Liquid fuel

Last updated September 20, 2024

Liquid fuels are combustible or energy-generating molecules that can be harnessed to create mechanical energy, usually producing kinetic energy; they also must take the shape of their container. It is the fumes of liquid fuels that are flammable instead of the fluid. Most liquid fuels in widespread use are derived from fossil fuels; however, there are several types, such as hydrogen fuel (for automotive uses), ethanol, and biodiesel, which are also categorized as a liquid fuel. Many liquid fuels play a primary role in transportation and the economy.

General properties

Some common properties of liquid fuels are that they are easy to transport, and can be handled with relative ease. Physical properties of liquid fuels vary by temperature, though not as greatly as for gaseous fuels. Some of these properties are: flash point, the lowest temperature at which a flammable concentration of vapor is produced; fire point, the temperature at which sustained burning of vapor will occur; cloud point for diesel fuels, the temperature at which dissolved waxy compounds begin to coalesce, and pour point, the temperature below which the fuel is too thick to pour freely. These properties affect the safety and handling of the fuel.

Petroleum fuels

Most liquid fuels used currently are produced from petroleum. The most notable of these is gasoline. Scientists generally accept that petroleum formed from the fossilized remains of dead plants and animals by exposure to heat and pressure in the Earth's crust.

Gasoline

Gasoline is the most widely used liquid fuel. Gasoline, as it is known in United States and Canada, or petrol virtually everywhere else, is made of hydrocarbon molecules (compounds that contain hydrogen and carbon only) forming aliphatic compounds, or chains of carbons with hydrogen atoms attached. However, many aromatic compounds (carbon chains forming rings) such as benzene are found naturally in gasoline and cause the health risks associated with prolonged exposure to the fuel.

Production of gasoline is achieved by distillation of crude oil. The desirable liquid is separated from the crude oil in refineries. Crude oil is extracted from the ground in several processes, the most commonly seen may be beam pumps. To create gasoline, petroleum must first be removed from crude oil.

Liquid gasoline itself is not actually burned, but its fumes ignite, causing the remaining liquid to evaporate and then burn. Gasoline is extremely volatile and easily combusts, making any leakage potentially extremely dangerous. Gasoline sold in most countries carries a published octane rating. The octane number is an empirical measure of the resistance of gasoline to combusting prematurely, known as knocking. The higher the octane rating, the more resistant the fuel is to autoignition under high pressures, which allows for a higher compression ratio. Engines with a higher compression ratio, commonly used in race cars and high-performance regular-production automobiles, can produce more power; however, such engines require a higher octane fuel. Increasing the octane rating has, in the past, been achieved by adding 'anti-knock' additives such as lead-tetra-ethyl. Because of the environmental impact of lead additives, the octane rating is increased today by refining out the impurities that cause knocking.

Diesel

Conventional diesel is similar to gasoline in that it is a mixture of aliphatic hydrocarbons extracted from petroleum. Diesel may cost more or less than gasoline, but generally costs less to produce because the extraction processes used are simpler. Some countries (particularly Canada, India and Italy) also have lower tax rates on diesel fuels.

After distillation, the diesel fraction is normally processed to reduce the amount of sulfur in the fuel. Sulfur causes corrosion in vehicles, acid rain and higher emissions of soot from the tail pipe (exhaust pipe). Historically, in Europe lower sulfur levels than in the United States were legally required. However, recent US legislation reduced the maximum sulfur content of diesel from 3,000 ppm to 500 ppm in 2007, and 15 ppm by 2010. Similar changes are also underway in Canada, Australia, New Zealand and several Asian countries. See also Ultra-low-sulfur diesel.

A diesel engine is a type of internal combustion engine which ignites fuel by injecting it into a combustion chamber previously compressed with air (which in turn raises the temperature) as opposed to using an outside ignition source, such as a spark plug.

Kerosene

Kerosene is used in kerosene lamps and as a fuel for cooking, heating, and small engines. It displaced whale oil for lighting use. Jet fuel for jet engines is made in several grades (Avtur, Jet A, Jet A-1, Jet B, JP-4, JP-5, JP-7 or JP-8) that are kerosene-type mixtures. One form of the fuel known as RP-1 is burned with liquid oxygen as rocket fuel. These fuel grade kerosenes meet specifications for smoke points and freeze points.

