Bowen's reaction series

Last updated
Discontinuous
Series

(Mafic minerals)
Continuous
Series

(Felsic minerals)
High
Olivine Plagioclase
(Calcium rich)
Pyroxene
Amphibole
Biotite
(Black Mica)
Plagioclase
(Sodium rich)
Relative
Crystallization
Temperature
Orthoclase
(K-feldspar)
Muscovite
(White Mica)
Quartz
(Felsic mineral)
Low

Within the field of geology, Bowen's reaction series is the work of the Canadian petrologist Norman L. Bowen, [1] who summarized, based on experiments and observations of natural rocks, the sequence of crystallization of common silicate minerals from typical basaltic magma undergoing fractional crystallization (i.e. crystallization wherein early-formed crystals are removed from the magma by crystal settling, leaving behind a liquid of slightly different composition). [2] Bowen's reaction series is able to explain why certain types of minerals tend to be found together while others are almost never associated with one another. He experimented in the early 1900s with powdered rock material that was heated until it melted and then allowed to cool to a target temperature whereupon he observed the types of minerals that formed in the rocks produced. He repeated this process with progressively cooler temperatures and the results he obtained led him to formulate his reaction series which is still accepted today as the idealized progression of minerals produced by cooling basaltic magma that undergoes fractional crystallization. Based upon Bowen's work, one can infer from the minerals present in a rock the relative conditions under which the material had formed. [3]

Contents

Description

Olivine weathering to iddingsite within a mantle xenolith, demonstrating the principles of the Goldich dissolution series Iddingsite.JPG
Olivine weathering to iddingsite within a mantle xenolith, demonstrating the principles of the Goldich dissolution series
Bowen's reaction series Bowen's Reaction Series.png
Bowen's reaction series

The series is divided into two branches, the continuous (felsic minerals: feldspars) and the discontinuous (mafic minerals). The minerals at the top of the illustration (given aside) are first to crystallize and so the temperature gradient can be read to be from high to low with the high-temperature minerals being on the top and the low-temperature ones on the bottom. The branch on the right of the illustration is the continuous one (with continuous solid solutions of felsic minerals) and results in progressively sodium-rich plagioclase at lowering temperatures. In the discontinuous series mafic minerals such as olivine will first crystallize at a higher temperature, as magma cools. However, if they are not precipitated (settled) out, the composition of the magma does not change and as the magma further cools the olivine will recrystallise as pyroxene.

Since the surface of the Earth is a low temperature environment compared to the zones of rock formation, the chart also reflects the relative stability of minerals, with the ones at bottom being most stable and the ones at top being quickest to weather, known as the Goldich dissolution series. This is because minerals are most stable in the temperature and pressure conditions closest to those under which they had formed.

Related Research Articles

Mafic Silicate mineral or igneous rock that is rich in magnesium and iron

A mafic mineral or rock is a silicate mineral or igneous rock rich in magnesium and iron. Most mafic minerals are dark in color, and common rock-forming mafic minerals include olivine, pyroxene, amphibole, and biotite. Common mafic rocks include basalt, diabase and gabbro. Mafic rocks often also contain calcium-rich varieties of plagioclase feldspar. Mafic materials can also be described as ferromagnesian.

Magma Hot semifluid material found beneath the surface of Earth

Magma is the molten or semi-molten natural material from which all igneous rocks are formed. Magma is found beneath the surface of the Earth, and evidence of magmatism has also been discovered on other terrestrial planets and some natural satellites. Besides molten rock, magma may also contain suspended crystals and gas bubbles.

Feldspar Group of rock-forming minerals

Feldspars are a group of rock-forming aluminium tectosilicate minerals, containing sodium, calcium, potassium or barium. The most common members of the feldspar group are the plagioclase (sodium-calcium) feldspars and the alkali (potassium-sodium) feldspars. Feldspars make up about 60% of the Earth's crust, and 41% of the Earth's continental crust by weight.

Olivine Magnesium iron silicate solid solution series mineral

The mineral olivine is a magnesium iron silicate with the chemical formula (Mg2+, Fe2+)
2
SiO
4
. It is a type of nesosilicate or orthosilicate. The primary component of the Earth's upper mantle, it is a common mineral in Earth's subsurface, but weathers quickly on the surface. For this reason, olivine has been proposed as a good candidate for accelerated weathering to sequester carbon dioxide from the Earth's oceans and atmosphere, as part of climate change mitigation. Olivine also has many other historical uses, such as the gemstone peridot (or chrysolite), as well as industrial applications like metalworking processes.

Rock (geology) Naturally occurring mineral aggregate

A rock is any naturally occurring solid mass or aggregate of minerals or mineraloid matter. It is categorized by the minerals included, its chemical composition and the way in which it is formed. Rocks form the Earth's outer solid layer, the crust, and most of its interior, except for the liquid outer core and pockets of magma in the asthenosphere.

Andesite Intermediate volcanic rock

Andesite is an extrusive volcanic rock of intermediate composition. In a general sense, it is the intermediate type between basalt and rhyolite. It is fine-grained (aphanitic) to porphyritic in texture, and is composed predominantly of sodium-rich plagioclase plus pyroxene or hornblende.

Volcanic rock Rock formed from lava erupted from a volcano

Volcanic rock is a rock formed from lava erupted from a volcano. In other words, it differs from other igneous rock by being of volcanic origin. Like all rock types, the concept of volcanic rock is artificial, and in nature volcanic rocks grade into hypabyssal and metamorphic rocks and constitute an important element of some sediments and sedimentary rocks. For these reasons, in geology, volcanics and shallow hypabyssal rocks are not always treated as distinct. In the context of Precambrian shield geology, the term "volcanic" is often applied to what are strictly metavolcanic rocks. Volcanic rocks and sediment that form from magma erupted into the air are called "volcaniclastics," and these are technically sedimentary rocks.

