Icosahedrite | |
---|---|
General | |
Category | Native element mineral, alloy |
Formula (repeating unit) | Al63Cu24Fe13 |
IMA symbol | Ihd [1] |
Crystal system | Quasicrystal |
Space group | Icosahedral H-M symbol: 53m Space group: Fm 35 [2] |
Identification | |
Color | Dark grey, black |
Crystal habit | Subhedral to anhedral grains |
Fracture | Irregular |
Luster | Metallic |
Streak | Grey |
Diaphaneity | Opaque |
Optical properties | Isotropic |
References | [3] |
Icosahedrite is the first known naturally occurring quasicrystal phase. It has the composition Al63Cu24Fe13 and is a mineral approved by the International Mineralogical Association in 2010. [2] [4] Its discovery followed a 10-year-long systematic search by an international team of scientists led by Luca Bindi and Paul J. Steinhardt to find the first natural quasicrystal. [5]
It occurs as tiny grains in a small sample labelled "khatyrkite" (catalog number 46407/G, housed in The Museum of Natural History, University of Florence, Italy), collected from an outcrop of weathered serpentinite in the Khatyrka ultramafic zone of the Koryak-Kamchatka area, Koryak Mountains, Russia. The rock sample also contains spinel, diopside, forsterite, nepheline, sodalite, corundum, stishovite, khatyrkite, cupalite and an unnamed AlCuFe alloy. Evidence shows that the sample is actually extraterrestrial in origin, delivered to the Earth by a CV3 carbonaceous chondrite asteroid that dates back 4.5 Gya. [6] [5] A geological expedition has identified the exact place of the original discovery and found more specimens of the meteorite. [7] [8] The same Al-Cu-Fe quasicrystal phase had previously been created in the laboratory by Japanese experimental metallurgists in the late 1980s. [9]
The concept of quasicrystals — along with the term — was first introduced in 1984 by Steinhardt and Dov Levine, both then at the University of Pennsylvania. The first synthetic quasicrystal, a combination of aluminium and manganese, was reported in 1984 by Israeli materials scientist Dan Shechtman and colleagues at the U.S. National Institute of Standards and Technology, a finding for which Shechtman won the 2011 Nobel Prize for Chemistry. [10] [11]
A quasiperiodic crystal, or quasicrystal, is a structure that is ordered but not periodic. A quasicrystalline pattern can continuously fill all available space, but it lacks translational symmetry. While crystals, according to the classical crystallographic restriction theorem, can possess only two-, three-, four-, and six-fold rotational symmetries, the Bragg diffraction pattern of quasicrystals shows sharp peaks with other symmetry orders—for instance, five-fold.
Baddeleyite is a rare zirconium oxide mineral (ZrO2 or zirconia), occurring in a variety of monoclinic prismatic crystal forms. It is transparent to translucent, has high indices of refraction, and ranges from colorless to yellow, green, and dark brown. See etymology below.
Trinitite, also known as atomsite or Alamogordo glass, is the glassy residue left on the desert floor after the plutonium-based Trinity nuclear bomb test on July 16, 1945, near Alamogordo, New Mexico. The glass is primarily composed of arkosic sand composed of quartz grains and feldspar that was melted by the atomic blast. It was first academically described in American Mineralogist in 1948.
A micrometeorite is a micrometeoroid that has survived entry through the Earth's atmosphere. Usually found on Earth's surface, micrometeorites differ from meteorites in that they are smaller in size, more abundant, and different in composition. The IAU officially defines meteoroids as 30 micrometers to 1 meter; micrometeorites are the small end of the range (~submillimeter). They are a subset of cosmic dust, which also includes the smaller interplanetary dust particles (IDPs).
Robert Ammann was an amateur mathematician who made several significant and groundbreaking contributions to the theory of quasicrystals and aperiodic tilings.
Paul Joseph Steinhardt is an American theoretical physicist whose principal research is in cosmology and condensed matter physics. He is currently the Albert Einstein Professor in Science at Princeton University, where he is on the faculty of both the Departments of Physics and of Astrophysical Sciences.
Dan Shechtman is the Philip Tobias Professor of Materials Science at the Technion – Israel Institute of Technology, an Associate of the US Department of Energy's Ames National Laboratory, and Professor of Materials Science at Iowa State University. On April 8, 1982, while on sabbatical at the U.S. National Bureau of Standards in Washington, D.C., Shechtman discovered the icosahedral phase, which opened the new field of quasiperiodic crystals.
Aguilarite is an uncommon sulfosalt mineral with formula Ag4SeS. It was described in 1891 and named for discoverer Ponciano Aguilar.
