Birefringence means double refraction. It is the optical property of a material having a refractive index that depends on the polarization and propagation direction of light. These optically anisotropic materials are described as birefringent or birefractive. The birefringence is often quantified as the maximum difference between refractive indices exhibited by the material. Crystals with non-cubic crystal structures are often birefringent, as are plastics under mechanical stress.
Leadhillite is a lead sulfate carbonate hydroxide mineral, often associated with anglesite. It has the formula Pb4SO4(CO3)2(OH)2. Leadhillite crystallises in the monoclinic system, but develops pseudo-hexagonal forms due to crystal twinning. It forms transparent to translucent variably coloured crystals with an adamantine lustre. It is quite soft with a Mohs hardness of 2.5 and a relatively high specific gravity of 6.26 to 6.55.
Todorokite is a complex hydrous manganese oxide mineral with generic chemical formula (Na,Ca,K,Ba,Sr)
1-x(Mn,Mg,Al)
6O
12·3-4H
2O. It was named in 1934 for the type locality, the Todoroki mine, Hokkaido, Japan. It belongs to the prismatic class 2/m of the monoclinic crystal system, but the angle β between the a and c axes is close to 90°, making it seem orthorhombic. It is a brown to black mineral which occurs in massive or tuberose forms. It is quite soft with a Mohs hardness of 1.5, and a specific gravity of 3.49 – 3.82. It is a component of deep ocean basin manganese nodules.
Vauxite is a phosphate mineral with the chemical formula Fe2+Al2(PO4)2(OH)2·6(H2O). It belongs to the laueite – paravauxite group, paravauxite subgroup, although Mindat puts it as a member of the vantasselite Al4(PO4)3(OH)3·9H2O group. There is no similarity in structure between vauxite and paravauxite Fe2+Al2(PO4)2(OH)2·8H2O or metavauxite Fe3+Al2(PO4)2(OH)2·8H2O, even though they are closely similar chemically and all minerals occur together as secondary minerals. Vauxite was named in 1922 for George Vaux Junior (1863–1927), an American attorney and mineral collector.
Optical mineralogy is the study of minerals and rocks by measuring their optical properties. Most commonly, rock and mineral samples are prepared as thin sections or grain mounts for study in the laboratory with a petrographic microscope. Optical mineralogy is used to identify the mineralogical composition of geological materials in order to help reveal their origin and evolution.
A conoscopic interference pattern or interference figure is a pattern of birefringent colours crossed by dark bands, which can be produced using a geological petrographic microscope for the purposes of mineral identification and investigation of mineral optical and chemical properties. The figures are produced by optical interference when diverging light rays travel through an optically non-isotropic substance – that is, one in which the substance's refractive index varies in different directions within it. The figure can be thought of as a "map" of how the birefringence of a mineral would vary with viewing angle away from perpendicular to the slide, where the central colour is the birefringence seen looking straight down, and the colours further from the centre equivalent to viewing the mineral at ever increasing angles from perpendicular. The dark bands correspond to positions where optical extinction would be seen. In other words, the interference figure presents all possible birefringence colours for the mineral at once.
Jonesite is a mineral with the chemical formula Ba4(K,Na)2[Ti4Al2Si10O36]*6H2O. This mineral is named after Francis Tucker Jones (1905–1993), who discovered the mineral while working as a Research Chemical Microscopist at Berkeley in CA. Jonesite has diffraction symmetry of mmm, which implies an orthorhombic system with all three axes perpendicular to each other and the angles between each axis equal to 90 degrees. In addition to symmetrical properties, Jonesite is a biaxial mineral with birefringence, which is a term to describe the difference between index of refraction. Jonesite is anisotropic, meaning the speed of light changes through the mineral, so the mineral shows color when viewed in crossed polarized light under a microscope. The mineral also has medium relief, which is a measure of how well the mineral stands out when viewed under a microscope in plane polarized light. In addition to being one of the rarest minerals in the Benitoite Gem mine located in California, Jonesite also is the first titanosilicate mineral with a porous double-layered crystal structure. This discovery is important because titanosilicate frameworks have industrial uses in energy companies and are used in containing radioactive waste.
Sarabauite (sar-a-bau'-ite) is a red monoclinic sulfide mineral with the chemical formula: CaSb10O10S6.
Kochite is a rare silicate mineral with chemical formula of (Na,Ca)3Ca2(Mn,Ca)ZrTi[(F,O)4(Si2O7)2] or double that. Kochite is a member of the rosenbuschite group.
Sacrofanite is a rare silicate mineral that has the general formula of (Na,Ca)9(Si,Al)12O24(SO4,CO3,OH,Cl)4·n(H2O). It was approved as a mineral by the International Mineralogical Association in 1980. Its name comes from the Sacrofano Caldera in the Monti Sabatini from which it was discovered in Latium, Italy.
Devilline is a sulfate mineral with the chemical formula CaCu4(SO4)2(OH)6·3H2O. The name originates from the French chemist's name, Henri Etienne Sainte-Claire Deville (1818–1881).
