Melanie Sanford

Last updated
Melanie Sanford
Born (1975-06-16) June 16, 1975 (age 48)
NationalityAmerican
Alma mater Yale University (BS, MS)
California Institute of Technology (PhD)
Awards MacArthur Fellowship, Sackler Prize
Scientific career
Fields Organometallic Chemistry, Organic Chemistry, Catalysis
Institutions University of Michigan
Thesis Synthetic and mechanistic investigations of ruthenium olefin metathesis catalysts  (2001)
Doctoral advisor Robert H. Grubbs
Other academic advisors Robert H. Crabtree, John T. Groves

Melanie Sarah Sanford (born June 16, 1975) is an American chemist, currently the Moses Gomberg Distinguished University Professor of Chemistry and Arthur F. Thurnau Professor of Chemistry at the University of Michigan. [1] She is a Fellow for the American Association for the Advancement of Science, and was elected a member of the National Academy of Sciences [2] and the American Academy of Arts and Sciences in 2016. [3] She has served as an executive editor of the Journal of the American Chemical Society since 2021, having been an associate editor of the since 2014. [4]

Contents

Life

Sanford was born and grew up in Providence, Rhode Island. She attended Classical High School. She graduated from Yale University with a BS and MS in chemistry in 1996, having carried out research with Robert H. Crabtree, while competing for the Yale Gymnastics NCAA team. She graduated from the California Institute of Technology with a Ph.D. in 2001, where she studied Chemistry with Robert H. Grubbs. She did postdoctoral work at Princeton University, where she studied with John T. Groves. [5]

Sanford began her academic career as an assistant professor at the University of Michigan in 2003. She was promoted to associate professor with tenure in 2007 and full professor in 2013.

Research

Sanford is best known for her studies of high-valent organopalladium species, particularly those implicated in Pd-catalyzed C–H functionalization reactions. [6] [7] Her group has also developed new methods to access fluorinated and radiofluorinated materials for agrochemicals, pharmaceuticals [8] and radiology. [9] In a collaboration with Matthew Sigman at the University of Utah her group has designed new compounds for use in redox flow batteries. [10] [11]

Awards and honors

Sanford has received numerous awards and honors including but not limited to:

