Khinite

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Khinite
Khinite.jpg
Dark green Khinite crystals from the type locality (Bird Nest Drift, San Bernardino County, California, United States of America).
General
Category Tellurate minerals
Formula
(repeating unit)		PbCu3TeO6(OH)2
IMA symbol Khn [1]
Strunz classification 4.FD.30
Dana classification33.1.3.1
Crystal system Orthorhombic
Unit cell Khinite-4O:
a = 5.740 Å,
b = 9.983 Å,
c = 23.960 Å, Z = 8
Khinite-3T (parakhinite):
a = 5.753 Å,
c = 17.958 Å, Z = 3
Identification
ColorDark green – Bottle green
Crystal habit Dipyramidal or curved crystals
Cleavage {001} fair
Tenacity Brittle
Mohs scale hardness3.5
Luster Vitreous
Streak Green
Diaphaneity Semitransparent
Specific gravity 6.5–7.0 (measured) 6.69 (calculated)
Optical propertiesBiaxial (+) (khinite) Uniaxial (−) (parakhinite)
Birefringence δ = 0.055
Pleochroism Yellow green – emerald green
2V angle 20o
Ultraviolet fluorescence None
Fusibility Fuses readily to a brown slag
Solubility Soluble in cold acids
Common impuritiesCa
References

Khinite is a rare tellurate mineral with the formula Pb 2+ Cu 2+3 Te O 6(O H)2. [2] [3] [4] It crystallizes in the orthorhombic system and has a bottle-green colour. It is often found as dipyramidal, curved or corroded crystals no more than 0.15 mm in size. [5] The tetragonal dimorph of khinite is called parakhinite.

Contents

Occurrence and name

Both khinite and parakhinite were first identified in 1978 in the Old Guard Mine (Royal Guard Mine), Tombstone District, Cochise County, Arizona, US They were named after Ba-Saw Khin, a Burmese-American mineralogist. [2] They are often found together with tenorite, quetzalcoatlite, quartz, gold, dugganite, chrysocolla, chlorargyrite, bromargyrite, xocomecatlite, and tlapallite. [2] [5] Khinite and parakhinite are found in multiple mines across Mexico and the USA.

Parakhinite

Parakhinite crystallizes in the tetragonal system. Khinite and parakhinite are also called khinite-4O and khinite-3T, respectively. Khinite and parakhinite are identical in colour and many other properties, like reactivity. They do differ in optical properties: Khinite is biaxial (+), while parakhinite is uniaxial (−). They also have different unit cells. [2] [4] [6] [7]

Related Research Articles

<span class="mw-page-title-main">Kernite</span>

Kernite, also known as rasorite, is a hydrated sodium borate hydroxide mineral with formula Na
2B
4O
6(OH)
2·3H
2O. It is a colorless to white mineral crystallizing in the monoclinic crystal system typically occurring as prismatic to acicular crystals or granular masses. It is relatively soft with Mohs hardness of 2.5 to 3 and light with a specific gravity of 1.91. It exhibits perfect cleavage and a brittle fracture.

Frankhawthorneite Cu2Te6+O4(OH)2 is a monoclinic copper tellurate mineral (space group P21/n) named after Prof. Frank Christopher Hawthorne (born 1946), University of Manitoba, Winnipeg, Canada. It was discovered at Centennial Eureka Mine, Tintic District, East Tintic Mountains, Juab County, Utah, in 1995. It has a leaf green color.

<span class="mw-page-title-main">Frank Hawthorne</span> Canadian mineralogist and crystallographer

Frank Christopher Hawthorne is a Canadian mineralogist, crystallographer and spectroscopist. He works at the University of Manitoba, Winnipeg, Manitoba, Canada, and is currently Distinguished Professor Emeritus. By combining Graph Theory, Bond-Valence Theory and the moments approach to the electronic energy density of solids he has developed Bond Topology as a rigorous approach to understanding the atomic arrangements, chemical compositions and paragenesis of complex oxide and oxysalt minerals.

