Tonka (fuel)

Last updated

Tonka (also TONKA-250 and R-Stoff) is the name given to a German-designed rocket propellant first used in the Wasserfall missile, [1] and recently used by North Korea. [2] It was used in the Soviet Union under the name TG-02, for example in the engine designs of the A.M. Isayev Chemical Engineering Design Bureau.

Its name is a reference to the tonka bean. [3] Being invented during the Second World War, it has no connection to the similarly named toys.

Its composition is approximately 50% triethylamine and 50% xylidine, most commonly used with nitric acid or its anhydrous nitric oxide derivatives (classified as the AK-2x family in the Soviet Union) as the oxidiser; the combination is hypergolic and has a maximum practical specific impulse of approximately 2.12–2.43 km/s (216–248 s) at sea level, with the latter figure stated as a specification for the R-21 Submarine Launched Ballistic Missile, first fielded in 1963. [4]

The Soviet Union reverse-engineered the Wasserfall missile and investigated the use of hypergolic propellants for the eventually abandoned Burya intercontinental cruise missile project. It put TG-02/AK-2x fuelled engines into service with the Kh-22 cruise missile [5] and the S5.4 de-orbit engine used on the Vostok and Voskhod spacecraft and the Zenit satellite. [6]

The most globalized use of Tonka is as an igniter in many Soviet Scud missile variants and its descendants, such as the North Korean Nodong, which are principally propelled by nitric acid and kerosene (TM-185). This combination is not hypergolic so needs an ignition source, supplied by a system that injects a few kilograms of Tonka fuel when ignition is desired. [7] The progenitor Scud engine, the S2.253, with a specific impulse of 2.15 km/s (219 s) at sea level, [8] popularized this ignition arrangement.

Triethylamine/xylidine mixtures composed the TX and TX2 fuels of the French SEPR rocket engines of the 1950s, used for auxiliary rocket power in the Mirage IIIC. [9] In aircraft use, TX fuels were later replaced by non-toxic kerosene jet fuels, simplifying fuelling of the aircraft. Little change was required to the engines but as this was no longer hypergolic with nitric acid, a small tank of TX was retained for ignition.

The use of Tonka by amateurs is not advised,[ citation needed ] because the exact proportions of ingredients necessary for the mixture to work as desired, rather than fail catastrophically, is a function both of the purity of the ingredients and their temperature during use.

See also

Related Research Articles

<span class="mw-page-title-main">Hypergolic propellant</span> Type of rocket engine fuel

A hypergolic propellant is a rocket propellant combination used in a rocket engine, whose components spontaneously ignite when they come into contact with each other.

<span class="mw-page-title-main">Ruhrstahl X-4</span> WWII guided missile developed by Nazi Germany

The Ruhrstahl Ru 344 X-4 or Ruhrstahl-Kramer RK 344 was a wire-guided air-to-air missile designed by Germany during World War II. The X-4 did not see operational service and thus was not proven in combat but inspired considerable post-war work around the world, and was the basis for the development of several ground-launched anti-tank missiles.

<span class="mw-page-title-main">Liquid-propellant rocket</span> Rocket engine that uses liquid fuels and oxidizers

A liquid-propellant rocket or liquid rocket utilizes a rocket engine that uses liquid propellants. Gaseous propellants may also be used but are not common because of their low density and difficulty with common pumping methods. Liquids are desirable because they have a reasonably high density and high specific impulse (Isp). This allows the volume of the propellant tanks to be relatively low. The rocket propellants are usually pumped into the combustion chamber with a lightweight centrifugal turbopump, although some aerospace companies have found ways to use electric pumps with batteries, allowing the propellants to be kept under low pressure. This permits the use of low-mass propellant tanks that do not need to resist the high pressures needed to store significant amounts of gasses, resulting in a low mass ratio for the rocket.

The highest specific impulse chemical rockets use liquid propellants. They can consist of a single chemical or a mix of two chemicals, called bipropellants. Bipropellants can further be divided into two categories; hypergolic propellants, which ignite when the fuel and oxidizer make contact, and non-hypergolic propellants which require an ignition source.

Triethylamine is the chemical compound with the formula N(CH2CH3)3, commonly abbreviated Et3N. It is also abbreviated TEA, yet this abbreviation must be used carefully to avoid confusion with triethanolamine or tetraethylammonium, for which TEA is also a common abbreviation. It is a colourless volatile liquid with a strong fishy odor reminiscent of ammonia. Like diisopropylethylamine (Hünig's base), triethylamine is commonly employed in organic synthesis, usually as a base.

<span class="mw-page-title-main">R-21 (missile)</span> Submarine-launched ballistic missile

The R-21 was a submarine-launched ballistic missile in service with the Soviet Union between 1963 and 1989. It was the first Soviet nuclear missile that could be launched from a submerged submarine, and also had twice the range of earlier missiles. It replaced the R-11FM and R-13 (SS-N-4) on many Golf and Hotel-class submarines, and was in turn superseded by the R-27 missile carried by Yankee-class submarines.

<span class="mw-page-title-main">Taifun (rocket)</span> Unguided anti-aircraft rocket

Taifun was a German World War II anti-aircraft unguided rocket system. Waves of small, relatively cheap, Taifun flak rockets were to be launched en masse into Allied bomber formations. Although never deployed operationally, the Taifun was further developed in the US as the 76mm HEAA T220 "Loki" Rocket.

<span class="mw-page-title-main">Bereznyak-Isayev BI-1</span> Experimental WW2-era Soviet rocket-powered interceptor

The Bereznyak-Isayev BI-1 was a Soviet short-range rocket-powered interceptor developed during the Second World War.