Recent publications

  1. Ferguson, D. M.; Bour, J. R.; Canty, A. J.; Kampf, J. W.; Sanford, M. S. "Aryl–CF3 Coupling from Phosphinoferrocene-Ligated Palladium(II) Complexes," Organometallics 2019, ASAP Article. [50]
  2. Lee, S. J.; Makaravage, K. J.; Brooks, A. F.; Scott, P. J. H.; Sanford, M. S. "Cu‐Mediated Aminoquinoline‐Directed Radiofluorination of Aromatic C–H Bonds with K18F," Angew. Chem. Int. Ed.2019, ASAP Article. [51]
  3. Yang, L.; Brooks, A. F.; Makaravage, K. J.; Zhang, H.; Sanford, M. S.; Scott, P. J. H.; Shao, X. "Radiosynthesis of [11C]LY2795050 for Preclinical and Clinical PET Imaging Using Cu(II)-Mediated Cyanation," ACS Med. Chem. Lett.2018, 9, 1274–1279. [52]
  4. Malapit, C. A.; Bour, J. R.; Brigham, C. E.; Sanford, M. S. "Base-free nickel-catalysed decarbonylative Suzuki–Miyaura coupling of acid fluorides," Nature 2018, 563, 100–104. [53]
  5. Aguilera, E. Y.; Sanford, M. S. "Model Complexes for the Palladium-Catalyzed Transannular C–H Functionalization of Alicyclic Amines," Organometallics 2018, 1, 138–142. [54]
  6. Mantell, M.; Kampf, J. W.; Sanford, M. S. "Improved Synthesis of [CpRRhCl2]2 Complexes," Organometallics 2018, 37, 3240–3242. [55]
  7. Schimler, S. D.; Froese, R. D. J.; Bland, D. C.; Sanford, M. S. "Reactions of Arylsulfonate Electrophiles with NMe4F: Mechanistic Insight, Reactivity, and Scope," J. Org. Chem.201883, 11178–11190. [55]
  8. Cabrera, P. J.; Lee, M.; Sanford, M. S. "Second-Generation Palladium Catalyst System for Transannular C–H Functionalization of Azabicycloalkanes," J. Am. Chem. Soc.2018, 140, 5599–5606. [56]
  9. Makaravage, K. J.; Shao, X.; Brooks, A. F.; Yang, L.; Sanford, M. S.; Scott, P. J. H. "Copper(II)-Mediated [11C]Cyanation of Arylboronic Acids and Arylstannanes," Org. Lett. 2018, 20, 1530–1533. [57]
  10. Hendricks, K. H.; Robinson, S. G.; Braten, M. N.; Sevov, C. S.; Helms, B. A.; Sigman, M. S.; Minteer, S. D.; Sanford, M. S. "High-Performance Oligomeric Catholytes for Effective Macromolecular Separation in Nonaqueous Redox Flow Batteries," ACS Cent. Sci.2018, 4, 189–196. [58]
  11. James, B. R.; Boissonnault, J. A.; Wong-Foy, A. G.; Matzger, A. J.; Sanford, M. S. "Structure activity relationships in metal–organic framework catalysts for the continuous flow synthesis of propylene carbonate from CO2 and propylene oxide," RSC Adv.2018, 8, 2132–2137. [59]
  12. Topczewski, J. T.; Cabrera, P. J.; Saper, N. I.; Sanford, M. S. "Palladium-Catalysed Transannular C–H Functionalization of Alicyclic Amines," Nature 2016, 531, 220–224. [60]
  13. Cook, A. K.; Schimler, S. D.; Matzger, A. J.; Sanford, M. S. "Catalyst-Controlled Selectivity in the C–H Borylation of Methane and Ethane," Science 2016, 351, 1421–1424. [61]
  14. Camasso, N. M.; Sanford, M. S. "Design, Synthesis, and Carbon-Heteroatom Coupling Reactions of Organometallic Nickel (IV) Complexes," Science 2015, 347, 1218–1220. [62]
  15. Hickman, A. J.; Sanford, M. S. "High-Valent Organometallic Copper and Palladium in Catalysis," Nature 2012, 484, 177–185. [63]