<span class="mw-page-title-main">Baotite</span>

Baotite Ba4Ti4(Ti, Nb, Fe)4(Si4O12)O16Cl is a rare mineral recognized as having a unique four-fold silicate ring. Crystals are tetragonal, though commonly deformed to the extent of appearing monoclinic. Named for the locality of first discovery, Baotou, China, baotite has been found in hydrothermal veins and alkalic rocks in various locations around the world.

<span class="mw-page-title-main">Xocomecatlite</span>

Xocomecatlite is a rare tellurate mineral with formula: Cu3(TeO4)(OH)4. It is an orthorhombic mineral which occurs as aggregates or spherules of green needlelike crystals.

<span class="mw-page-title-main">Huttonite</span> Thorium nesosilicate mineral

Huttonite is a thorium nesosilicate mineral with the chemical formula ThSiO4 and which crystallizes in the monoclinic system. It is dimorphous with tetragonal thorite, and isostructual with monazite. An uncommon mineral, huttonite forms transparent or translucent cream–colored crystals. It was first identified in samples of beach sands from the West Coast region of New Zealand by the mineralogist Colin Osborne Hutton (1910–1971). Owing to its rarity, huttonite is not an industrially useful mineral.

<span class="mw-page-title-main">Boleite</span>

Boleite is a complex halide mineral with formula: KPb26Ag9Cu24(OH)48Cl62. It was first described in 1891 as an oxychloride mineral. It is an isometric mineral which forms in deep-blue cubes. There are numerous minerals related to boleite, such as pseudoboleite, cumengite, and diaboleite, and these all have the same complex crystal structure. They all contain bright-blue cubic forms and are formed in altered zones of lead and copper deposits, produced during the reaction of chloride bearing solutions with primary sulfide minerals.

<span class="mw-page-title-main">Cyrilovite</span>

Cyrilovite (NaFe33+(PO4)2(OH)4·2(H2O)) is a hydrous sodium iron phosphate mineral. It is isomorphous and isostructural with wardite, the sodium aluminium counterpart.

<span class="mw-page-title-main">Anthonyite</span>

Anthonyite is a hydrous secondary copper halide mineral with chemical formula of Cu(OH,Cl)2·3(H2O).

<span class="mw-page-title-main">Zemannite</span>

Zemannite is a very rare oxide mineral with the chemical formula Mg0.5ZnFe3+[TeO3]3·4.5H2O. It crystallizes in the hexagonal crystal system and forms small prismatic brown crystals. Because of the rarity and small crystal size, zemannite has no applications and serves as a collector's item.

Georgerobinsonite, named for George Willard Robinson, is a lead chromate mineral with formula Pb4(CrO4)2(OH)2FCl. It exhibits very small, transparent crystals with a bright orange-red color. It was obtained from the Mammoth–St. Anthony Mine in Arizona in the 1940s and identified in 2009.

<span class="mw-page-title-main">Shigaite</span>

Shigaite is a mineral with formula NaAl3(Mn2+)6(SO4)2(OH)18·12H2O that typically occurs as small, hexagonal crystals or thin coatings. It is named for Shiga Prefecture, Japan, where it was discovered in 1985. The formula was significantly revised in 1996, identifying sodium as a previously unknown constituent.

<span class="mw-page-title-main">Ruizite</span>

Ruizite is a sorosilicate mineral with formula Ca2Mn2Si4O11(OH)4·2H2O. It was discovered at the Christmas mine in Christmas, Arizona, and described in 1977. The mineral is named for discoverer Joe Ana Ruiz.

Daubréeite is a rare bismuth oxohalide mineral with formula BiO(OH,Cl). It is a creamy-white to yellow-brown, soft, earthy clay–like mineral which crystallizes in the tetragonal crystal system. It is a member of the matlockite group.