In the mid-20th century, kerosene or "TVO" (Tractor Vaporising Oil) was used as a cheap fuel for tractors. The engine would start on gasoline, then switch over to kerosene once the engine warmed up. A "heat valve" on the manifold would route the exhaust gases around the intake pipe, heating the kerosene to the point where it can be ignited by an electric spark.

Kerosene is sometimes used as an additive in diesel fuel to prevent gelling or waxing in cold temperatures. However, this is not advisable in some recent vehicle diesel engines, as doing so may interfere with the engine's emissions regulation equipment.

Liquefied petroleum gas (LPG)

LP gas is a mixture of propane and butane, both of which are easily compressible gases under standard atmospheric conditions. It offers many of the advantages of compressed natural gas (CNG), but does not burn as cleanly, is denser than air and is much more easily compressed. Commonly used for cooking and space heating, LP gas and compressed propane are seeing increased use in motorized vehicles; propane is the third most commonly used motor fuel globally.

Carbon dioxide formation from petroleum fuels.

Petroleum fuels, when burnt, release carbon dioxide that is necessary for plant growth, but which (given the large scale of global emissions) is potentially harmful to world climate. The amount of carbon dioxide released when one liter of fuel is combusted can be estimated:^[1] As a good approximation the chemical formula of e.g. diesel is C^_nH^_2n. Note that diesel is a mixture of different molecules. As carbon has a molar mass of 12 g/mol and hydrogen (atomic!) has a molar mass of about 1 g/mol, so the fraction by weight of carbon in diesel is roughly 12/14. The reaction of diesel combustion is given by:

2C^_nH^_2n + 3nO^₂⇌ 2nCO^₂ + 2nH^₂O

Carbon dioxide has a molar mass of 44g/mol as it consists of 2 atoms of oxygen (16 g/mol) and 1 atom of carbon (12 g/mol). So 12 g of carbon yield 44 g of Carbon dioxide. Diesel has a density of 0.838 kg per liter. Putting everything together the mass of carbon dioxide that is produced by burning 1 liter of diesel can be calculated as:

$0.838kg/L\cdot {\frac {12}{14}}\cdot {\frac {44}{12}}=2.63kg/L$

The number of 2.63 kg of carbon dioxide from 1 liter of Diesel is close to the values found in the literature.

For gasoline, with a density of 0.75 kg/L and a ratio of carbon to hydrogen atoms of about 6 to 14, the estimated value of carbon emission if 1 liter of gasoline is burnt gives:

$0.75kg/L\cdot {{\frac {6\cdot 12}{6\cdot 12+14}}\cdot 1}\cdot {\frac {44}{12}}=2.3kg/L$

Non-petroleum fossil fuels

When petroleum is not easily available, chemical processes such as the Fischer–Tropsch process can be used to produce liquid fuels from coal or natural gas. Synthetic fuels from coal were strategically important during World War II for the German military. Today synthetic fuels produced from natural gas are manufactured, to take advantage of the higher value of liquid fuels in transportation.

Liquefied natural gas

Natural gas, composed chiefly of methane, can be compressed to a liquid and used as a substitute for other traditional liquid fuels. Its combustion is very clean compared to other hydrocarbon fuels, but the fuel's low boiling point requires the fuel to be kept at high pressures to keep it in the liquid state. Though it has a much lower flash point than fuels such as gasoline, it is in many ways safer due to its higher autoignition temperature and its low density, which causes it to dissipate when released in air.

Biodiesel

Biodiesel is similar to diesel but has differences akin to those between petrol and ethanol. For instance, biodiesel has a higher cetane rating (45-60 compared to 45-50 for crude-oil-derived diesel) and it acts as a cleaning agent to get rid of dirt and deposits. It has been argued that it only becomes economically feasible above oil prices of $80 (£40 or €60 as of late February, 2007) per barrel. This does, however, depend on locality, economic situation, government stance on biodiesel and a host of other factors- and it has been proven to be viable at much lower costs in some countries. Also, it yields about 10% less energy than ordinary diesel. Analogous to the use of higher compression ratios used for engines burning higher octane alcohols and petrol in spark-ignition engines, taking advantage of biodiesel's high cetane rating can potentially overcome the energy deficit compared to ordinary Number 2 diesel.

Alcohols

Generally, the term alcohol refers to ethanol, the first organic chemical produced by humans,^[2] but any alcohol can be burned as a fuel. Ethanol and methanol are the most common, being sufficiently inexpensive to be useful.

