Deoxy sugar

Last updated
Ribofuranose-2D-skeletal.png

Deoxyribose.svg
Comparison of the chemical
structures of ribose (top)
and deoxyribose (bottom).
fucose Fucose2.png
fucose

Deoxy sugars are sugars that have had a hydroxyl group replaced with a hydrogen atom. [1]

Contents

Examples include:

In Escherichia coli bacteria, deoxyribose sugars are synthesized via two different pathways - one pathway involves aldol condensation, whereas the other pathway is conversion of a ribose sugar into a deoxyribose sugar by means of changes on the nucleotide or nucleoside level. Deoxyribose is synthesized through the reduction of ribose. Deoxyribose is derived from the same precursor as ribose being that the reduction of the sugar with the extra hydroxyl group results in the deoxy-sugar, which has its hydroxyl group replaced with a hydrogen atom. [2]

Dideoxy sugars

Some biologically important dideoxy sugars, sugars that have had two hydroxyl groups replaced with hydrogen atoms, include colitose and abequose.

Colitose.svg
Colitose
(3,6-Dideoxy-L-xylo-hexose)
Abequose linear.svg
Abequose
(3,6-Dideoxy-D-xylo-hexose)

See also

References

  1. Lichtenthaler, Frieder W. (2010). "Carbohydrates: Occurrence, Structures and Chemistry". Ullmann's Encyclopedia of Industrial Chemistry. doi:10.1002/14356007.a05_079.pub2. ISBN   978-3-527-30385-4.
  2. Sable, Henry Z.; Wright, Elmer M.; Bagatell, Fillmore K. (1959-06-01). "Biosynthesis of Ribose and Deoxyribose in Escherichia coli". Journal of Biological Chemistry. 234 (6): 1369–1374. doi: 10.1016/S0021-9258(18)70013-6 . ISSN   1083-351X. PMID   13654380.