Peridotite A coarse-grained ultramafic igneous rock

Peridotite ( PERR-ih-doh-tyte, pə-RID-ə-) is a dense, coarse-grained igneous rock consisting mostly of the silicate minerals olivine and pyroxene. Peridotite is ultramafic, as the rock contains less than 45% silica. It is high in magnesium (Mg2+), reflecting the high proportions of magnesium-rich olivine, with appreciable iron. Peridotite is derived from Earth's mantle, either as solid blocks and fragments, or as crystals accumulated from magmas that formed in the mantle. The compositions of peridotites from these layered igneous complexes vary widely, reflecting the relative proportions of pyroxenes, chromite, plagioclase, and amphibole.

Phenocryst Crystal larger than the rock grains that surround it in an igneous rock

A phenocryst is an early forming, relatively large and usually conspicuous crystal distinctly larger than the grains of the rock groundmass of an igneous rock. Such rocks that have a distinct difference in the size of the crystals are called porphyries, and the adjective porphyritic is used to describe them. Phenocrysts often have euhedral forms, either due to early growth within a magma, or by post-emplacement recrystallization. Normally the term phenocryst is not used unless the crystals are directly observable, which is sometimes stated as greater than .5 millimeter in diameter. Phenocrysts below this level, but still larger than the groundmass crystals, are termed microphenocrysts. Very large phenocrysts are termed megaphenocrysts. Some rocks contain both microphenocrysts and megaphenocrysts. In metamorphic rocks, crystals similar to phenocrysts are called porphyroblasts.

Forsterite Magnesium end-member of olivine, a nesosilicate mineral

Forsterite (Mg2SiO4; commonly abbreviated as Fo; also known as white olivine) is the magnesium-rich end-member of the olivine solid solution series. It is isomorphous with the iron-rich end-member, fayalite. Forsterite crystallizes in the orthorhombic system (space group Pbnm) with cell parameters a 4.75 Å (0.475 nm), b 10.20 Å (1.020 nm) and c 5.98 Å (0.598 nm).

Formation of rocks

Terrestrial rocks are formed by three main mechanisms:

Komatiite Ultramafic mantle-derived volcanic rock

Komatiite is a type of ultramafic mantle-derived volcanic rock defined as having crystallised from a lava of at least 18 wt% MgO. Komatiites have low silicon, potassium and aluminium, and high to extremely high magnesium content. Komatiite was named for its type locality along the Komati River in South Africa, and frequently displays spinifex texture composed of large dendritic plates of olivine and pyroxene.

Restite is the residual material left at the site of melting during the in place production of granite through intense metamorphism.

Cumulate rock

Cumulate rocks are igneous rocks formed by the accumulation of crystals from a magma either by settling or floating. Cumulate rocks are named according to their texture; cumulate texture is diagnostic of the conditions of formation of this group of igneous rocks. Cumulates can be deposited on top of other older cumulates of different composition and colour, typically giving the cumulate rock a layered or banded appearance.

In geology, igneous differentiation, or magmatic differentiation, is an umbrella term for the various processes by which magmas undergo bulk chemical change during the partial melting process, cooling, emplacement, or eruption. The sequence of magmas produced by igneous differentiation is known as a magma series.

The tholeiitic magma series is one of two main magma series in subalkaline igneous rocks, the other being the calc-alkaline series. A magma series is a chemically distinct range of magma compositions that describes the evolution of a mafic magma into a more evolved, silica rich end member. Rock types of the tholeiitic magma series include tholeiitic basalt, ferro-basalt, tholeiitic basaltic andesite, tholeiitic andesite, dacite and rhyolite. The variety of basalt in the series was originally called tholeiite but the International Union of Geological Sciences recommends that tholeiitic basalt be used in preference to that term.

Fractional crystallization (geology) One of the main processes of magmatic differentiation

Fractional crystallization, or crystal fractionation, is one of the most important geochemical and physical processes operating within crust and mantle of a rocky planetary body, such as the Earth. It is important in the formation of igneous rocks because it is one of the main processes of magmatic differentiation. Fractional crystallization is also important in the formation of sedimentary evaporite rocks.

The calc-alkaline magma series is one of two main subdivisions of the subalkaline magma series, the other subalkaline magma series being the tholeiitic series. A magma series is a series of compositions that describes the evolution of a mafic magma, which is high in magnesium and iron and produces basalt or gabbro, as it fractionally crystallizes to become a felsic magma, which is low in magnesium and iron and produces rhyolite or granite. Calc-alkaline rocks are rich in alkaline earths and alkali metals and make up a major part of the crust of the continents.

Igneous rock Rock formed through the cooling and solidification of magma or lava

Igneous rock, or magmatic rock, is one of the three main rock types, the others being sedimentary and metamorphic. Igneous rock is formed through the cooling and solidification of magma or lava.

São Tomé and Príncipe both formed within the past 30 million years due to volcanic activity in deep water along the Cameroon line. Long-running interactions with seawater and different eruption periods have generated a wide variety of different igneous and volcanic rocks on the islands with complex mineral assemblages.

References

  1. Tilley, C. E. (1957). "Norman Levi Bowen 1887-1956". Biographical Memoirs of Fellows of the Royal Society. 3: 6–26. doi:10.1098/rsbm.1957.0002. JSTOR   769349. S2CID   73262622.
  2. Bowen, N.L. (1956). The Evolution of the Igneous Rocks. Canada: Dover. pp. 60–62.
  3. Klein, Cornelis and Cornelius S. Hurlbut, Jr., Manual of Mineralogy, Wiley, 20th ed. 1985, p. 476 ISBN   0-471-80580-7