Methanol

Methanol is the lightest and simplest alcohol, produced from the natural gas component methane. Its application is limited primarily due to its toxicity (similar to gasoline), but also due to its high corrosivity and miscibility with water. Small amounts are used in some types of gasoline to increase the octane rating. Methanol-based fuels are used in some race cars and model aeroplanes.

Methanol is also called methyl alcohol or wood alcohol, the latter because it was formerly produced from the distillation of wood. It is also known by the name methyl hydrate.

Ethanol

Ethanol, also known as grain alcohol or ethyl alcohol, is commonly found in alcoholic beverages. However, it may also be used as a fuel, most often in combination with gasoline. For the most part, it is used in a 9:1 ratio of gasoline to ethanol to reduce the negative environmental effects of gasoline.^{[ citation needed ]}

There is increasing interest in the use of a blend of 85% fuel ethanol blended with 15% gasoline. This fuel blend called E85 has a higher fuel octane than most premium types of gasoline. When used in a modern Flexible fuel vehicle, it delivers more performance to the gasoline it replaces at the expense of higher fuel consumption due to ethanol's lesser specific energy content.^[3]

Ethanol for use in gasoline and industrial purposes may be considered a fossil fuel because it is often synthesized from the petroleum product ethylene, which is cheaper than production from fermentation of grains or sugarcane.

Butanol

Butanol is an alcohol which can be used as a fuel in most gasoline internal combustion engines without engine modification. It is typically a product of the fermentation of biomass by the bacterium Clostridium acetobutylicum (also known as the Weizmann organism). This process was first delineated by Chaim Weizmann in 1916 for the production of acetone from starch for making cordite, a smokeless gunpowder.

The advantages of butanol are its high octane rating (over 100) and high energy content, only about 10% lower than gasoline, and subsequently about 50% more energy-dense than ethanol, 100% more so than methanol. Butanol's only major disadvantages are its high flashpoint (35 °C or 95 °F), toxicity (note that toxicity levels exist but are not precisely confirmed), and the fact that the fermentation process for renewable butanol emits a foul odour. The Weizmann organism can only tolerate butanol levels up to 2% or so, compared to 14% for ethanol and yeast. Making butanol from oil produces no such odour, but the limited supply and environmental impact of oil usage defeat the purpose of alternative fuels. The cost of butanol is about $1.25–$1.32 per kilogram ($0.57-$0.58 per pound or $4 approx. per US gallon). Butanol is much more expensive than ethanol (approximately $0.40 per litre or 1.50 per gallon) and methanol.

On June 20, 2006, DuPont and BP announced that they were converting an existing ethanol plant to produce 9 million gallons (34 000 cubic meters) of butanol per year from sugar beets. DuPont stated a goal of being competitive with oil at $30–$40 per barrel ($0.19-$0.25 per liter) without subsidies, so the price gap with ethanol is narrowing.

Hydrogen

Liquefied hydrogen is the liquid state of the element hydrogen. It is a common liquid rocket fuel for rocket applications and can be used as a fuel in an internal combustion engine or fuel cell. Various concept hydrogen vehicles have been lower volumetric energy, the hydrogen volumes needed for combustion are large. Hydrogen was liquefied for the first time by James Dewar in 1898.

Ammonia

Ammonia (NH₃) has been used as a fuel before at times when gasoline is unavailable (e.g. for buses in Belgium during WWII). It has a volumetric energy density of 17 Megajoules per liter (compared to 10 for hydrogen, 18 for methanol, 21 for dimethyl ether and 34 for gasoline). It must be compressed or cooled to be a liquid fuel, although it does not require cryogenic cooling as hydrogen does to be liquefied.^[4]

Related Research Articles

Gasoline or petrol is a petrochemical product characterized as a transparent, yellowish, and flammable liquid normally used as a fuel for spark-ignited internal combustion engines. When formulated as a fuel for engines, gasoline is chemically composed of organic compounds derived from the fractional distillation of petroleum and later chemically enhanced with gasoline additives. It is a high-volume profitable product produced in crude oil refineries.

Diesel fuel, also called diesel oil, heavy oil (historically) or simply diesel, is any liquid fuel specifically designed for use in a diesel engine, a type of internal combustion engine in which fuel ignition takes place without a spark as a result of compression of the inlet air and then injection of fuel. Therefore, diesel fuel needs good compression ignition characteristics.

