Baddeleyite

Last updated
Baddeleyite
Baddeleyite-md12a.jpg
Baddeleyite from Phalaborwa, South Africa
General
CategoryOxide mineral
Formula
(repeating unit)
Zirconium dioxide (ZrO2)
IMA symbol Bdy [1]
Strunz classification 4.DE.35
Dana classification04.04.14.01
Crystal system Monoclinic
Crystal class Prismatic (2/m)
(same H-M symbol)
Space group P21/c
Unit cell a = 5.1505 Å,
b = 5.2116 Å,
c = 5.3173 Å, β = 99.23°; Z = 4
Identification
ColorColorless to yellow, blue, green, greenish or reddish brown, brown, iron-black
Crystal habit Tabular prismatic, radially fibrous in botryoidal masses
Twinning Ubiquitous polysynthetic on {100} and {110}
Cleavage {001} distinct
Fracture Irregular uneven to subconchoidal
Tenacity Brittle
Mohs scale hardness6.5
Luster Greasy to vitreous
Streak White
Diaphaneity Transparent to translucent
Specific gravity 5.5–6
Optical propertiesBiaxial (–)
Refractive index nα = 2.130
nβ = 2.190
nγ = 2.200
Birefringence δ = 0.070
Pleochroism X = yellow, reddish brown, oil-green; Y = oil-green, reddish brown; Z = brown, light brown
2V angle Measured: 30° to 31°
Dispersion r > v, rather strong
Other characteristicsBlue-green cathodoluminescence
References [2] [3] [4]

Baddeleyite is a rare zirconium oxide mineral (ZrO2 or zirconia), occurring in a variety of monoclinic prismatic crystal forms. It is transparent to translucent, has high indices of refraction, and ranges from colorless to yellow, green, and dark brown. See etymology below.

Contents

Baddeleyite is a refractory mineral, with a melting point of 2700 °C. Hafnium is a substituting impurity and may be present in quantities ranging from 0.1 to several percent.

It can be found in igneous rocks containing potassium feldspar and plagioclase. Baddeleyite is commonly not found with zircon (ZrSiO4), because it forms in silica-undersaturated rocks, such as mafic rocks. This is because, when silica is free in the system (silica-saturated/oversaturated), zircon is the dominating phase, not baddeleyite. It belongs to the monoclinic-prismatic class, of the P21/c crystal system. It has been used for geochronology. [5]

Geologic occurrence

Baddeleyite was first found in Sri Lanka in 1892. It can be found in numerous terrestrial and extraterrestrial rocks. Some of these terrestrial rocks are carbonatite, kimberlite, alkaline syenite, some rocks of layered mafic intrusions, diabase dikes, gabbroid sills and anorthosite. [5] Some examples of extraterrestrial rocks are tektites, meteorites and lunar basalt. Studies have shown that zircon and baddeleyite can be recovered from some anorthositic rocks in Proterozoic anorthosite complexes. [6] Places where these Proterozoic anorthosite complexes can be found are: the Laramie Anorthosite Complex in Wyoming, the Nain and Grenville provinces of Canada, the Vico Volcanic Complex in Italy, [7] and Minas Gerais and Jacupiranga, São Paulo, Brazil. Baddeleyite forms in igneous rocks low in silica, it can be found in rocks containing potassium feldspar and plagioclase. It has been observed in thin section that baddeleyite forms within plagioclase grains. Associated minerals include ilmenite, zirkelite, apatite, magnetite, perovskite, fluorite, nepheline, pyrochlore and allanite. [2]

Because of their refractory nature and stability under diverse conditions, baddeleyite grains, along with zircon, are used for uranium-lead radiometric age determinations.

Crystal structure of baddeleyite BaddeleyiteStructure.png
Crystal structure of baddeleyite

Structure

There has been some dispute in the structure of baddeleyite. Originally, the mineral was assigned to the 8-fold coordination by Naray Szabo. This structure was ruled out due to the inaccuracy of the data used to establish it.

