Corrosion in space

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Corrosion in space is the corrosion of materials occurring in outer space. Instead of moisture and oxygen acting as the primary corrosion causes, the materials exposed to outer space are subjected to vacuum, bombardment by ultraviolet and X-rays, and high-energy charged particles (mostly electrons and protons from solar wind). In the upper layers of the atmosphere (between 90–800 km), the atmospheric atoms, ions, and free radicals, most notably atomic oxygen, play a major role. The concentration of atomic oxygen depends on altitude and solar activity, as the bursts of ultraviolet radiation cause photodissociation of molecular oxygen. [1] Between 160 and 560 km, the atmosphere consists of about 90% atomic oxygen. [2]

Contents

Materials

Corrosion in space has the highest impact on spacecraft with moving parts. Early satellites tended to develop problems with seizing bearings. Now the bearings are coated with a thin layer of gold.

Different materials resist corrosion in space differently. For example, aluminium is slowly eroded by atomic oxygen, while gold and platinum are highly corrosion-resistant. Gold-coated foils and thin layers of gold on exposed surfaces are therefore used to protect the spacecraft from the harsh environment. Thin layers of silicon dioxide deposited on the surfaces can also protect metals from the effects of atomic oxygen; e.g., the Starshine 3 satellite aluminium front mirrors were protected that way. However, the protective layers are subject to erosion by micrometeorites.

Silver builds up a layer of silver oxide, which tends to flake off and has no protective function; such gradual erosion of silver interconnects of solar cells was found to be the cause of some observed in-orbit failures. [3]

Many plastics are considerably sensitive to atomic oxygen and ionizing radiation. Coatings resistant to atomic oxygen are a common protection method, especially for plastics. Silicone-based paints and coatings are frequently employed, due to their excellent resistance to radiation and atomic oxygen. [4] However, the silicone durability is somewhat limited, as the surface exposed to atomic oxygen is converted to silica which is brittle and tends to crack.

Solving corrosion

The process of space corrosion is being actively investigated. One of the efforts aims to design a sensor based on zinc oxide, able to measure the amount of atomic oxygen in the vicinity of the spacecraft; the sensor relies on drop of electrical conductivity of zinc oxide as it absorbs further oxygen. [ citation needed ]

Other problems

The outgassing of volatile silicones on low Earth orbit devices leads to presence of a cloud of contaminants around the spacecraft. Together with atomic oxygen bombardment, this may lead to gradual deposition of thin layers of carbon-containing silicon dioxide. Their poor transparency is a concern in case of optical systems and solar panels. Deposits of up to several micrometers were observed after 10 years of service on the solar panels of the Mir space station. [5]

Other sources of problems for structures subjected to outer space are erosion and redeposition of the materials by sputtering caused by fast atoms and micrometeoroids. Another major concern, though of non-corrosive kind, is material fatigue caused by cyclical heating and cooling and associated thermal expansion mechanical stresses.

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Interplanetary spaceflight Crewed or uncrewed travel between stars or planets

Interplanetary spaceflight or interplanetary travel is the crewed or uncrewed travel between stars and planets, usually within a single planetary system. In practice, spaceflights of this type are confined to travel between the planets of the Solar System. Uncrewed space probes have flown to all the observed planets in the Solar System as well as to dwarf planets Pluto and Ceres, and several asteroids. Orbiters and landers return more information than fly-by missions. Crewed flights have landed on the Moon and have been planned, from time to time, for Mars and Venus. While many scientists appreciate the knowledge value that uncrewed flights provide, the value of crewed missions is more controversial. Science fiction writers propose a number of benefits, including the mining of asteroids, access to solar power, and room for colonization in the event of an Earth catastrophe.

Ozone layer Region of Earths stratosphere that absorbs most of the Suns ultraviolet radiation

The ozone layer or ozone shield is a region of Earth's stratosphere that absorbs most of the Sun's ultraviolet radiation. It contains a high concentration of ozone (O3) in relation to other parts of the atmosphere, although still small in relation to other gases in the stratosphere. The ozone layer contains less than 10 parts per million of ozone, while the average ozone concentration in Earth's atmosphere as a whole is about 0.3 parts per million. The ozone layer is mainly found in the lower portion of the stratosphere, from approximately 15 to 35 kilometers (9 to 22 mi) above Earth, although its thickness varies seasonally and geographically.

