or a salt, which is not directly bonded to the metal cation.

<span class="mw-page-title-main">Scandium nitrate</span> Chemical compound

Scandium(III) nitrate, Sc(NO3)3, is an ionic compound. It is an oxidizer, as all nitrates are. The salt is applied in optical coatings, catalysts, electronic ceramics and the laser industry.

Indium(III) sulfate (In2(SO4)3) is a sulfate salt of the metal indium. It is a sesquisulfate, meaning that the sulfate group occurs 11/2 times as much as the metal. It may be formed by the reaction of indium, its oxide, or its carbonate with sulfuric acid. An excess of strong acid is required, otherwise insoluble basic salts are formed. As a solid indium sulfate can be anhydrous, or take the form of a pentahydrate with five water molecules or a nonahydrate with nine molecules of water. Indium sulfate is used in the production of indium or indium containing substances. Indium sulfate also can be found in basic salts, acidic salts or double salts including indium alum.

<span class="mw-page-title-main">Iron(III) nitrate</span> Chemical compound

Iron(III) nitrate, or ferric nitrate, is the name used for a series of inorganic compounds with the formula Fe(NO3)3.(H2O)n. Most common is the nonahydrate Fe(NO3)3.(H2O)9. The hydrates are all pale colored, water-soluble paramagnetic salts.

<span class="mw-page-title-main">Cobalt(II) nitrate</span> Chemical compound

Cobalt nitrate is the inorganic compound with the formula Co(NO3)2.xH2O. It is cobalt(II)'s salt. The most common form is the hexahydrate Co(NO3)2·6H2O, which is a red-brown deliquescent salt that is soluble in water and other polar solvents.

<span class="mw-page-title-main">Mercury(I) nitrate</span> Chemical compound

Mercury(I) nitrate is an inorganic compound, a salt of mercury and nitric acid with the formula Hg2(NO3)2. A yellow solid, the compound is used as a precursor to other Hg22+ complexes. The structure of the hydrate has been determined by X-ray crystallography. It consists of a [H2O-Hg-Hg-OH2]2+ center, with a Hg-Hg distance of 254 pm.

<span class="mw-page-title-main">Cobalt(III) nitrate</span> Chemical compound

Cobalt(III) nitrate is an inorganic compound with the chemical formula Co(NO3)3. It is a green, diamagnetic solid that sublimes at ambient temperature.

<span class="mw-page-title-main">Bismuth oxynitrate</span> Chemical compound

Bismuth oxynitrate is the name applied to a number of compounds that contain Bi3+, nitrate ions and oxide ions and which can be considered as compounds formed from Bi2O3, N2O5 and H2O. Other names for bismuth oxynitrate include bismuth subnitrate and bismuthyl nitrate. In older texts bismuth oxynitrate is often simply described as BiONO3 or basic bismuth nitrate. Bismuth oxynitrate was once called magisterium bismuti or bismutum subnitricum, and was used as a white pigment, in beauty care, and as a gentle disinfectant for internal and external use. It is also used to form Dragendorff's reagent, which is used as a TLC stain.

<span class="mw-page-title-main">Cerium nitrates</span> Chemical compound

Cerium nitrate refers to a family of nitrates of cerium in the +3 or +4 oxidation state. Often these compounds contain water, hydroxide, or hydronium ions in addition to cerium and nitrate. Double nitrates of cerium also exist.

<span class="mw-page-title-main">Sodium hyponitrite</span> Chemical compound

Sodium hyponitrite is a solid ionic compound with formula Na
2
N
2
O
2
or (Na+
)2[ON=NO]2−.

<span class="mw-page-title-main">Titanium(IV) nitrate</span> Chemical compound

Titanium nitrate is the inorganic compound with formula Ti(NO3)4. It is a colorless, diamagnetic solid that sublimes readily. It is an unusual example of a volatile binary transition metal nitrate. Ill defined species called titanium nitrate are produced upon dissolution of titanium or its oxides in nitric acid.

<span class="mw-page-title-main">Thorium(IV) nitrate</span> Chemical compound

Thorium(IV) nitrate is a chemical compound, a salt of thorium and nitric acid with the formula Th(NO3)4. A white solid in its anhydrous form, it can form tetra- and pentahydrates. As a salt of thorium it is weakly radioactive.