Baddeleyite has the group symmetry P21/c with four ZrO2 in the unit cell. It has unit cell dimensions of: a = 5.169 b = 5.232 c = 5.341 Å (all ± 0.008 Å), β = 99˚15ˊ ± 10ˊ.

The coordination number for ZrO2 has been found to be 7. The mineral has two types of separations. The first being the seven shortest Zr-O, ranging from 2.04 to 2.26 Å, and the second Zr-O separation is 3.77 Å. Because of this, the coordination of baddeleyite was determined to be sevenfold. Baddeleyite's structure is a combination of tetrahedrally coordinated oxide ions parallel to (100) with triangular coordinated oxide ions. This explains baddeleyite's tendency to twin along the (100) planes. It has been observed that baddeleyite without twinning is extremely rare. [9]

Composition

Baddeleyite belongs to the oxide group, having a composition of ZrO2. Similar minerals belonging to the same group are the rutile group: rutile (TiO2), pyrolusite (MnO2), cassiterite (SnO2), uraninite (UO2) and thorianite (ThO2). Baddeleyite is chemically homogeneous, but it may contain impurities such as Ti, Hf, and Fe. [10] Higher concentrations of Ti and Fe are restricted to mafic-ultramafic rocks.

Physical properties

Baddeleyite is black in color with a submetallic lustre. It has a 6.5 hardness, and a brownish-white streak. Baddeleyite can also be brown, brownish black, green, and greenish brown. Its streak is white, or brownish white. It has a distinct cleavage along {001} and tends to twin along (100). It belongs to the monoclinic system and is part of the P21/c group. [11]

Origin of the name

It was named for Joseph Baddeley. The mineral was discovered in Rakwana, Ceylon (now Sri Lanka). Baddeley was a superintendent of a railroad project in Rakwana. As recounted by J.J.H. Teall – director of the British Geological Survey in the early 1900s – baddeleyite was discovered consequent to the discovery of geikielite.

Baddeley sent specimens of several pebbles from the Rakwana railroad excavations to the Museum of Practical Geology in London, where a Mr. Pringle examined them and attempted to classify them. Pringle was unable to assign the specimens to a known mineral species and submitted them to Teall. After analyzing the specimens, Teall concluded that the mineral was mainly composed of titanic acid and magnesia, with an incidental mixture of protoxide of iron. Geikielite has the composition of MgTiO3. Teall and Pringle decided to name the new mineral geikielite, naming it after Sir  Archibald Geikie, then the Director General of the Geological Survey.

Baddeley sent more specimens to Teall, in order to provide an exemplary specimen for display at the Museum of Practical Geology. While trying to find the specimens, Teall noticed that one of them was different from the rest: This new mineral was black in color, with a submetallic lustre, and a hardness of 6.5 . After analyzing it, the odd mineral was determined to not be MgTiO3 (geikielite), but instead ZrO2. Teall proposed mineral name baddeleyite, after Joseph Baddeley, to honor the man who brought the two new minerals to notice. [11]

See also

Related Research Articles

<span class="mw-page-title-main">Gabbro</span> Coarse-grained mafic intrusive rock

Gabbro is a phaneritic (coarse-grained), mafic intrusive igneous rock formed from the slow cooling of magnesium-rich and iron-rich magma into a holocrystalline mass deep beneath the Earth's surface. Slow-cooling, coarse-grained gabbro is chemically equivalent to rapid-cooling, fine-grained basalt. Much of the Earth's oceanic crust is made of gabbro, formed at mid-ocean ridges. Gabbro is also found as plutons associated with continental volcanism. Due to its variant nature, the term gabbro may be applied loosely to a wide range of intrusive rocks, many of which are merely "gabbroic". By rough analogy, gabbro is to basalt as granite is to rhyolite.

<span class="mw-page-title-main">Mafic</span> Silicate mineral or igneous rock that is rich in magnesium and iron

A mafic mineral or rock is a silicate mineral or igneous rock rich in magnesium and iron. Most mafic minerals are dark in color, and common rock-forming mafic minerals include olivine, pyroxene, amphibole, and biotite. Common mafic rocks include basalt, diabase and gabbro. Mafic rocks often also contain calcium-rich varieties of plagioclase feldspar. Mafic materials can also be described as ferromagnesian.

