Carminite

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Carminite
Carminite-170211.jpg
Carminite from the Alto das Quelhas do Gestoso Mines, Gestoso, Manhouce, São Pedro do Sul, Viseu District, Portugal. Picture width 1.5 mm.
General
Category Arsenate minerals
Formula
(repeating unit)
PbFe3+2(AsO4)2(OH)2
IMA symbol Cmt [1]
Strunz classification 8.BH.30 (10 ed)
7/B.28-40 (8 ed)
Dana classification41 Anhydrous phosphates, arsenates and vanadates containing hydroxyl or halogen
Crystal system Orthorhombic
Crystal class Dipyramidal (mmm)
H-M symbol: (2/m 2/m 2/m)
Space group Cccm
Unit cell a = 16.591 Å,
b = 7.58 Å,
c = 12.285 Å; Z = 8
Identification
Formula mass 639.87 g/mol
ColourCarmine red
Crystal habit Typically bladed crystals, also acicular crystals, in spherical or tufted aggregates and as fibrous or drusy masses
Cleavage Distinct on {110}
Tenacity Brittle (D, All)
Mohs scale hardness3+12
Lustre Vitreous, pearly on cleavages
Streak Reddish yellow
Diaphaneity Translucent
Specific gravity 5.03–5.18
Optical propertiesBiaxial (+)
Refractive index nα = 2.070, nβ = 2.070, nγ = 2.080
Birefringence 0.010
Pleochroism strong, X= pale yellowish red; Y=Z= dark carmine red
Solubility Slowly soluble in HCl with the separation of PbCl2, and totally soluble in HNO3
Other characteristicsCarminite is not radioactive. No piezoelectric effect could be detected [2]
References [3] [4] [5] [6] [7]
Carminite from the Alto das Quelhas do Gestoso Mines, Gestoso, Manhouce, Sao Pedro do Sul, Viseu District, Portugal. Picture width 8 mm Carminite-170210.jpg
Carminite from the Alto das Quelhas do Gestoso Mines, Gestoso, Manhouce, São Pedro do Sul, Viseu District, Portugal. Picture width 8 mm
Blue scorodite crystals on red brown carminite from Alto das Quelhas do Gestoso Mines, Gestoso, Manhouce, Sao Pedro do Sul, Viseu District, Portugal. Picture width 3 mm. Scorodite-Carminite-170220.jpg
Blue scorodite crystals on red brown carminite from Alto das Quelhas do Gestoso Mines, Gestoso, Manhouce, São Pedro do Sul, Viseu District, Portugal. Picture width 3 mm.

Carminite (PbFe3+2(AsO4)2(OH)2 [8] ) is an anhydrous arsenate mineral containing hydroxyl.[ citation needed ] It is a rare secondary mineral that is structurally related to palermoite (Li2SrAl4(PO4)4(OH)4). [8] Sewardite (CaFe3+2(AsO4)2(OH)2) is an analogue of carminite, with calcium in sewardite in place of the lead in carminite. Mawbyite is a dimorph (same formula, different structure) of carminite; mawbyite is monoclinic and carminite is orthorhombic. [4] It has a molar mass of 639.87 g. [5] It was discovered in 1850 [4] and named for the characteristic carmine colour. [5] [6]

Contents

Structure

Carminite belongs to the orthorhombic crystal class (2/m 2/m 2/m) and has space group C ccm or C cc2. [9] The structure consists of linked octahedra of iron surrounded by oxygen and hydroxyl which are aligned parallel to the c axis. They are connected together in the direction of the a axis by arsenate tetrahedra (arsenic surrounded by 4 oxygen). Coordination about the lead atoms is eight-fold. [9] The edges of the unit cell have lengths a = 16.59 Å, b = 7.58 Å and c = 12.295 Å. There are 8 formula units in each unit cell (Z = 8). [9]

Appearance

Crystals have been found up to 2 cm long, though most are smaller. They are typically bladed, elongated along the c axis and flattened perpendicular to the b axis. They also occur as acicular crystals, in spherical or tufted aggregates and as fibrous or drusy masses. [4] [6] [7] The crystals are a characteristic carmine red colour, hence the name, and they are also red in transmitted light. They are translucent with a vitreous lustre and a reddish yellow streak. [4] [6] [7]

Physical properties

Carminite is fairly soft, with a Mohs hardness of 3+12, between that of calcite and fluorite. Because of the lead content it is heavy, with specific gravity of 5.03 – 5.18, although specimens from Mapimi are less dense at 4.10. [7] Cleavage is distinct in one direction parallel to the c axis. [4] [6] [7] The mineral is slowly soluble in hydrochloric acid (HCl) with the separation of lead(II) chloride (PbCl2) and totally soluble in nitric acid (HNO3). [4] [7] Carminite is not radioactive [5] and no piezoelectric effect has been detected. [2]