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References

  1. ↑ Melanie S Sanford
  2. ↑ "National Academy of Sciences Members and Foreign Associates Elected" . Retrieved 2016-05-05.
  3. ↑ "Press Releases - American Academy of Arts & Sciences". amacad.org. Retrieved 2018-07-26.
  4. ↑ "Editorial Board". pubs.acs.org. Retrieved 2021-05-20.
  5. ↑ Jim Austin (November 24, 2006). "Melanie Sanford: The Interview". Science.
  6. ↑ Dick, Allison R.; Hull, Kami L.; Sanford, Melanie S. (2004). "A Highly Selective Catalytic Method for the Oxidative Functionalization of C–H Bonds". Journal of the American Chemical Society. 126 (8): 2300–2301. doi:10.1021/ja031543m. PMID   14982422.
  7. ↑ Lyons, Thomas W.; Sanford, Melanie S. (2010). "Palladium-Catalyzed Ligand-Directed C–H Functionalization Reactions". Chemical Reviews. 110 (2): 1147–1169. doi:10.1021/cr900184e. PMC   2836499 . PMID   20078038.
  8. ↑ Allen, Laura J.; Lee, Shin Hee; Cheng, Yang; Hanley, Patrick S.; Muhuhi, Joseck M.; Kane, Elisabeth; Powers, Stacey L.; Anderson, John E.; Bell, Bruce M. (2014-07-16). "Developing Efficient Nucleophilic Fluorination Methods and Application to Substituted Picolinate Esters". Organic Process Research & Development. 18 (8): 1045–1054. doi:10.1021/op5001258. ISSN   1083-6160.
  9. ↑ Mossine, Andrew V.; Brooks, Allen F.; Makaravage, Katarina J.; Miller, Jason M.; Ichiishi, Naoko; Sanford, Melanie S.; Scott, Peter J. H. (2015-11-14). "Synthesis of [18F]Arenes via the Copper-Mediated [18F]Fluorination of Boronic Acids". Organic Letters. 17 (23): 5780–5783. doi:10.1021/acs.orglett.5b02875. ISSN   1523-7060. PMC   4672358 . PMID   26568457.
  10. ↑ Cabrera, Pablo J.; Yang, Xingyi; Suttil, James A.; Hawthorne, Krista L.; Brooner, Rachel E. M.; Sanford, Melanie S.; Thompson, Levi T. (2015-07-06). "Complexes Containing Redox Noninnocent Ligands for Symmetric, Multielectron Transfer Nonaqueous Redox Flow Batteries". The Journal of Physical Chemistry C. 119 (28): 15882–15889. doi:10.1021/acs.jpcc.5b03582. ISSN   1932-7447.
  11. ↑ Sevov, Christo S.; Hickey, David P.; Cook, Monique E.; Robinson, Sophia G.; Barnett, Shoshanna; Minteer, Shelley D.; Sigman, Matthew S.; Sanford, Melanie S. (2017-02-21). "Physical Organic Approach to Persistent, Cyclable, Low-Potential Electrolytes for Flow Battery Applications". Journal of the American Chemical Society. 139 (8): 2924–2927. doi:10.1021/jacs.7b00147. ISSN   0002-7863. PMID   28219237.
  12. ↑ "The Herbert Newby McCoy Award is given in recognition of outstanding achievement in research by Chemistry graduate students". wag.caltech.edu. Retrieved 2019-01-26.
  13. 1 2 "Melanie Sanford | Blavatnik Awards for Young Scientists". blavatnikawards.org. Retrieved 2019-01-26.
  14. ↑ "Sanford, Melanie S." beckman-foundation.org. Archived from the original on 2019-03-27. Retrieved 2019-01-26.
  15. 1 2 Austin, Jim (2013-09-27). "Melanie Sanford: The Interview". Science | AAAS. Retrieved 2019-01-26.
  16. ↑ "What does the Eli Lilly Grantee Award provide to academic research?" (PDF). chem.ucla.edu. Retrieved 2019-01-27.
  17. ↑ "Research Corporation – Annual Report" (PDF).
  18. ↑ "Franco-Spanish Prize: C. Nájera / ACS Pure Chemistry Award: M. S. Sanford / AstraZeneca Award in Chemistry: V. M. Dong". Angewandte Chemie International Edition. 50 (4): 801. 2011-01-24. doi:10.1002/anie.201006893. ISSN   1521-3773.
  19. ↑ "White House Announces 2006 Awards for Early Career Scientists and Engineers" (PDF). 2008-07-19. Archived from the original (PDF) on 2008-07-19. Retrieved 2019-01-26.
  20. ↑ "ACS 2008 National Award Winners". Chemical & Engineering News. 85 (34). cen.acs.org. August 20, 2007. Retrieved 2019-01-26.
  21. ↑ "Roche Names Excellence in Chemistry Award Winners | August 6, 2007 Issue - Vol. 85 Issue 32 | Chemical & Engineering News". cen.acs.org. Retrieved 2019-01-26.