<span class="mw-page-title-main">Zirconium</span> Chemical element, symbol Zr and atomic number 40

Zirconium is a chemical element; it has symbol Zr and atomic number 40. The name zirconium is derived from the name of the mineral zircon, the most important source of zirconium. The word is related to Persian zargun. It is a lustrous, grey-white, strong transition metal that closely resembles hafnium and, to a lesser extent, titanium. Zirconium is mainly used as a refractory and opacifier, although small amounts are used as an alloying agent for its strong resistance to corrosion. Zirconium forms a variety of inorganic and organometallic compounds such as zirconium dioxide and zirconocene dichloride, respectively. Five isotopes occur naturally, four of which are stable. Zirconium compounds have no known biological role.

<span class="mw-page-title-main">Rutile</span> Oxide mineral composed of titanium dioxide

Rutile is an oxide mineral composed of titanium dioxide (TiO2), the most common natural form of TiO2. Rarer polymorphs of TiO2 are known, including anatase, akaogiite, and brookite.

<span class="mw-page-title-main">Plagioclase</span> Type of feldspar

Plagioclase is a series of tectosilicate (framework silicate) minerals within the feldspar group. Rather than referring to a particular mineral with a specific chemical composition, plagioclase is a continuous solid solution series, more properly known as the plagioclase feldspar series. This was first shown by the German mineralogist Johann Friedrich Christian Hessel (1796–1872) in 1826. The series ranges from albite to anorthite endmembers (with respective compositions NaAlSi3O8 to CaAl2Si2O8), where sodium and calcium atoms can substitute for each other in the mineral's crystal lattice structure. Plagioclase in hand samples is often identified by its polysynthetic crystal twinning or "record-groove" effect.

<span class="mw-page-title-main">Zircon</span> Zirconium silicate, a mineral belonging to the group of nesosilicates

Zircon is a mineral belonging to the group of nesosilicates and is a source of the metal zirconium. Its chemical name is zirconium(IV) silicate, and its corresponding chemical formula is ZrSiO4. An empirical formula showing some of the range of substitution in zircon is (Zr1–y, REEy)(SiO4)1–x(OH)4x–y. Zircon precipitates from silicate melts and has relatively high concentrations of high field strength incompatible elements. For example, hafnium is almost always present in quantities ranging from 1 to 4%. The crystal structure of zircon is tetragonal crystal system. The natural color of zircon varies between colorless, yellow-golden, red, brown, blue, and green.

<span class="mw-page-title-main">Ilmenite</span> Titanium-iron oxide mineral

Ilmenite is a titanium-iron oxide mineral with the idealized formula FeTiO
3
. It is a weakly magnetic black or steel-gray solid. Ilmenite is the most important ore of titanium and the main source of titanium dioxide, which is used in paints, printing inks, fabrics, plastics, paper, sunscreen, food and cosmetics.

<span class="mw-page-title-main">Zirconium dioxide</span> Chemical compound

Zirconium dioxide, sometimes known as zirconia, is a white crystalline oxide of zirconium. Its most naturally occurring form, with a monoclinic crystalline structure, is the mineral baddeleyite. A dopant stabilized cubic structured zirconia, cubic zirconia, is synthesized in various colours for use as a gemstone and a diamond simulant.

<span class="mw-page-title-main">Anorthite</span> Calcium-rich feldspar mineral

Anorthite (an = not, ortho = straight) is the calcium endmember of the plagioclase feldspar mineral series. The chemical formula of pure anorthite is CaAl2Si2O8. Anorthite is found in mafic igneous rocks. Anorthite is rare on the Earth but abundant on the Moon.

<span class="mw-page-title-main">Trachyte</span> Extrusive igneous rock

Trachyte is an extrusive igneous rock composed mostly of alkali feldspar. It is usually light-colored and aphanitic (fine-grained), with minor amounts of mafic minerals, and is formed by the rapid cooling of lava enriched with silica and alkali metals. It is the volcanic equivalent of syenite.