Kröhnkite ( Na2Cu(SO4)2•2H2O ) is a rare copper sulfate mineral named after B. Kröhnke who first researched it. Kröhnkite may be replaced by Saranchinaite, the anhydrous form of the mineral, if heated to temperatures above 200 °C (392 °F).
Laplandite has a general formula of Na4CeTiPO4Si7O18•5H2O, and is found primarily in igneous rocks. This silicate mineral has been found as inclusions in pegmatites, primarily in the Kola Peninsula in Lappland, where the mineral's name gets its origin. Laplandite is orthorhombic, which states that crystallographically, it contains three axes of unequal lengths that all intersect at 90 degrees, perpendicular to one another. The shape of the crystal is bipyramidal, and is similar in structure to olivine or aragonite. Because of these different axes lengths, it shows anisotropism, which will allow for the visibility of birefringence. This property can give the mineral very distinct colors when viewed under cross-polarization. Laplandite has three different indices of refraction, which are measures of the speed of light in vacuum divided by the speed of light within the mineral, determined individually on each axis. Due to these different indices, Laplandite is a biaxial mineral, which states that the mineral will have two optic axes. Under the microscope, this mineral has moderate relief, which describes the contrast between Laplandite's refractive index and the refractive index of the mounting medium on which it is placed. The relief can be seen physically as how easily you can see the boundary lines of the mineral under plane polarized light in a petrographic microscope.
Samuelsonite is a complex mineral that is found near North Groton, Grafton County, New Hampshire, US. Additionally, it is most commonly found as a secondary mineral in granite pegmatite. Samuelsonite is named after Peter B. Samuelson, a prospector from Rumney, New Hampshire.
Perite is a mineral that has a general chemical formula of PbBiO2Cl. The name is given for Per Adolf Geijer, a Swedish economic geologist with the Geological Survey of Sweden, who discovered the mineral in 1960 outside of Långban, Sweden. Perite is orthorhombic, space group Cmcm {C2/m 2/c 21/m}. In terms of its optical properties, Perite is anisotropic which means the velocity of light varies depending on direction through the mineral (i.e. it is birefringent). Its calculated relief is 1.45–1.461, which is moderate. It is colorless in plane polarized light, and it is weakly pleochroic. Perite is found in areas near igneous extrusions in places like the Western United States, Southern Australia, and scattered around Europe.
Fluor-uvite is a tourmaline mineral with the chemical formula CaMg3(Al5Mg)(Si6O18)(BO3)3(OH)3F. It is a rare mineral that is found in calcium rich contact metamorphic rocks with increased amounts of boron. Uvite is trigonal hexagonal, which means that it has three equal length axes at 120 degrees, all perpendicular to its fourth axis which has a different length. Uvite is part of the space group 3m. Uvite's hardness has been measured to be 7.5 on the Mohs hardness scale. The color of uvite widely varies, depending on the sample, but is mostly deep green or brown. In regard to uvite's optical properties, it is uniaxial (-) and anisotropic, meaning that the velocity of light in the mineral depends on the path that it takes. In plane polarized light, uvite is colorless to pale yellow and shows weak pleochroism.
Tsumcorite is a rare hydrated lead arsenate mineral that was discovered in 1971, and reported by Geier, Kautz and Muller. It was named after the TSUMeb CORporation mine at Tsumeb, in Namibia, in recognition of the Corporation's support for mineralogical investigations of the orebody at its Mineral Research Laboratory.
Pearceite is one of the four so-called "ruby silvers", pearceite Cu(Ag,Cu)6Ag9As2S11, pyrargyrite Ag3SbS3, proustite Ag3AsS3 and miargyrite AgSbS2. It was discovered in 1896 and named after Dr Richard Pearce (1837–1927), a Cornish–American chemist and metallurgist from Denver, Colorado.
Köttigite is a rare hydrated zinc arsenate which was discovered in 1849 and named by James Dwight Dana in 1850 in honour of Otto Friedrich Köttig (1824–1892), a German chemist from Schneeberg, Saxony, who made the first chemical analysis of the mineral. It has the formula Zn3(AsO4)2·8H2O and it is a dimorph of metaköttigite, which means that the two minerals have the same formula, but a different structure: köttigite is monoclinic and metaköttigite is triclinic. There are several minerals with similar formulae but with other cations in place of the zinc. Iron forms parasymplesite Fe2+3(AsO4)2·8H2O; cobalt forms the distinctively coloured pinkish purple mineral erythrite Co3(AsO4)2·8H2O and nickel forms annabergite Ni3(AsO4)2·8H2O. Köttigite forms series with all three of these minerals and they are all members of the vivianite group.
Carminite (PbFe3+2(AsO4)2(OH)2) is an anhydrous arsenate mineral containing hydroxyl. It is a rare secondary mineral that is structurally related to palermoite (Li2SrAl4(PO4)4(OH)4). Sewardite (CaFe3+2(AsO4)2(OH)2) is an analogue of carminite, with calcium in sewardite in place of the lead in carminite. Mawbyite is a dimorph (same formula, different structure) of carminite; mawbyite is monoclinic and carminite is orthorhombic. It has a molar mass of 639.87 g. It was discovered in 1850 and named for the characteristic carmine colour.