<span class="mw-page-title-main">Hubeite</span> Sorosilicate mineral

The mineral hubeite, Ca
2Mn2+
Fe3+
[Si
4O
12(OH)]·(H
2O)
2, is a sorosilicate of the Si
4O
13 group. Structurally it also belongs to the Akatoreite group. It was found and named after the province of Hubei, China. It is common to iron ores in a mine of that region. It occurs mainly as aggregates of fan like crystals. It is dark to pale brown, has orange-brown streak and is vitreous. Hubeite has a hardness of 5.5 in the Mohs scale, one good cleavage and conchoidal fracture. It is triclinic with a space group of P1*. The structure of hubeite is very uncommon, and in fact there is only one other mineral that fits the Si
4O
13 group, which is ruizite.

<span class="mw-page-title-main">Pinnoite</span>

Pinnoite is a magnesium borate mineral with formula: MgB2O(OH)6 or MgB2O4·3(H2O). It crystallizes in the tetragonal crystal system and occurs as colorless to yellow or light green radial fibrous clusters and rarely as short prismatic crystals.

Arakiite (IMA symbol: Ark) is a rare mineral with the formula (Zn,Mn2+)(Mn2+,Mg)12(Fe3+,Al)2(As3+O3)(As5+O4)2(OH)23. It is both arsenate and arsenite mineral, a combination that is rare in the world of minerals. Arakiite is stoichiometrically similar to hematolite. It is one of many rare minerals coming from the famous Långban manganese skarn deposit in Sweden. Other minerals bearing both arsenite and zinc include kraisslite and mcgovernite.

<span class="mw-page-title-main">Tlapallite</span>

Tlapallite is a rare and complex tellurate mineral with the chemical formula (Ca,Pb)3CaCu6[Te4+3Te6+O12]2(Te4+O3)2(SO4)2·3H2O. It has a Moh's hardness of 3 and it is green in colour. It was named after the Nahua word "Tlalpalli", which translates to paint, referring to the paint-like habit of the mineral. Its formula and crystal structure were redefined in 2019, showing it contained a mixed-valence phyllotellurate layer [Te4+3Te6+O12]12−.

<span class="mw-page-title-main">Quetzalcoatlite</span>

Quetzalcoatlite is a rare tellurium oxysalt mineral with the formula Zn6Cu3(TeO6)2(OH)6 · AgxPbyClx+2y. It also contains large amounts of silver- and lead(II)chloride with the formula AgxPbyClx+2y (x+y≤2). It has a Mohs hardness of 3 and it crystallizes in the trigonal system. It has a deep blue color. It was named after Quetzalcoatl, the Aztec and Toltec god of the sea, alluding to its color. It is not to be confused with tlalocite, which has a similar color and habit.

Eskebornite is a selenide mineral with the formula CuFeSe2. It crystallizes in the tetragonal system and it has a brassy colour. Eskebornite is sometimes found as thick tabular crystals, but is more often found intergrown with other selenides. It is part of the chalcopyrite group and forms a series with chalcopyrite.

References

  1. ↑ Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine. 85 (3): 291–320. Bibcode:2021MinM...85..291W. doi: 10.1180/mgm.2021.43 . S2CID   235729616.
  2. 1 2 3 4 "Khinite: Khinite mineral information and data". www.mindat.org. Retrieved 2016-10-28.
  3. ↑ Barthelmy, Dave. "Khinite Mineral Data". www.webmineral.com. Retrieved 2016-10-28.
  4. 1 2 Williams, S.A. (1978). "Khinite, parakhinite, and dugganite, three new tellurates from Tombstone. Arizona" (PDF). American Mineralogist. 63: 1016–1019.
  5. 1 2 "Handbook of mineralogy, Khinite" (PDF).
  6. ↑ Cooper, M. A.; Hawthorne, F. C.; Back, M. E. (2008). "The crystal structure of khinite and polytypism in khinite and parakhinite". Mineralogical Magazine. 72 (3): 763–770. Bibcode:2008MinM...72..763C. doi:10.1180/minmag.2008.072.3.763. S2CID   140537204.
  7. ↑ Hawthorne, F. C.; Cooper, M. A.; Back, M. E. (2009). "Khinite-4O [= Khinite] and Khinite-3T [= Parakhinite]". The Canadian Mineralogist. 47 (2): 473–476. Bibcode:2009CaMin..47..473H. doi:10.3749/canmin.47.2.473.
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