<span class="mw-page-title-main">Anorthosite</span> Mafic intrusive igneous rock composed predominantly of plagioclase

Anorthosite is a phaneritic, intrusive igneous rock characterized by its composition: mostly plagioclase feldspar (90–100%), with a minimal mafic component (0–10%). Pyroxene, ilmenite, magnetite, and olivine are the mafic minerals most commonly present.

<span class="mw-page-title-main">Nepheline syenite</span> Holocrystalline plutonic rock

Nepheline syenite is a holocrystalline plutonic rock that consists largely of nepheline and alkali feldspar. The rocks are mostly pale colored, grey or pink, and in general appearance they are not unlike granites, but dark green varieties are also known. Phonolite is the fine-grained extrusive equivalent.

<span class="mw-page-title-main">Lamproite</span> Mantle rock expulsed to the surface in volcanic pipes

Lamproite is an ultrapotassic mantle-derived volcanic or subvolcanic rock. It has low CaO, Al2O3, Na2O, high K2O/Al2O3, a relatively high MgO content and extreme enrichment in incompatible elements.

<span class="mw-page-title-main">Moon rock</span> Rocks on or from the Moon

Moon rock or lunar rock is rock originating from Earth's Moon. This includes lunar material collected during the course of human exploration of the Moon, and rock that has been ejected naturally from the Moon's surface and landed on Earth as meteorites.

<span class="mw-page-title-main">Cumulate rock</span> Igneous rocks formed by the accumulation of crystals from a magma either by settling or floating.

Cumulate rocks are igneous rocks formed by the accumulation of crystals from a magma either by settling or floating. Cumulate rocks are named according to their texture; cumulate texture is diagnostic of the conditions of formation of this group of igneous rocks. Cumulates can be deposited on top of other older cumulates of different composition and colour, typically giving the cumulate rock a layered or banded appearance.

<span class="mw-page-title-main">Hafnium(IV) oxide</span> Chemical compound

Hafnium(IV) oxide is the inorganic compound with the formula HfO
2
. Also known as hafnium dioxide or hafnia, this colourless solid is one of the most common and stable compounds of hafnium. It is an electrical insulator with a band gap of 5.3~5.7 eV. Hafnium dioxide is an intermediate in some processes that give hafnium metal.

<span class="mw-page-title-main">Monzogranite</span> Biotite granite rocks that are considered to be the final fractionation product of magma

Monzogranites are biotite granite rocks that are considered to be the final fractionation product of magma. Monzogranites are characteristically felsic (SiO2 > 73%, and FeO + MgO + TiO2 < 2.4), weakly peraluminous (Al2O3/ (CaO + Na2O + K2O) = 0.98–1.11), and contain ilmenite, sphene, apatite and zircon as accessory minerals. Although the compositional range of the monzogranites is small, it defines a differentiation trend that is essentially controlled by biotite and plagioclase fractionation. (Fagiono, 2002). Monzogranites can be divided into two groups (magnesio-potassic monzogranite and ferro-potassic monzogranite) and are further categorized into rock types based on their macroscopic characteristics, melt characteristics, specific features, available isotopic data, and the locality in which they are found.

<span class="mw-page-title-main">Geikielite</span> Magnesium titanium oxide mineral

Geikielite is a magnesium titanium oxide mineral with formula: MgTiO3. It is a member of the ilmenite group. It crystallizes in the trigonal system forming typically opaque, black to reddish black crystals.

<span class="mw-page-title-main">Titanium in zircon geothermometry</span>

Titanium in zircon geothermometry is a form of a geothermometry technique by which the crystallization temperature of a zircon crystal can be estimated by the amount of titanium atoms which can only be found in the crystal lattice. In zircon crystals, titanium is commonly incorporated, replacing similarly charged zirconium and silicon atoms. This process is relatively unaffected by pressure and highly temperature dependent, with the amount of titanium incorporated rising exponentially with temperature, making this an accurate geothermometry method. This measurement of titanium in zircons can be used to estimate the cooling temperatures of the crystal and infer conditions during which it crystallized. Compositional changes in the crystals growth rings can be used to estimate the thermodynamic history of the entire crystal. This method is useful as it can be combined with radiometric dating techniques that are commonly used with zircon crystals, to correlate quantitative temperature measurements with specific absolute ages. This technique can be used to estimate early Earth conditions, determine metamorphic facies, or to determine the source of detrital zircons, among other uses.

