Allose

Last updated
Allose [1]
Allose.png
Alpha allose ball-and-stick.png
Names
Preferred IUPAC name
Allose
Systematic IUPAC name
(2R,3R,4R,5R)-2,3,4,5,6-Pentahydroxyhexanal
Identifiers
3D model (JSmol)
ChEBI
ChemSpider
ECHA InfoCard 100.018.178
PubChem CID
Properties
C6H12O6
Molar mass 180.16 g·mol−1
Melting point 128 °C (262 °F; 401 K)
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references

Allose is an aldohexose sugar. It is a rare monosaccharide that occurs as a 6-O-cinnamyl glycoside in the leaves of the African shrub Protea rubropilosa. Extracts from the fresh-water alga Ochromas malhamensis contain this sugar but of unknown absolute configuration. It is soluble in water and practically insoluble in methanol.

An aldohexose is a hexose with an aldehyde group on one end.

Monosaccharides, also called simple sugars, are the simplest form of sugar and the most basic units of carbohydrates. They cannot be further hydrolyzed to simpler chemical compounds. The general formula is C
n
H
2n
O
n
. They are usually colorless, water-soluble, and crystalline solids. Some monosaccharides have a sweet taste.

<i>Protea</i> genus of plants

Protea is both the botanical name and the English common name of a genus of South African flowering plants, sometimes also called sugarbushes or fynbos. In local tradition, the Protea flower represents change and hope.

Allose is a C-3 epimer of glucose.

Notes

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Disaccharide complex sugars, the sugar formed when two monosaccharides (simple sugars) are joined by glycosidic linkage; soluble in water; one of the four chemical groupings of carbohydrates

A disaccharide is the sugar formed when two monosaccharides are joined by glycosidic linkage. Like monosaccharides, disaccharides are soluble in water. Three common examples are sucrose, lactose, and maltose.

Sugar generic name for sweet-tasting, soluble carbohydrates

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Ribose is a carbohydrate with the formula C5H10O5; specifically, it is a pentose monosaccharide (simple sugar) with linear form H−(C=O)−(CHOH)4−H, which has all the hydroxyl groups on the same side in the Fischer projection.

Amylase is an enzyme that catalyses the hydrolysis of starch into sugars. Amylase is present in the saliva of humans and some other mammals, where it begins the chemical process of digestion. Foods that contain large amounts of starch but little sugar, such as rice and potatoes, may acquire a slightly sweet taste as they are chewed because amylase degrades some of their starch into sugar. The pancreas and salivary gland make amylase to hydrolyse dietary starch into disaccharides and trisaccharides which are converted by other enzymes to glucose to supply the body with energy. Plants and some bacteria also produce amylase. As diastase, amylase is the first enzyme to be discovered and isolated. Specific amylase proteins are designated by different Greek letters. All amylases are glycoside hydrolases and act on α-1,4-glycosidic bonds.

In bio-organic chemistry, a hexose is a monosaccharide with six carbon atoms, having the chemical formula C6H12O6. Hexoses are classified by functional group, with aldohexoses having an aldehyde at position 1, and ketohexoses having a ketone at position 2.

<i>Merck Index</i> іndex of chemicals

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Sorbose chemical compound

Sorbose is a ketose belonging to the group of sugars known as monosaccharides. It has a sweetness that is equivalent to sucrose. The commercial production of vitamin C often begins with sorbose. L-Sorbose is the configuration of the naturally occurring sugar.

Simvastatin Simvastatin is a lipid-lowering medication

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Xylose chemical compound

Xylose is a sugar first isolated from wood, and named for it. Xylose is classified as a monosaccharide of the aldopentose type, which means that it contains five carbon atoms and includes an aldehyde functional group. It is derived from hemicellulose, one of the main constituents of biomass. Like most sugars, it can adopt several structures depending on conditions. With its free aldehyde group, it is a reducing sugar.

Isobutyric acid chemical compound

Isobutyric acid, also known as 2-methylpropanoic acid, is a carboxylic acid with structural formula (CH3)2CHCOOH. It is a colorless liquid with a somewhat unpleasant odor. It is soluble in water and organic solvents. Isobutyric acid is an isomer of n-butyric acid. Deprotonation or esterification of isobutyric acid gives derivatives called isobutyrates. Isobutyric acid is found in the free state in carobs (Ceratonia siliqua), in vanilla, and in the root of Arnica dulcis, and as an ethyl ester in croton oil.

Sodium erythorbate chemical compound

Sodium erythorbate (C6H7NaO6) is a food additive used predominantly in meats, poultry, and soft drinks. Chemically, it is the sodium salt of erythorbic acid. When used in processed meat such as hot dogs and beef sticks, it increases the rate at which nitrite reduces to nitric oxide, thus facilitating a faster cure and retaining the pink coloring. As an antioxidant structurally related to vitamin C, it helps improve flavor stability and prevents the formation of carcinogenic nitrosamines. When used as a food additive, its E number is E316. The use of erythorbic acid and sodium erythorbate as a food preservative has increased greatly since the U.S. Food and Drug Administration banned the use of sulfites as preservatives in foods intended to be eaten fresh (such as ingredients for fresh salads) and as food processors have responded to the fact that some people are allergic to sulfites. It can also be found in bologna, and is occasionally used in beverages, baked goods, and potato salad.

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Methylglyoxal chemical compound

Methylglyoxal, also called pyruvaldehyde or 2-oxopropanal, is the organic compound with the formula CH3C(O)CHO. Gaseous methylglyoxal has two carbonyl groups, an aldehyde and a ketone but in the presence of water, it exists as hydrates and oligomers. It is a reduced derivative of pyruvic acid.

Gentiobiose chemical compound

Gentiobiose is a disaccharide composed of two units of D-glucose joined with a β(1->6) linkage. It is a white crystalline solid that is soluble in water or hot methanol. Gentiobiose is incorporated into the chemical structure of crocin, the chemical compound that gives saffron its color. It is a product of the caramelization of glucose.

Gulose chemical compound

Gulose is an aldohexose sugar. It is a monosaccharide that is very rare in nature, but has been found in archaea, bacteria and eukaryotes. It also exists as a syrup with a sweet taste. It is soluble in water and slightly soluble in methanol. Neither the D- and L-forms are not fermentable by yeast. Gulose is a C-3 epimer of galactose. The syrup created by this substance when concentrated was used in the Gulag during the cold war in the USSR to make people think that they were less famined than they actually were, some myths say that this is where the substance gets its name from.

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Isomaltol chemical compound

Isomaltol is a natural furan obtained by the enzymatic degradation of starch. It is also a flavor component in bread crust, produced by thermal degradation (caramelization) of sugars. Isomaltol is obtained after the Maillard reaction from an amino acid and a reducing sugar

A rare sugar is a sugar that occurs in very small quantities in nature. Typically they occur in amounts too small to allow for economic separation from their underlying natural source and are typically made through biological processes such as fermentation or enzyme conversion to create the identical compound.

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References

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