Optical properties

Orthorhombic crystals (and monoclinic and triclinic crystals) have two directions in which light travels with zero birefringence; these directions are called the optic axes, and the crystal is said to be biaxial. The speed of a ray of light travelling through the crystal differs with direction. The direction of the fastest ray is called the X direction and the direction of the slowest ray is called the Z direction. X and Z are perpendicular to each other and a third direction Y is defined as perpendicular to both X and Z; light travelling along Y has an intermediate speed. Refractive index is inversely proportional to speed, so the refractive indices for the X, Y and Z directions increase from X to Z. [10]

Carminite is crystal axes a, b and c, but not necessarily in that order. [10] For carminite the orientation is X = c, Y = a and Z = b [6] [7] and the refractive indices are high, with nα = 2.070, nβ = 2.070, nγ = 2.080, only a little less than diamond at 2.4. [7] [11]

The maximum birefringence δ is the difference between the highest and lowest refractive index; for carminite δ = 0.010.
The angle between the two optic axes is called the optic angle, 2V, and it is always acute, and bisected either by X or by Z. If Z is the bisector then the crystal is said to be positive, and if X is the bisector it is said to be negative. [10] Carminite is biaxial (+) and 2V is moderate to large. [7] [11] 2V depends on the refractive indices, but refractive index varies with wavelength, and hence with colour. So 2V also depends on the colour, and is different for red and for violet light. This effect is called dispersion of the optic axes, or just dispersion (not to be confused with chromatic dispersion). If 2V is greater for red light than for violet light the dispersion is designated r > v, and vice versa. For carminite the dispersion is strong, with r < v. [7] [11]
The mineral exhibits strong pleochroism; when viewed along the X direction it appears pale yellowish red and dark carmine red along the Y and Z directions. Absorption is equal along the Y and Z optic directions, but less along the X optic direction. [6] [11]
When a birefringent crystal is rotated between crossed polarizers it will turn dark every 90° of rotation. This effect is known as extinction. Carminite exhibits the parallel extinction [11] that is characteristic of orthorhombic crystals. [10]

Occurrence

Carminite is formed as an uncommon alteration product of arsenopyrite (FeAsS) in the oxidized zones of some lead-bearing deposits. [4] [5] [6] Common associates are wulfenite, scorodite, plumbojarosite, mimetite, dussertite, cerussite, beudantite, bayldonite, arseniosiderite and anglesite. [4] [6]

The type locality is the Louise Mine, Bürdenbach, Altenkirchen, Wied Iron Spar District, Westerwald, Rhineland-Palatinate, Germany [4] where it is associated with beudantite. [4] [7] At the Hingston Down Consols mine in Cornwall, England, carminite occurs with scorodite, mimetite and pharmacosiderite. [7]

The ores of the Ojuela Mine, Mexico, are replacement deposits in limestone and consist of galena, sphalerite, pyrite, and arsenopyrite in a matrix of quartz, dolomite and fluorite. Arsenopyrite is abundant. On a dump near the north shaft blocks of massive scorodite containing seams and pockets of arseniosiderite and small areas of dussertite and carminite have been found. Carminite also occurs as masses mixed with cerussite, anglesite and plumbojarosite. It is almost always intimately associated with arseniosiderite and dussertite. [11]

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<span class="mw-page-title-main">Alstonite</span>

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, sometimes with some strontium. Barytocalcite and paralstonite have the same formula but different structures, so these three minerals are said to be trimorphous. Alstonite is triclinic but barytocalcite is monoclinic and paralstonite is trigonal. The species was named Bromlite by Thomas Thomson in 1837 after the Bromley-Hill mine, and alstonite by August Breithaupt of the Freiberg Mining Academy in 1841, after Alston, Cumbria, the base of operations of the mineral dealer from whom the first samples were obtained by Thomson in 1834. Both of these names have been in common use.

<span class="mw-page-title-main">Barytocalcite</span>

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<span class="mw-page-title-main">Todorokite</span> Hydrous manganese oxide mineral

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1-x
(Mn,Mg,Al)
6
O
12
·3-4H
2
O
. It was named in 1934 for the type locality, the Todoroki mine, Hokkaido, Japan. It belongs to the prismatic class 2/m of the monoclinic crystal system, but the angle β between the a and c axes is close to 90°, making it seem orthorhombic. It is a brown to black mineral which occurs in massive or tuberose forms. It is quite soft with a Mohs hardness of 1.5, and a specific gravity of 3.49 – 3.82. It is a component of deep ocean basin manganese nodules.