<span class="mw-page-title-main">Biofuel</span> Type of biological fuel

Biofuel is a fuel that is produced over a short time span from biomass, rather than by the very slow natural processes involved in the formation of fossil fuels such as oil. Biofuel can be produced from plants or from agricultural, domestic or industrial biowaste. Biofuels are mostly used for transportation, but can also be used for heating and electricity. Biofuels are regarded as a renewable energy source. The use of biofuel has been subject to criticism regarding the "food vs fuel" debate, varied assessments of their sustainability, and possible deforestation and biodiversity loss as a result of biofuel production.

RP-1 (alternatively, Rocket Propellant-1 or Refined Petroleum-1) is a highly refined form of kerosene outwardly similar to jet fuel, used as rocket fuel. RP-1 provides a lower specific impulse than liquid hydrogen (H₂), but is cheaper, is stable at room temperature, and presents a lower explosion hazard. RP-1 is far denser than H₂, giving it a higher energy density (though its specific energy is lower). RP-1 also has a fraction of the toxicity and carcinogenic hazards of hydrazine, another room-temperature liquid fuel.

Ethanol fuel is fuel containing ethyl alcohol, the same type of alcohol as found in alcoholic beverages. It is most often used as a motor fuel, mainly as a biofuel additive for gasoline.

Alternative fuels, also known as non-conventional and advanced fuels, are fuels derived from sources other than petroleum. Alternative fuels include gaseous fossil fuels like propane, natural gas, methane, and ammonia; biofuels like biodiesel, bioalcohol, and refuse-derived fuel; and other renewable fuels like hydrogen and electricity.

Methanol fuel is an alternative biofuel for internal combustion and other engines, either in combination with gasoline or independently. Methanol (CH₃OH) is less expensive to sustainably produce than ethanol fuel, although it is more toxic than ethanol and has a lower energy density than gasoline. Methanol is safer for the environment than gasoline, is an anti-freeze agent, prevents dirt and grime buildup within the engine, has a higher ignition temperature, and produces horsepower equivalent to that of super high-octane gasoline. It can readily be used in most modern engines. To prevent vapor lock due to being a simple, pure fuel, a small percentage of other fuel or certain additives can be included. Methanol may be made from fossil fuels or renewable resources, in particular natural gas and coal, or biomass respectively. In the case of the latter, it can be synthesized from CO₂ (carbon dioxide) and hydrogen. The vast majority of methanol produced globally is currently made with gas and coal. However, projects, investments, and the production of green-methanol has risen steadily into 2023. Methanol fuel is currently used by racing cars in many countries and has seen increasing adoption by the maritime industry.

Ethanol, an alcohol fuel, is an important fuel for the operation of internal combustion engines that are used in cars, trucks, and other kinds of machinery.

The methanol economy is a suggested future economy in which methanol and dimethyl ether replace fossil fuels as a means of energy storage, ground transportation fuel, and raw material for synthetic hydrocarbons and their products. It offers an alternative to the proposed hydrogen economy or ethanol economy, although these concepts are not exclusive. Methanol can be produced from a variety of sources including fossil fuels as well as agricultural products and municipal waste, wood and varied biomass. It can also be made from chemical recycling of carbon dioxide.

Gas to liquids (GTL) is a refinery process to convert natural gas or other gaseous hydrocarbons into longer-chain hydrocarbons, such as gasoline or diesel fuel. Methane-rich gases are converted into liquid synthetic fuels. Two general strategies exist: (i) direct partial combustion of methane to methanol and (ii) Fischer–Tropsch-like processes that convert carbon monoxide and hydrogen into hydrocarbons. Strategy ii is followed by diverse methods to convert the hydrogen-carbon monoxide mixtures to liquids. Direct partial combustion has been demonstrated in nature but not replicated commercially. Technologies reliant on partial combustion have been commercialized mainly in regions where natural gas is inexpensive.

Various alcohols are used as fuel for internal combustion engines. The first four aliphatic alcohols are of interest as fuels because they can be synthesized chemically or biologically, and they have characteristics which allow them to be used in internal combustion engines. The general chemical formula for alcohol fuel is C_nH_2n+1OH.

The United States produces mainly biodiesel and ethanol fuel, which uses corn as the main feedstock. The US is the world's largest producer of ethanol, having produced nearly 16 billion gallons in 2017 alone. The United States, together with Brazil accounted for 85 percent of all ethanol production, with total world production of 27.05 billion gallons. Biodiesel is commercially available in most oilseed-producing states. As of 2005, it was somewhat more expensive than fossil diesel, though it is still commonly produced in relatively small quantities, in comparison to petroleum products and ethanol fuel.