<span class="mw-page-title-main">Southern Oklahoma Aulacogen</span> Failed rift in the western and southern US of the triple junction that became the Iapetus Ocean

The Southern Oklahoma Aulacogen is a failed rift, or failed rift arm (aulacogen), of the triple junction that became the Iapetus Ocean spreading ridges. It is a significant geological feature in the Western and Southern United States. It formed sometime in the early to mid Cambrian Period and spans the Wichita Mountains, Taovayan Valley, Anadarko Basin, and Hardeman Basin in Southwestern Oklahoma. The Southern Oklahoma Aulacogen is primarily composed of basaltic dikes, gabbros, and units of granitic rock.

References

  1. Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine. 85 (3): 291–320. Bibcode:2021MinM...85..291W. doi: 10.1180/mgm.2021.43 . S2CID   235729616.
  2. 1 2 Anthony, John W.; Bideaux, Richard A.; Bladh, Kenneth W.; Nichols, Monte C., eds. (1990). "Baddeleyite". Handbook of Mineralogy (PDF). Vol. III (Halides, Hydroxides, Oxides). Chantilly, VA, US: Mineralogical Society of America. ISBN   0962209724 . Retrieved December 5, 2011.
  3. Baddeleyite. Webmineral
  4. Baddeleyite. Mindat
  5. 1 2 Bayanova, T.B. (2006). "Baddeleyite: A promising geochronometer for alkaline and basic magmatism". Petrology. 14 (2): 187–200. Bibcode:2006Petro..14..187B. doi:10.1134/S0869591106020032. S2CID   129079168.
  6. Scoates, James & Kevin Chamberlain (1995). "Baddeleyite (ZrOr) and zircon (ZrSiO) from anorthositic rocks of the Laramie anorthosite complex, Wyoming: Petrologic consequences and U-Pb ages" (PDF). American Mineralogist. 80 (11–12): 1317–1327. Bibcode:1995AmMin..80.1317S. doi:10.2138/am-1995-11-1222. S2CID   46901671.
  7. Bellatreccia, Fabio; Giancarlo Della Ventura; Gian Carlo Parodi & Terry Williams (1998). "Baddeleyite from the vico volcanic complex, latium Italy" (PDF). Rendiconti Lincei. 9 (1): 27–33. Bibcode:1998RLSFN...9...27B. doi:10.1007/BF02904453. S2CID   126680669. Archived from the original (PDF) on 2007-12-12.
  8. Drabińska, A.; Grodecki, K.; Strupiński, W.; Bożek, R.; Korona, K. P.; Wysmołek, A.; Stępniewski, R.; Baranowski, J. M. (2010). "Growth kinetics of epitaxial graphene on SiC substrates". Physical Review B. 81 (24): 245410. Bibcode:2010PhRvB..81x5410D. doi:10.1103/PhysRevB.81.245410.
  9. McCullough, J. D. & Trueblood, K. N. (1959). "The crystal structure of baddeleyite (monoclinic ZrO2)". Acta Crystallographica. 12 (7): 507. Bibcode:1959AcCry..12..507M. doi:10.1107/S0365110X59001530.
  10. Lumpkin, G.R. (1999). "Physical and chemical characteristics of baddeleyite (monoclinic zirconia) in natural environments: An overview and case study". Journal of Nuclear Materials. 274 (1–2): 206–217. Bibcode:1999JNuM..274..206L. doi:10.1016/S0022-3115(99)00066-5.
  11. 1 2 Fletcher, L. (1892). "On Baddeleyite (native zirconia), a new Mineral, from Rakwana, Ceylon" (PDF). Mineralogy Magazine and Journal of the Mineralogical Society: 149–161.