<span class="mw-page-title-main">Vauxite</span> Phosphate mineral

Vauxite is a phosphate mineral with the chemical formula Fe2+Al2(PO4)2(OH)2·6(H2O). It belongs to the laueite – paravauxite group, paravauxite subgroup, although Mindat puts it as a member of the vantasselite Al4(PO4)3(OH)3·9H2O group. There is no similarity in structure between vauxite and paravauxite Fe2+Al2(PO4)2(OH)2·8H2O or metavauxite Fe3+Al2(PO4)2(OH)2·8H2O, even though they are closely similar chemically and all minerals occur together as secondary minerals. Vauxite was named in 1922 for George Vaux Junior (1863–1927), an American attorney and mineral collector.

<span class="mw-page-title-main">Beudantite</span> Secondary mineral of the alunite group

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<span class="mw-page-title-main">Magnesiohastingsite</span>

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<span class="mw-page-title-main">Köttigite</span>

Köttigite is a rare hydrated zinc arsenate which was discovered in 1849 and named by James Dwight Dana in 1850 in honour of Otto Friedrich Köttig (1824–1892), a German chemist from Schneeberg, Saxony, who made the first chemical analysis of the mineral. It has the formula Zn3(AsO4)2·8H2O and it is a dimorph of metaköttigite, which means that the two minerals have the same formula, but a different structure: köttigite is monoclinic and metaköttigite is triclinic. There are several minerals with similar formulae but with other cations in place of the zinc. Iron forms parasymplesite Fe2+3(AsO4)2·8H2O; cobalt forms the distinctively coloured pinkish purple mineral erythrite Co3(AsO4)2·8H2O and nickel forms annabergite Ni3(AsO4)2·8H2O. Köttigite forms series with all three of these minerals and they are all members of the vivianite group.

<span class="mw-page-title-main">Serpierite</span>

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<span class="mw-page-title-main">Mottramite</span>

Mottramite is an orthorhombic anhydrous vanadate hydroxide mineral, PbCu(VO4)(OH), at the copper end of the descloizite subgroup. It was formerly called cuprodescloizite or psittacinite (this mineral characterized in 1868 by Frederick Augustus Genth). Duhamelite is a calcium- and bismuth-bearing variety of mottramite, typically with acicular habit.

<span class="mw-page-title-main">Talmessite</span>

Talmessite is a hydrated calcium magnesium arsenate, often with significant amounts of cobalt or nickel. It was named in 1960 for the type locality, the Talmessi mine, Anarak district, Iran. It forms a series with β-Roselite, where cobalt replaces some of the magnesium, and with gaitite, where zinc replaces the magnesium. All these minerals are members of the fairfieldite group. Talmessite is dimorphic with wendwilsonite.

Raygrantite is a mineral first discovered in Big Horn Mountains, Maricopa County, Arizona, US. More specifically, it is located in the evening star mine, which is a Cu, V, Pb, Ag, Au, and W mine. Raygrantite is a member of the iranite mineral group, which consists of hemihedrite, iranite, and raygrantite. This mineral received its name in honor of Raymond W. Grant, a retired professor who primarily focused on the minerals of Arizona. The typical crystal structure of raygrantite is bladed with parallel striations to the C axis. Its ideal chemical formula is Pb10Zn(SO4)6(SiO4)2(OH)2. The IMA (International Mineralogical Association) approved raygrantite in 2013, and the first publication regarding this mineral was put forth in 2017.

References

  1. Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine. 85 (3): 291–320. Bibcode:2021MinM...85..291W. doi: 10.1180/mgm.2021.43 . S2CID   235729616.
  2. 1 2 Rosenzweig, A and Finney, J J Finney (1959) American Mineralogist 44: 663–665
  3. Mineralienatlas
  4. 1 2 3 4 5 6 7 8 9 10 11 Carminite on Mindat.org
  5. 1 2 3 4 5 Carminite data on Webmineral
  6. 1 2 3 4 5 6 7 8 9 Carminite in the Handbook of Mineralogy
  7. 1 2 3 4 5 6 7 8 9 10 11 12 Gaines et al (1997) Dana's New Mineralogy, Eighth Edition. Wiley
  8. 1 2 "Commission on New Minerals, Nomenclature and Classification". Archived from the original on 2011-12-29. Retrieved 2014-09-19.
  9. 1 2 3 Finney J J (1963) American Mineralogist 48: 1–13
  10. 1 2 3 4 Klein and Hurlbut (1993) Manual of Mineralogy 21st Edition. Wiley
  11. 1 2 3 4 5 6 Foshag (1937) American Mineralogist 22: 479–484