Rust Type of iron oxide

Rust is an iron oxide, a usually reddish-brown oxide formed by the reaction of iron and oxygen in the catalytic presence of water or air moisture. Rust consists of hydrous iron(III) oxides (Fe2O3·nH2O) and iron(III) oxide-hydroxide (FeO(OH), Fe(OH)3), and is typically associated with the corrosion of refined iron.

Ganymede (moon) Largest moon of Jupiter and in the Solar System

Ganymede, a satellite of Jupiter, is the largest and most massive of the Solar System's moons. The ninth-largest object of the Solar System, it is the largest without a substantial atmosphere. It has a diameter of 5,268 km (3,273 mi), making it 26 percent larger than the planet Mercury by volume, although it is only 45 percent as massive. Possessing a metallic core, it has the lowest moment of inertia factor of any solid body in the Solar System and is the only moon known to have a magnetic field. Outward from Jupiter, it is the seventh satellite and the third of the Galilean moons, the first group of objects discovered orbiting another planet. Ganymede orbits Jupiter in roughly seven days and is in a 1:2:4 orbital resonance with the moons Europa and Io, respectively.

The exosphere is a thin, atmosphere-like volume surrounding a planet or natural satellite where molecules are gravitationally bound to that body, but where the density is so low that the molecules are essentially collisionless. In the case of bodies with substantial atmospheres, such as Earth's atmosphere, the exosphere is the uppermost layer, where the atmosphere thins out and merges with outer space. It is located directly above the thermosphere. Very little is known about it due to lack of research. Mercury, the Moon, Europa, and Ganymede have surface boundary exospheres, which are exospheres without a denser atmosphere underneath. The Earth's exosphere is mostly hydrogen and helium, with some heavier atoms and molecules near the base.

Corrosion Gradual destruction of materials by chemical reaction with its environment

Corrosion is a natural process that converts a refined metal into a more chemically stable form such as oxide, hydroxide, carbonate or sulfide. It is the gradual destruction of materials by chemical or electrochemical reaction with their environment. Corrosion engineering is the field dedicated to controlling and preventing corrosion.

Atmosphere of Earth Gas layer surrounding Earth

The atmosphere of Earth, commonly known as air, is the layer of gases retained by Earth's gravity that surrounds the planet and forms its planetary atmosphere. The atmosphere of Earth protects life on Earth by creating pressure allowing for liquid water to exist on the Earth's surface, absorbing ultraviolet solar radiation, warming the surface through heat retention, and reducing temperature extremes between day and night.

Atmosphere Layer of gases surrounding an astronomical body held by gravity

An atmosphere is a layer of gas or layers of gases that envelope a planet, and is held in place by the gravity of the planetary body. A planet retains an atmosphere when the gravity is great and the temperature of the atmosphere is low. A stellar atmosphere is the outer region of a star, which includes the layers above the opaque photosphere; stars of low temperature might have outer atmospheres containing compound molecules.

Flux (metallurgy)

In metallurgy, a flux is a chemical cleaning agent, flowing agent, or purifying agent. Fluxes may have more than one function at a time. They are used in both extractive metallurgy and metal joining.

Solar mirror Type of mirror designed for sunlight

A solar mirror contains a substrate with a reflective layer for reflecting the solar energy, and in most cases an interference layer. This may be a planar mirror or parabolic arrays of solar mirrors used to achieve a substantially concentrated reflection factor for solar energy systems.

Silvering is the chemical process of coating a non-conductive substrate such as glass with a reflective substance, to produce a mirror. While the metal is often silver, the term is used for the application of any reflective metal.

Aluminium bronze

Aluminium bronze is a type of bronze in which aluminium is the main alloying metal added to copper, in contrast to standard bronze or brass. A variety of aluminium bronzes of differing compositions have found industrial use, with most ranging from 5% to 11% aluminium by weight, the remaining mass being copper; other alloying agents such as iron, nickel, manganese, and silicon are also sometimes added to aluminium bronzes.

A diffusion barrier is a thin layer of metal usually placed between two other metals. It is done to act as a barrier to protect either one of the metals from corrupting the other.

Space blanket Aluminized plastic sheet used to protect against heat in space

A space blanket is an especially low-weight, low-bulk blanket made of heat-reflective, thin, plastic sheeting. They are used on the exterior surfaces of spacecraft for thermal control, as well as by people. Their design reduces the heat loss in a person's body, which would otherwise occur due to thermal radiation, water evaporation, or convection. Their low weight and compact size before unfurling make them ideal when space or weight are at a premium. They may be included in first aid kits and with camping equipment. Lost campers and hikers have an additional possible benefit: the shiny surface flashes in the sun, allowing its use as an improvised distress beacon for searchers and as a method of signalling over long distances to other people.