Butanol may be used as a fuel in an internal combustion engine. It is more similar to gasoline than it is to ethanol. A C4-hydrocarbon, butanol is a drop-in fuel and thus works in vehicles designed for use with gasoline without modification. Both n-butanol and isobutanol have been studied as possible fuels. Both can be produced from biomass (as "biobutanol" ) as well as from fossil fuels (as "petrobutanol"). The chemical properties depend on the isomer (n-butanol or isobutanol), not on the production method.

Renewable fuels are fuels produced from renewable resources. Examples include: biofuels, Hydrogen fuel, and fully synthetic fuel produced from ambient carbon dioxide and water. This is in contrast to non-renewable fuels such as natural gas, LPG (propane), petroleum and other fossil fuels and nuclear energy. Renewable fuels can include fuels that are synthesized from renewable energy sources, such as wind and solar. Renewable fuels have gained in popularity due to their sustainability, low contributions to the carbon cycle, and in some cases lower amounts of greenhouse gases. The geo-political ramifications of these fuels are also of interest, particularly to industrialized economies which desire independence from Middle Eastern oil.

An alternative fuel vehicle is a motor vehicle that runs on alternative fuel rather than traditional petroleum fuels. The term also refers to any technology powering an engine that does not solely involve petroleum. Because of a combination of factors, such as environmental and health concerns including climate change and air pollution, high oil-prices and the potential for peak oil, development of cleaner alternative fuels and advanced power systems for vehicles has become a high priority for many governments and vehicle manufacturers around the world.

Second-generation biofuels, also known as advanced biofuels, are fuels that can be manufactured from various types of non-food biomass. Biomass in this context means plant materials and animal waste used especially as a source of fuel.

Biogasoline is a type of gasoline produced from biomass such as algae. Like traditionally produced gasoline, it is made up of hydrocarbons with 6 (hexane) to 12 (dodecane) carbon atoms per molecule and can be used in internal combustion engines. However, unlike traditional gasoline/petroleum based fuels, which are mainly composed from oil, biogasolines are made from plants such as beets and sugarcane or cellulosic biomass- substances normally referred to as plant waste.

Electrofuels, also known as e-fuels, are a class of synthetic fuels which function as drop-in replacement fuels for internal combustion engines. They are manufactured using captured carbon dioxide or carbon monoxide, together with hydrogen obtained from water split. Electrolysis is possible with both traditional fossil fuel energy sources, as well as low-carbon electricity sources such as wind, solar and nuclear power.

Carbon-neutral fuel is fuel which produces no net-greenhouse gas emissions or carbon footprint. In practice, this usually means fuels that are made using carbon dioxide (CO₂) as a feedstock. Proposed carbon-neutral fuels can broadly be grouped into synthetic fuels, which are made by chemically hydrogenating carbon dioxide, and biofuels, which are produced using natural CO₂-consuming processes like photosynthesis.

An internal combustion engine is a heat engine in which the combustion of a fuel occurs with an oxidizer in a combustion chamber that is an integral part of the working fluid flow circuit. In an internal combustion engine, the expansion of the high-temperature and high-pressure gases produced by combustion applies direct force to some component of the engine. The force is typically applied to pistons, turbine blades, a rotor, or a nozzle. This force moves the component over a distance. This process transforms chemical energy into kinetic energy which is used to propel, move or power whatever the engine is attached to.

References

↑ Hilgers, Michael (2020). The Diesel Engine, in series: commercial vehicle technology. Berlin/Heidelberg/New York: Springer. ISBN 978-3-662-60856-2.
↑ "AccessScience | Encyclopedia Article | Alcohol fuel". Accessscience.com. Retrieved 2008-11-06.
↑ E85
↑ "Ammonia FAQs" . Retrieved 9 August 2012.

External links

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[1] Hilgers, Michael (2020). The Diesel Engine, in series: commercial vehicle technology. Berlin/Heidelberg/New York: Springer. ISBN 978-3-662-60856-2.

[2] "AccessScience | Encyclopedia Article | Alcohol fuel". Accessscience.com. Retrieved 2008-11-06.

[3] E85

[4] "Ammonia FAQs" . Retrieved 9 August 2012.

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