  22. ↑ "Arthur C. Cope Scholar Awards". American Chemical Society. Retrieved 2019-01-26.
  23. ↑ "BASF Catalysis Award 2015 /". 11 May 2015. Retrieved 2019-01-26.
  24. ↑ "Individual Award for Outstanding Contributions to Undergraduate Education | U-M LSA U-M College of LSA". lsa.umich.edu. Retrieved 2019-01-26.
  25. ↑ "Class of 1923 Memorial Teaching Award and John Dewey Award | U-M LSA U-M College of LSA". lsa.umich.edu. Retrieved 2019-01-26.
  26. ↑ "Award Recipients | Phi Lambda Upsilon". philambdaupsilon.org. Retrieved 2019-01-26.
  27. ↑ "U-M Office of the Provost | Programs | Thurnau Professorships". provost.umich.edu. Retrieved 2019-01-26.
  28. ↑ "ACS Award in Pure Chemistry". American Chemical Society. Retrieved 2019-01-26.
  29. ↑ "RSC Fluorine Chemistry Prize". rsc.org. Retrieved 2019-01-26.
  30. ↑ "Melanie Sanford, Organometallic Chemist". MacArthur Foundation. Retrieved 3 February 2015.
  31. ↑ classicalalum2. "Distinguished Alumni Awards". Classical High School Alumni Association. Archived from the original on 2019-01-26. Retrieved 2019-01-26.{{cite web}}: CS1 maint: numeric names: authors list (link)
  32. ↑ "Alumni". The Groves Lab. 2012-09-19. Retrieved 2019-01-26.
  33. ↑ "Melanie Sanford Awarded Thieme-IUPAC Prize | Chemical & Engineering News". cen.acs.org. Retrieved 2019-01-26.
  34. ↑ "Ipatieff Prize". American Chemical Society. Retrieved 2019-01-26.
  35. ↑ Tetrahedron.
  36. ↑ "The Raymond and Beverly Sackler International Prize in the Physical Sciences". 6 June 2012. Retrieved June 25, 2013.
  37. ↑ "Sierra Nevada Local Section, American Chemical Society". chem.unr.edu. Archived from the original on 2019-01-26. Retrieved 2019-01-26.
  38. ↑ "Faculty Recognition Awards". Rackham Graduate School: University of Michigan. Retrieved 2019-01-26.
  39. ↑ "OMCOS 18". barcelocongresos.com.es. Retrieved 2019-01-26.
  40. ↑ "Activities". Catalysis Science & Technology. Archived from the original on 2019-03-07. Retrieved 2019-01-26.
  41. ↑ "Four U-M faculty elected to American Academy of Arts and Sciences". University of Michigan News. 2016-04-20. Retrieved 2019-01-26.
  42. ↑ "Melanie Sanford". nasonline.org. Retrieved 2019-01-26.
  43. ↑ "U-M professors elected to National Academy of Sciences". University of Michigan News. 2016-05-05. Retrieved 2019-01-26.
  44. ↑ Record, Safiya Merchant The University. "2018 lectures set for seven Distinguished University Professors". The University Record. Retrieved 2019-01-26.
  45. ↑ "2016 ACS Fellows". American Chemical Society. Retrieved 2019-01-26.
  46. ↑ "Melanie S. Sanford Wins 2017 Blavatnik National Award". ACS Axial. 2017-07-13. Retrieved 2019-01-26.
  47. ↑ "Winners of 2017 Blavatnik National Awards for Young Scientists | Blavatnik Awards for Young Scientists". blavatnikawards.org. Retrieved 2019-01-26.
  48. ↑ "National Finalists | Blavatnik Awards for Young Scientists". blavatnikawards.org. Retrieved 2019-01-26.
  49. ↑ "LSA Chemist Melanie Sanford Wins 2017 Blavatnik National Award for Young Scientists | U-M LSA U-M College of LSA". lsa.umich.edu. Retrieved 2019-01-26.
  50. ↑ Ferguson, Devin M.; Bour, James R.; Canty, Allan J.; Kampf, Jeff W.; Sanford, Melanie S. (2019-01-04). "Aryl–CF3 Coupling from Phosphinoferrocene-Ligated Palladium(II) Complexes". Organometallics. 38 (2): 519–526. doi:10.1021/acs.organomet.8b00828. ISSN   0276-7333. S2CID   104361738.
  51. ↑ Lee, So Jeong; Makaravage, Katarina J.; Brooks, Allen F.; Scott, Peter J. H.; Sanford, Melanie S. (2019). "Copper-Mediated Aminoquinoline-Directed Radiofluorination of Aromatic C−H Bonds with K18F". Angewandte Chemie International Edition. 58 (10): 3119–3122. doi:10.1002/anie.201812701. ISSN   1521-3773. PMC   6476334 . PMID   30605563.