Embrittlement

Embrittlement is a significant decrease of ductility of a material, which makes the material brittle. Embrittlement is used to describe any phenomena where the environment compromises a stressed material's mechanical performance, such as temperature or environmental composition. This is oftentimes undesirable as brittle fracture occurs quicker and can much more easily propagate than ductile fracture, leading to complete failure of the equipment. Various materials have different mechanisms of embrittlement, therefore it can manifest in a variety of ways, from slow crack growth to a reduction of tensile ductility and toughness.

Polyphenyl ether Class of polymers

Phenyl ether polymers are a class of polymers that contain a phenoxy or a thiophenoxy group as the repeating group in ether linkages. Commercial phenyl ether polymers belong to two chemical classes: polyphenyl ethers (PPEs) and polyphenylene oxides (PPOs). The phenoxy groups in the former class of polymers do not contain any substituents whereas those in the latter class contain 2 to 4 alkyl groups on the phenyl ring. The structure of an oxygen-containing PPE is provided in Figure 1 and that of a 2, 6-xylenol derived PPO is shown in Figure 2. Either class can have the oxygen atoms attached at various positions around the rings.

Solid State of matter

Solid is one of the four fundamental states of matter. The molecules in a solid are closely packed together and contain the least amount of kinetic energy. A solid is characterized by structural rigidity and resistance to a force applied to the surface. Unlike a liquid, a solid object does not flow to take on the shape of its container, nor does it expand to fill the entire available volume like a gas. The atoms in a solid are bound to each other, either in a regular geometric lattice, or irregularly. Solids cannot be compressed with little pressure whereas gases can be compressed with little pressure because the molecules in a gas are loosely packed.

Materials for use in vacuum

Materials for use in vacuum are materials that show very low rates of outgassing in vacuum and, where applicable, are tolerant to bake-out temperatures. The requirements grow increasingly stringent with the desired degree of vacuum to be achieved in the vacuum chamber. The materials can produce gas by several mechanisms. Molecules of gases and water can be adsorbed on the material surface. Materials may sublimate in vacuum. Or the gases can be released from porous materials or from cracks and crevices. Traces of lubricants, residues from machining, can be present on the surfaces. A specific risk is outgassing of solvents absorbed in plastics after cleaning.

Spacecraft thermal control

In spacecraft design, the function of the thermal control system (TCS) is to keep all the spacecraft's component systems within acceptable temperature ranges during all mission phases. It must cope with the external environment, which can vary in a wide range as the spacecraft is exposed to deep space or to solar or planetary flux, and with ejecting to space the internal heat generated by the operation of the spacecraft itself.

Student Nitric Oxide Explorer NASA satellite of the Explorer program

Student Nitric Oxide Explorer, was a NASA small scientific satellite which studied the concentration of nitric oxide in the thermosphere. It was launched in 1998 as part of NASA's Explorer program. The satellite was the first of three missions developed within the Student Explorer Demonstration Initiative (STEDI) program funded by the NASA and managed by the Universities Space Research Association (USRA). STEDI was a pilot program to demonstrate that high-quality space science can be carried out with small, low-cost free-flying satellites on a time scale of two years from go-ahead to launch. The satellite was developed by the University of Colorado Boulder's Laboratory for Atmospheric and Space Physics (LASP) and had met its goals by the time its mission ended with reentry in December 2003.

References

  1. Martines, S. "Analysis of LEO Radiation Environment and itsEffects on Spacecraft's Critical Electronic Dev ices". Mendeley. Embry Riddle Aeronautical University. Retrieved 23 August 2019.
  2. The Use of Silicone Adhesives in Space Applications
  3. Myer Kutz - Handbook of Environmental Degradation of Materials (2005, 0815515006)
  4. "Optimizing Atomic Oxygen Resistance on Coated Substrates Using TechOptimizer". Archived from the original on 2006-06-24. Retrieved 2006-06-07.
  5. Banks, Bruce A.; De Groh, Kim K.; Rutledge, Sharon K.; Haytas, Christy A. (1999). "Consequences of atomic oxygen interaction with silicone and silicone contamination on surfaces in low earth orbit". Proc. SPIE. 3784: 62. Bibcode:1999SPIE.3784...62B. CiteSeerX   10.1.1.870.5957 . doi:10.1117/12.366725. hdl:2060/19990047772.