Absolute zero is the lowest limit of the thermodynamic temperature scale; a state at which the enthalpy and entropy of a cooled ideal gas reach their minimum value, taken as zero kelvin. The fundamental particles of nature have minimum vibrational motion, retaining only quantum mechanical, zero-point energy-induced particle motion. The theoretical temperature is determined by extrapolating the ideal gas law; by international agreement, absolute zero is taken as −273.15 degrees on the Celsius scale, which equals −459.67 degrees on the Fahrenheit scale. The corresponding Kelvin and Rankine temperature scales set their zero points at absolute zero by definition.
Atomic theory is the scientific theory that matter is composed of particles called atoms. The concept that matter is ultimately composed of discrete particles is an ancient idea, but gained scientific credence in the 19th century when scientists found it could explain the behavior of gases and how chemical elements reacted with each other. By the end of the 19th century, atomic theory had gained full acceptance in the scientific community. It was one of the most crucial scientific discoveries in history.
Diatomic molecules are molecules composed of only two atoms, of the same or different chemical elements. If a diatomic molecule consists of two atoms of the same element, such as hydrogen or oxygen, then it is said to be homonuclear. Otherwise, if a diatomic molecule consists of two different atoms, such as carbon monoxide or nitric oxide, the molecule is said to be heteronuclear. The bond in a homonuclear diatomic molecule is non-polar.
Lorenzo Romano Amedeo Carlo Avogadro, Count of Quaregna and Cerreto (, also, Italian:[ameˈdɛːoavoˈɡaːdro]; 9 August 1776 – 9 July 1856) was an Italian scientist, most noted for his contribution to molecular theory now known as Avogadro's law, which states that equal volumes of gases under the same conditions of temperature and pressure will contain equal numbers of molecules. In tribute to him, the ratio of the number of elementary entities (atoms, molecules, ions or other particles) in a substance to its amount of substance (the latter having the unit mole), 6.02214076×1023 mol−1, is known as the Avogadro constant. This constant is denoted NA, and is one of the seven defining constants of the SI.
The laws describing the behaviour of gases under fixed pressure, volume and absolute temperature conditions are called Gas Laws. The basic gas laws were discovered by the end of the 18th century when scientists found out that relationships between pressure, volume and temperature of a sample of gas could be obtained which would hold to approximation for all gases. These macroscopic gas laws were found to be consistent with atomic and kinetic theory.
Joseph Louis Gay-Lussac was a French chemist and physicist. He is known mostly for his discovery that water is made of two parts hydrogen and one part oxygen by volume, for two laws related to gases, and for his work on alcohol–water mixtures, which led to the degrees Gay-Lussac used to measure alcoholic beverages in many countries.
The following is a timeline of low-temperature technology and cryogenic technology. It also lists important milestones in thermometry, thermodynamics, statistical physics and calorimetry, that were crucial in development of low temperature systems.
A timeline of events in the history of thermodynamics.
The ideal gas law, also called the general gas equation, is the equation of state of a hypothetical ideal gas. It is a good approximation of the behavior of many gases under many conditions, although it has several limitations. It was first stated by Benoît Paul Émile Clapeyron in 1834 as a combination of the empirical Boyle's law, Charles's law, Avogadro's law, and Gay-Lussac's law. The ideal gas law is often written in an empirical form:
Dalton's law states that in a mixture of non-reacting gases, the total pressure exerted is equal to the sum of the partial pressures of the individual gases. This empirical law was observed by John Dalton in 1801 and published in 1802. Dalton's law is related to the ideal gas laws.
Charles' law is an experimental gas law that describes how gases tend to expand when heated. A modern statement of Charles' law is:
When the pressure on a sample of a dry gas is held constant, the Kelvin temperature and the volume will be in direct proportion.
Jacques Alexandre César Charles was a French inventor, scientist, mathematician, and balloonist. Charles wrote almost nothing about mathematics, and most of what has been credited to him was due to mistaking him with another Jacques Charles, also a member of the Paris Academy of Sciences, entering on 12 May 1785. He was sometimes called Charles the Geometer.
Avogadro's law or Avogadro-Ampère's hypothesis is an experimental gas law relating the volume of a gas to the amount of substance of gas present. The law is a specific case of the ideal gas law. A modern statement is:
Avogadro's law states that "equal volumes of all gases, at the same temperature and pressure, have the same number of molecules."
For a given mass of an ideal gas, the volume and amount (moles) of the gas are directly proportional if the temperature and pressure are constant.
The year 1811 in science and technology involved some significant events, listed below.
The year 1802 in science and technology involved some significant events, listed below.
Guillaume Amontons was a French scientific instrument inventor and physicist. He was one of the pioneers in studying the problem of friction, which is the resistance to motion when bodies make contact. He is also known for his work on thermodynamics, the concept of absolute zero, and early engine design.
In chemistry, the amount of substance (symbol n) in a given sample of matter is defined as a ratio (n = N/NA) between the number of elementary entities (N) and the Avogadro constant (NA). The entities are usually molecules, atoms, or ions of a specified kind. The particular substance sampled may be specified using a subscript, e.g., the amount of sodium chloride (NaCl) would be denoted as nNaCl. The unit of amount of substance in the International System of Units is the mole (symbol: mol), a base unit. Since 2019, the value of the Avogadro constant NA is defined to be exactly 6.02214076×1023 mol−1. Sometimes, the amount of substance is referred to as the chemical amount or, informally, as the "number of moles" in a given sample of matter.
The history of chemistry represents a time span from ancient history to the present. By 1000 BC, civilizations used technologies that would eventually form the basis of the various branches of chemistry. Examples include the discovery of fire, extracting metals from ores, making pottery and glazes, fermenting beer and wine, extracting chemicals from plants for medicine and perfume, rendering fat into soap, making glass, and making alloys like bronze.
Gas is one of the four fundamental states of matter. The others are solid, liquid, and plasma.
Jacques Etienne Bérard was a French naturalist, chemist and physicist.