Peter James Lu, PhD (陸述義) is a post-doctoral research fellow in the Department of Physics and the School of Engineering and Applied Sciences at Harvard University in Cambridge, Massachusetts. He has been recognized for his discoveries of quasicrystal patterns in medieval Islamic architecture, early precision compound machines in ancient China, and man's first use of diamond in neolithic China.
Tenham meteorites are the fragments of a larger meteorite that fell in 1879 in a remote area of Australia near the Tenham station, South Gregory, in western Queensland. Although the fall was seen by a number of people, its exact date has not been established. Bright meteors were seen to be moving roughly from west to east. Stones were subsequently recovered from over a large area, about 20 kilometres (12 mi) long by 5 kilometres (3.1 mi) wide.
Khatyrkite is a rare mineral which is mostly composed of copper and aluminium, but may contain up to about 15% of zinc or iron. Its chemical structure is described by an approximate formula (Cu,Zn)Al2 or (Cu,Fe)Al2. It was discovered in 1985 in a placer in association with another rare mineral cupalite. These two minerals have only been found at 62°39′11″N174°30′02″E in the area of the Iomrautvaam, a tributary of the Khatyrka river, in the Koryak Mountains, in Anadyrsky District, Chukotka, Russia. Analysis of one of the samples containing khatyrkite showed that the small rock was from a meteorite. A geological expedition has identified the exact place of the original discovery and found more specimens of the Khatyrka meteorite. The mineral's name derives from the Khatyrka zone where it was discovered. Its type specimen is preserved in the Mining Museum in Saint Petersburg, and parts of it can be found in other museums, such as Museo di Storia Naturale di Firenze.
Cupalite is a rare mineral which is mostly composed of copper and aluminium, but might contain up to several percent of zinc or iron; its chemical structure is therefore described by an approximate formula (Cu,Zn)Al or (Cu,Fe)Al. It was discovered in 1985 in placers derived from serpentine, in association with another rare mineral khatyrkite (CuAl2). Both minerals are thus far restricted to the area of the Iomrautvaam, in the Khatyrka ultramafic (silicon-poor) zone of the Koryak–Kamchatka fold area, Koryak Mountains, Anadyrsky District, Chukotka Autonomous Okrug, Far Eastern Federal District, Russia. The mineral name derives from cuprum (Latin for copper) and aluminium. Its holotype (defining sample) is preserved in the Mining Museum in Saint Petersburg, and parts of it can be found in other museums, such as Museo di Storia Naturale di Firenze.
Delafossite is a copper iron oxide mineral with formula CuFeO2 or Cu1+Fe3+O2. It is a member of the delafossite mineral group, which has the general formula ABO2, a group characterized by sheets of linearly coordinated A cations stacked between edge-shared octahedral layers (BO6). Delafossite, along with other minerals of the ABO2 group, is known for its wide range of electrical properties, its conductivity varying from insulating to metallic. Delafossite is usually a secondary mineral that crystallizes in association with oxidized copper and rarely occurs as a primary mineral.
Djerfisherite is an alkali copper–iron sulfide mineral and a member of the djerfisherite group.
Ichnusaite (pronounced iknusa-ait) is a very rarely found mineral. Ichnusaite is a natural compound of thorium and molybdenum with the formula Th(MoO4)2·3H2O. It was discovered in Su Seinargiu, Sarroch, Cagliari, Sardegna, Italy in 2013. The name is from the old Greek name of Sardinia, Ιχνουσσα, Ichnusa.
This locality is also a place of discovery of the second natural thorium molybdate - nuragheite.
Nuragheite is a rare natural thorium molybdate, formula Th(MoO4)2·H2O, discovered in Su Seinargiu, Sarroch, Cagliari, Sardegna, Italy. This locality is also a place of discovery of the other thorium molybdate - ichnusaite, which is a trihydrate.
Luca Bindi is an Italian geologist. He holds the Chair of Mineralogy and Crystallography and is the Head of the Department of Earth Sciences of the University of Florence. He is also a research associate at the Istituto di Geoscienze e Georisorse of the National Research Council (Italy) (CNR). He has received national and international scientific awards that include the President of the Republic Prize 2015 in the category of Physical, Mathematical and Natural Sciences. Since 2019 is a Member of the National Academy of Lincei.
Kamanio Chattopadhyay is an Indian materials engineer and an honorary professor at the Indian Institute of Science, Bengaluru. He is the chair of the Mechanical Sciences Division of IISc and a former chair of the Department of Materials Engineering.
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Dov I. Levine is an American-Israeli physicist, known for his research on quasicrystals, soft condensed matter physics, and statistical mechanics out of equilibrium.