<span class="mw-page-title-main">Nitratoauric acid</span> Chemical compound

Nitratoauric acid, hydrogen tetranitratoaurate, or simply called gold(III) nitrate is a crystalline gold compound that forms the trihydrate, HAu(NO3)4·3H2O or more correctly H5O2Au(NO3)4·H2O. This compound is an intermediate in the process of extracting gold. In older literature it is also known as aurinitric acid.

<span class="mw-page-title-main">Ytterbium(III) nitrate</span> Chemical compound

Ytterbium(III) nitrate is an inorganic compound, a salt of ytterbium and nitric acid with the chemical formula Yb(NO3)3. The compound forms colorless crystals, dissolves in water, and also forms crystalline hydrates.

<span class="mw-page-title-main">Transition metal nitrate complex</span> Compound of nitrate ligands

A transition metal nitrate complex is a coordination compound containing one or more nitrate ligands. Such complexes are common starting reagents for the preparation of other compounds.

<span class="mw-page-title-main">Europium compounds</span> Chemical compounds

Europium compounds are compounds formed by the lanthanide metal europium (Eu). In these compounds, europium generally exhibits the +3 oxidation state, such as EuCl3, Eu(NO3)3 and Eu(CH3COO)3. Compounds with europium in the +2 oxidation state are also known. The +2 ion of europium is the most stable divalent ion of lanthanide metals in aqueous solution. Many europium compounds fluoresce under ultraviolet light due to the excitation of electrons to higher energy levels. Lipophilic europium complexes often feature acetylacetonate-like ligands, e.g., Eufod.

<span class="mw-page-title-main">Nickel tungstate</span> Chemical compound

Nickel tungstate is an inorganic compound of nickel, tungsten and oxygen, with the chemical formula of NiWO4.

Cobalt compounds are chemical compounds formed by cobalt with other elements.

Neodymium tungstate is an inorganic compound, a salt of neodymium and tungstic acid with the chemical formula Nd2(WO4)3. It forms hydrated light purple crystals that are slightly soluble in water.

References

  1. 1 2 3 4 5 6 M. A. Malyarik; S. P. Petrosyants; A. B. Ilyukhin; Yu. A. Buslaev (1993). "Polyfunctionality of the nitrate group, coordination numbers of trivalent indium in nitrates complexes, and crystal structures of [In(NO3)(H2O)5](NO3)2 and HK6[In(NO3)4(H2O)2]3(NO3)4". Russian Journal of Inorganic Chemistry. 38 (12): 1849–1854. ISSN   0036-0236.
  2. 1 2 3 4 D. G. Tuck; E. J. Woodhouse; P. Carty (1966). "Co-ordination compounds of indium. Part III. Indium(III) nitrate species". Journal of the Chemical Society A: Inorganic, Physical, Theoretical: 1077–1080. doi:10.1039/J19660001077.
  3. 1 2 Galina V. Kozhevnikova; Gábor Keresztury (1985). "The state of indium ions in nitrate solutions: A Raman spectroscopic study". Inorganica Chimica Acta. 98 (1): 59–65. doi:10.1016/S0020-1693(00)90751-5.
  4. B. O. Field; C. J. Hardy (1964). "Volatile and anhydrous nitrato-complexes of metals: preparation by the use of dinitrogen pentroxide, and measurement of infrared spectra". Journal of the Chemical Society: 4428–4434. doi:10.1039/JR9640004428.
  5. Keita Yura; Karl C. Fredrikson; Egon Matijević (1990). "Preparation and properties of uniform colloidal indium compounds of different morphologies". Colloids and Surfaces. 50: 281–293. doi:10.1016/0166-6622(90)80270-E.
  6. Shcherbina, K. G.; Mokhosoev, M. V.; Gruba, A. I. (1974). "Reaction of aluminum and indium nitrates with sodium tungstate in hot solutions". Zhurnal Neorganicheskoi Khimii (in Russian). 19 (2): 396–399. ISSN   0044-457X.{{cite journal}}: CS1 maint: multiple names: authors list (link)