  52. ↑ Yang, Lingyun; Brooks, Allen F.; Makaravage, Katarina J.; Zhang, Huibin; Sanford, Melanie S.; Scott, Peter J. H.; Shao, Xia (2018-12-13). "Radiosynthesis of [11C]LY2795050 for Preclinical and Clinical PET Imaging Using Cu(II)-Mediated Cyanation". ACS Medicinal Chemistry Letters. 9 (12): 1274–1279. doi:10.1021/acsmedchemlett.8b00460. PMC   6295869 . PMID   30613339.
  53. ↑ Sanford, Melanie S.; Conor E. Brigham; Bour, James R.; Malapit, Christian A. (November 2018). "Base-free nickel-catalysed decarbonylative Suzuki–Miyaura coupling of acid fluorides". Nature. 563 (7729): 100–104. Bibcode:2018Natur.563..100M. doi:10.1038/s41586-018-0628-7. ISSN   1476-4687. PMC   6212315 . PMID   30356210.
  54. ↑ Aguilera, Ellen Y.; Sanford, Melanie S. (2019-01-14). "Model Complexes for the Palladium-Catalyzed Transannular C–H Functionalization of Alicyclic Amines". Organometallics. 38 (1): 138–142. doi:10.1021/acs.organomet.8b00533. ISSN   0276-7333. PMC   6527359 . PMID   31118540.
  55. 1 2 Mantell, Mark A.; Kampf, Jeff W.; Sanford, Melanie (2018-10-08). "Improved Synthesis of [CpRRhCl2]2 Complexes". Organometallics. 37 (19): 3240–3242. doi:10.1021/acs.organomet.8b00400. ISSN   0276-7333. S2CID   105559506.
  56. ↑ Cabrera, Pablo J.; Lee, Melissa; Sanford, Melanie S. (2018-04-25). "Second-Generation Palladium Catalyst System for Transannular C–H Functionalization of Azabicycloalkanes". Journal of the American Chemical Society. 140 (16): 5599–5606. doi:10.1021/jacs.8b02142. ISSN   0002-7863. PMC   5956530 . PMID   29652497.
  57. ↑ Makaravage, Katarina J.; Shao, Xia; Brooks, Allen F.; Yang, Lingyun; Sanford, Melanie S.; Scott, Peter J. H. (2018-03-16). "Copper(II)-Mediated [11C]Cyanation of Arylboronic Acids and Arylstannanes". Organic Letters. 20 (6): 1530–1533. doi:10.1021/acs.orglett.8b00242. ISSN   1523-7060. PMC   5892454 . PMID   29484880.
  58. ↑ Hendriks, Koen H.; Robinson, Sophia G.; Braten, Miles N.; Sevov, Christo S.; Helms, Brett A.; Sigman, Matthew S.; Minteer, Shelley D.; Sanford, Melanie S. (2018-02-28). "High-Performance Oligomeric Catholytes for Effective Macromolecular Separation in Nonaqueous Redox Flow Batteries". ACS Central Science. 4 (2): 189–196. doi:10.1021/acscentsci.7b00544. ISSN   2374-7943. PMC   5833001 . PMID   29532018.
  59. ↑ Sanford, Melanie S.; Matzger, Adam J.; Wong-Foy, Antek G.; Boissonnault, Jake A.; James, Bryant R. (2018-01-05). "Structure activity relationships in metal–organic framework catalysts for the continuous flow synthesis of propylene carbonate from CO2 and propylene oxide". RSC Advances. 8 (4): 2132–2137. Bibcode:2018RSCAd...8.2132J. doi: 10.1039/C7RA13245J . ISSN   2046-2069. PMC   9077212 . PMID   35542571.
  60. ↑ Sanford, Melanie S.; Noam I. Saper; Cabrera, Pablo J.; Topczewski, Joseph J. (March 2016). "Palladium-catalysed transannular C–H functionalization of alicyclic amines". Nature. 531 (7593): 220–224. Bibcode:2016Natur.531..220T. doi:10.1038/nature16957. ISSN   1476-4687. PMC   5082708 . PMID   26886789.
  61. ↑ Sanford, Melanie S.; Matzger, Adam J.; Schimler, Sydonie D.; Cook, Amanda K. (2016-03-25). "Catalyst-controlled selectivity in the Câ€"H borylation of methane and ethane". Science. 351 (6280): 1421–1424. doi: 10.1126/science.aad9289 . ISSN   0036-8075. PMID   27013725.
  62. ↑ Sanford, Melanie S.; Camasso, Nicole M. (2015-03-13). "Design, synthesis, and carbon-heteroatom coupling reactions of organometallic nickel(IV) complexes". Science. 347 (6227): 1218–1220. Bibcode:2015Sci...347.1218C. doi: 10.1126/science.aaa4526 . ISSN   0036-8075. PMID   25766226.
  63. ↑ Melanie S. Sanford; Hickman, Amanda J. (April 2012). "High-valent organometallic copper and palladium in catalysis". Nature. 484 (7393): 177–185. Bibcode:2012Natur.484..177H. doi:10.1038/nature11008. ISSN   1476-4687. PMC   4384170 . PMID   22498623.
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