A coordination complex is a chemical compound consisting of a central atom or ion, which is usually metallic and is called the coordination centre, and a surrounding array of bound molecules or ions, that are in turn known as ligands or complexing agents. Many metal-containing compounds, especially those that include transition metals, are coordination complexes.
A deltahedron is a polyhedron whose faces are all equilateral triangles. The deltahedron is named by Martyn Cundy, after the Greek capital letter delta resembling a triangular shape Δ. The deltahedron can be categorized by the property of convexity. There are eight convex deltahedra, which can be used in the applications of chemistry as in the polyhedral skeletal electron pair theory and chemical compounds. Omitting the convex property leaves the results in infinitely many deltahedrons alongside its subclasses recognition.
In geometry, the gyroelongated square bipyramid is a polyhedron with 16 triangular faces. it can be constructed from a square antiprism by attaching two equilateral square pyramids to each of its square faces. The same shape is also called hexakaidecadeltahedron, heccaidecadeltahedron, or tetrakis square antiprism; these last names mean a polyhedron with 16 triangular faces. It is an example of deltahedron, and of a Johnson solid.
The triaugmented triangular prism, in geometry, is a convex polyhedron with 14 equilateral triangles as its faces. It can be constructed from a triangular prism by attaching equilateral square pyramids to each of its three square faces. The same shape is also called the tetrakis triangular prism, tricapped trigonal prism, tetracaidecadeltahedron, or tetrakaidecadeltahedron; these last names mean a polyhedron with 14 triangular faces. It is an example of a deltahedron, composite polyhedron, and Johnson solid.
Valence shell electron pair repulsion (VSEPR) theory is a model used in chemistry to predict the geometry of individual molecules from the number of electron pairs surrounding their central atoms. It is also named the Gillespie-Nyholm theory after its two main developers, Ronald Gillespie and Ronald Nyholm.
In geometry, the gyroelongated square pyramid is the Johnson solid that can be constructed by attaching an equilateral square pyramid to a square antiprism. It occurs in chemistry; for example, the square antiprismatic molecular geometry.
In geometry, the biaugmented triangular prism is a polyhedron constructed from a triangular prism by attaching two equilateral square pyramids onto two of its square faces. It is an example of Johnson solid. It can be found in stereochemistry in bicapped trigonal prismatic molecular geometry.
In chemistry, octahedral molecular geometry, also called square bipyramidal, describes the shape of compounds with six atoms or groups of atoms or ligands symmetrically arranged around a central atom, defining the vertices of an octahedron. The octahedron has eight faces, hence the prefix octa. The octahedron is one of the Platonic solids, although octahedral molecules typically have an atom in their centre and no bonds between the ligand atoms. A perfect octahedron belongs to the point group Oh. Examples of octahedral compounds are sulfur hexafluoride SF6 and molybdenum hexacarbonyl Mo(CO)6. The term "octahedral" is used somewhat loosely by chemists, focusing on the geometry of the bonds to the central atom and not considering differences among the ligands themselves. For example, [Co(NH3)6]3+, which is not octahedral in the mathematical sense due to the orientation of the N−H bonds, is referred to as octahedral.
In geometry, a triangular prism or trigonal prism is a prism with 2 triangular bases. If the edges pair with each triangle's vertex and if they are perpendicular to the base, it is a right triangular prism. A right triangular prism may be both semiregular and uniform.
In geometry, the square antiprism is the second in an infinite family of antiprisms formed by an even-numbered sequence of triangle sides closed by two polygon caps. It is also known as an anticube.
In 4-dimensional geometry, a uniform antiprismatic prism or antiduoprism is a uniform 4-polytope with two uniform antiprism cells in two parallel 3-space hyperplanes, connected by uniform prisms cells between pairs of faces. The symmetry of a p-gonal antiprismatic prism is [2p,2+,2], order 8p.
In chemistry, the square antiprismatic molecular geometry describes the shape of compounds where eight atoms, groups of atoms, or ligands are arranged around a central atom, defining the vertices of a square antiprism. This shape has D4d symmetry and is one of the three common shapes for octacoordinate transition metal complexes, along with the dodecahedron and the bicapped trigonal prism.
In chemistry, the trigonal prismatic molecular geometry describes the shape of compounds where six atoms, groups of atoms, or ligands are arranged around a central atom, defining the vertices of a triangular prism. The structure commonly occurs for d0, d1 and d2 transition metal complexes with covalently-bound ligands and small charge separation. In d0 complexes it may be ascribed to sd5 hybridization, but in d1 and d2 complexes the dz2 orbital is occupied by nonbonding electron (pair). Furthermore, when unoccupied, said orbital participates in bonding and causes C3v distortion, like in W(CH3)6.
In chemistry, the tricapped trigonal prismatic molecular geometry describes the shape of compounds where nine atoms, groups of atoms, or ligands are arranged around a central atom, defining the vertices of a triaugmented triangular prism.
In chemistry, the capped octahedral molecular geometry describes the shape of compounds where seven atoms or groups of atoms or ligands are arranged around a central atom defining the vertices of a gyroelongated triangular pyramid. This shape has C3v symmetry and is one of the three common shapes for heptacoordinate transition metal complexes, along with the pentagonal bipyramid and the capped trigonal prism.
In geometry, a diminished trapezohedron is a polyhedron in an infinite set of polyhedra, constructed by removing one of the polar vertices of a trapezohedron and replacing it by a new face (diminishment). It has one regular n-gonal base face, n triangle faces around the base, and n kites meeting on top. The kites can also be replaced by rhombi with specific proportions.
In chemistry, the capped trigonal prismatic molecular geometry describes the shape of compounds where seven atoms or groups of atoms or ligands are arranged around a central atom defining the vertices of an augmented triangular prism. This shape has C2v symmetry and is one of the three common shapes for heptacoordinate transition metal complexes, along with the pentagonal bipyramid and the capped octahedron.
In chemistry, the dodecahedral molecular geometry describes the shape of compounds where eight atoms or groups of atoms or ligands are arranged around a central atom defining the vertices of a snub disphenoid. This shape has D2d symmetry and is one of the three common shapes for octacoordinate transition metal complexes, along with the square antiprism and the bicapped trigonal prism.
In chemistry, the bicapped trigonal prismatic molecular geometry describes the shape of compounds where eight atoms or groups of atoms or ligands are arranged around a central atom defining the vertices of a biaugmented triangular prism. This shape has C2v symmetry and is one of the three common shapes for octacoordinate transition metal complexes, along with the square antiprism and the dodecahedron.
