Names | |
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IUPAC name 1-(5-tetrazolyl)-3-guanyl tetrazene hydrate | |
Other names Tetracene [1] | |
Identifiers | |
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3D model (JSmol) | |
ECHA InfoCard | 100.128.336 |
PubChem CID | |
UNII | |
CompTox Dashboard (EPA) | |
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Properties | |
C2H6N10·H2O | |
Molar mass | 188.15 g/mol |
Appearance | Pale yellow/colorless crystal plates [1] |
Density | 1.7 g/cm3 |
Boiling point | Decomposes at160 °C (320 °F; 433 K) |
Explosive data | |
Shock sensitivity | High |
Friction sensitivity | High |
Detonation velocity | ~4000 m/s |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). |
Tetrazene (1-(5-tetrazolyl)-3-guanyl tetrazene hydrate) [2] is an explosive material used for sensitization of priming compositions. It is a derivative of the compound with the IUPAC name tetrazene.
Tetrazene is slightly more impact-sensitive than mercury fulminate. When pressed enough, its sensitivity is reduced or destroyed; this is known as dead pressing. It also decomposes in boiling water. In contact with fire, it readily explodes, producing large amounts of black smoke. It is prepared by reacting sodium nitrite with an aminoguanidine salt dissolved in acetic acid at 30–40 °C.
The decomposition of tetrazene is quite rapid around 90 °C. A sample of tetrazene was heated in an oven at 90 °C and its rate of thermal decomposition was monitored by infrared and ultraviolet spectroscopy. [3] The thermal decomposition reaction is autocatalytic and it is likely that the same reaction can occur at even lower temperatures, however at much slower rates.
Many explosives are considered to be highly sensitive to mechanical stimuli such as impact, friction, stab, heat, static electricity, flame, etc. Since explosive compounds are subject to friction practically every time they are handled, it is of particular interest to be aware of the sensitivity to friction. The sensitivity of tetrazene was determined using a FSKM-PEx friction sensitivity tester. [4] The probability of ignition of tetrazene is 100 percent likely at 27N of frictional force. [4]
Instances of occupational rhinitis, dermatitis, and asthma have been reported due to prolonged exposure to tetrazene. [5]
An explosive is a reactive substance that contains a great amount of potential energy that can produce an explosion if released suddenly, usually accompanied by the production of light, heat, sound, and pressure. An explosive charge is a measured quantity of explosive material, which may either be composed solely of one ingredient or be a mixture containing at least two substances.
Trinitrotoluene, more commonly known as TNT (and more specifically 2,4,6-trinitrotoluene, and by its preferred IUPAC name 2-methyl-1,3,5-trinitrobenzene), is a chemical compound with the formula C6H2(NO2)3CH3. TNT is occasionally used as a reagent in chemical synthesis, but it is best known as an explosive material with convenient handling properties. The explosive yield of TNT is considered to be the standard comparative convention of bombs and asteroid impacts. In chemistry, TNT is used to generate charge transfer salts.
In organic chemistry, isocyanate is the functional group with the formula R−N=C=O. Organic compounds that contain an isocyanate group are referred to as isocyanates. An organic compound with two isocyanate groups is known as a diisocyanate. Diisocyanates are manufactured for the production of polyurethanes, a class of polymers.
Allergies, also known as allergic diseases, are various conditions caused by hypersensitivity of the immune system to typically harmless substances in the environment. These diseases include hay fever, food allergies, atopic dermatitis, allergic asthma, and anaphylaxis. Symptoms may include red eyes, an itchy rash, sneezing, coughing, a runny nose, shortness of breath, or swelling. Note that food intolerances and food poisoning are separate conditions.
Mercury(II) fulminate, or Hg(CNO)2, is a primary explosive. It is highly sensitive to friction, heat and shock and is mainly used as a trigger for other explosives in percussion caps and detonators. Mercury(II) cyanate, though its chemical formula is identical, has a different atomic arrangement, making the cyanate and fulminate anions isomers.
2,4,6-Trinitrophenylmethylnitramine or tetryl (C7H5N5O8) is an explosive compound used to make detonators and explosive booster charges.
An allergen is an otherwise harmless substance that triggers an allergic reaction in sensitive individuals by stimulating an immune response.
Nitrogen dioxide is a chemical compound with the formula NO2. One of several nitrogen oxides, nitrogen dioxide is a reddish-brown gas. It is a paramagnetic, bent molecule with C2v point group symmetry. Industrially, NO2 is an intermediate in the synthesis of nitric acid, millions of tons of which are produced each year, primarily for the production of fertilizers.
Rhinitis, also known as coryza, is irritation and inflammation of the mucous membrane inside the nose. Common symptoms are a stuffy nose, runny nose, sneezing, and post-nasal drip.
Food intolerance is a detrimental reaction, often delayed, to a food, beverage, food additive, or compound found in foods that produces symptoms in one or more body organs and systems, but generally refers to reactions other than food allergy. Food hypersensitivity is used to refer broadly to both food intolerances and food allergies.
Dichlorine monoxide is an inorganic compound with the molecular formula Cl2O. It was first synthesised in 1834 by Antoine Jérôme Balard, who along with Gay-Lussac also determined its composition. In older literature it is often referred to as chlorine monoxide, which can be a source of confusion as that name now refers to the ClO• radical.
Tetrasulfur tetranitride is an inorganic compound with the formula S4N4. This vivid orange, opaque, crystalline explosive is the most important binary sulfur nitride, which are compounds that contain only the elements sulfur and nitrogen. It is a precursor to many S-N compounds and has attracted wide interest for its unusual structure and bonding.
Copper(I) acetylide, Kupfercarbid or cuprous acetylide, is a chemical compound with the formula Cu2C2. Although never characterized by X-ray crystallography, the material has been claimed at least since 1856. One form is claimed to be a monohydrate with formula Cu
2C
2.H
2O is a reddish-brown explosive powder.
Erythritol tetranitrate (ETN) is an explosive compound chemically similar to PETN, though it is thought to be slightly more sensitive to friction and impact.
Imidazole-1-sulfonyl azide is an organic azide compound that can be used as an alternative organic synthesis reagent to trifluoromethanesulfonyl azide. It is an explosive colorless liquid, but some of its organic-soluble salts can be safely handled and stored as a solid.
In explosives engineering, sensitivity refers to the degree to which an explosive can be initiated by impact, heat, or friction. Current in-use standard methods of mechanical sensitivity determination differ by the sample preparation, sample arrangement, instrument type, go/not go criteria, and the statistical analysis of results.
Bromine azide is an explosive inorganic compound with the formula BrN3. It has been described as a crystal or a red liquid at room temperature. It is extremely sensitive to small variations in temperature and pressure, with explosions occurring at Δp ≥ 0.05 Torr and also upon crystallization, thus extreme caution must be observed when working with this chemical.
Nickel hydrazine nitrate (NHN), (chemical formula: [Ni(N2H4)3](NO3)2 is an energetic material having explosive properties in between that of primary explosive and a secondary explosive. It is a salt of a coordination compound of nickel with a reaction equation of 3N2H4·H2O + Ni(NO3)2 →〔Ni(N2H4)3〕(NO3)2 + 3H2O
1-Diazidocarbamoyl-5-azidotetrazole, often jokingly referred to as azidoazide azide, is a heterocyclic inorganic compound with the formula C2N14. It is a highly reactive and extremely sensitive explosive.
Dinitroglycoluril (DNGU) is a high explosive chemical compound with the formula C4H4N6O6. Dinitroglycoluril is of growing interest due to its stability, ability to mix with oxygen positive explosives to form composites, and it is a precursor to tetranitroglycoluril.