Devil's venom was a nickname coined by Soviet rocket scientists for a liquid rocket fuel composed of a dangerous combination of red fuming nitric acid and hydrazine—specifically, hypergolic UDMH-nitric acid. Both propellants are extremely dangerous individually: Nitric acid is highly corrosive and causes offgassing of toxic nitrogen dioxide during reactions, or even simply while exposed to air in its highly concentrated "red fuming" form used as rocket propellant. UDMH is both toxic and corrosive. Despite these dangers, the pairing has been used in rocketry because this combination of fuel and oxidizer is hypergolic, which makes rockets using these materials simpler. Further, both the fuel and oxidizer have high boiling points compared to other rocket fuels and oxidizers, allowing rockets to be stored ready for launch for long periods without the fuel or oxidizer boiling off and needing to be replenished.

The Keldysh bomber was a Soviet design for a rocket-powered sub-orbital bomber spaceplane, which drew heavily upon work carried out by Eugen Sänger and Irene Bredt for the German Silbervogel project.

<span class="mw-page-title-main">2-Dimethylaminoethylazide</span> Chemical compound

2-Dimethylaminoethylazide (DMAZ) is a liquid rocket fuel being investigated for use as a spacecraft propellent to replace the toxic, carcinogenic monomethylhydrazine. It is a member of the competitive impulse non-carcinogenic hypergol (CINCH) family which were assessed as a replacement for hydrazine-derived propellants. DMAZ was also found to be sensitive to impact, direct flame, shock wave, heat in confined space, and electrostatic discharge.

The Hwasong-10, also known by the names BM-25 and Musudan, is a mobile intermediate-range ballistic missile developed by North Korea. Hwasong-10 was first revealed to the international community in a military parade on 10 October 2010 celebrating the Workers' Party of Korea's 65th anniversary, although experts believe these were mock-ups of the missile. Hwasong-10 resembles the shape of the Soviet Union's R-27 Zyb submarine-launched missile, but is slightly longer. It is based on the R-27, which uses a 4D10 engine propelled by unsymmetrical dimethylhydrazine (UDMH) and nitrogen tetroxide (NTO). These propellants are much more advanced than the kerosene compounds used in North Korea's Scuds and Nodong missiles.

The BMW 109-558 is a liquid fuelled sustainer rocket motor developed by BMW at their Bruckmühl facility, in Germany during the Second World War.

<span class="mw-page-title-main">S5.92</span>

The S5.92 is a Russian rocket engine, currently used on the Fregat upper stage.

<span class="mw-page-title-main">RD-214</span> Rocket engine

The RD-214 (GRAU Index 8D59) was a liquid rocket engine, burning AK-27I (a mixture of 73% nitric acid and 27% N2O4 + iodine passivant and TM-185 (a kerosene and gasoline mix) in the gas generator cycle. As was the case with many V-2 influenced engines, the single turbine was driven by steam generated by catalytic decomposition of H2O2. It also had four combustion chambers and vector control was achieved by refractory vanes protruding into the nozzle's exhaust.

<span class="mw-page-title-main">A.M. Isayev Chemical Engineering Design Bureau</span>

The A.M. Isayev Chemical Engineering Design Bureau, also known as KB KhimMash or just KBKhM, is a Russian rocket engine design and manufacturing company. It is located in the city of Korolyov. It started as the OKB-2 division of the NII-88 research institute, where A.Isaev directed the development of liquid rocket engines for ballistic missile submarines.

<span class="mw-page-title-main">SEPR 84</span>

The SEPR 84 is a family of liquid-propellant rocket engines used as boosters for the Dassault Mirage III mixed-power high-altitude interceptor aircraft of the 1960s. The engine was one of several similar developed by SEPR.

<span class="mw-page-title-main">Société d'Etudes pour la Propulsion par Réaction</span>

The Société d'Études pour la Propulsion par Réaction (SEPR) was a French research and manufacturing company founded in 1944 which specialised in the development of liquid-fuelled rocket engines during the 1950s, 60s, 70s and 80s.

<span class="mw-page-title-main">KDU-414</span> Type of rocket engine

The KDU-414, is a pressure-fed liquid rocket Propulsion Unit developed and produced by the Isayev Design Bureau. From 1960 onward, it powered several unmanned Soviet Spacecraft, including the first series of Molniya satellites, several Kosmos satellites as well as the space probes Mars 1, Venera 1, Zond 2 and Zond 3, featured as a part of standardized spacecraft buses known as KAUR-2, 2MV and 3MV.

References

  1. Nitric acid/Amine. Encycylopedia Astronautica
  2. "Analysis of North Korean missiles using Tonka fuel". Nuclear Threat Initiative. Archived from the original on 2006-09-07.
  3. Clark, John D. (1972). Ignition! An Informal History of Liquid Rocket Propellants. Rutgers University Press. p. 14. ISBN   0-8135-0725-1.
  4. Nodong missile analysis by FAS. data on R-13/SS-N-4 and R-21/SS-N-5 Isayev engine S5.38
  5. Soviet/Russian Cruise Missiles, Technical Report APA-TR-2009-0805
  6. Brügge, Norbert. "Spacecraft-propulsion blocks (KDU) from Isayev's design bureau (now Khimmash)". B14643.de. Archived from the original on 2015-06-02. Retrieved 2015-06-02.
  7. Debris from North Korea’s Launcher: What It Shows
  8. "S2.253".
  9. Rothmund, Christophe (2004). Reusable Man-rated Rocket Engines: The French Experience, 1944-1996 (PDF). 55th International Astronautical Congress. Vancouver, Canada. p. 2. IAC-04-IAA-6.15.3.02. Archived from the original (PDF) on 2015-10-24.