Urea phosphate

Last updated
Urea phosphate
Urea phosphate.svg
Names
IUPAC name
phosphoric acid;urea
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.023.149 OOjs UI icon edit-ltr-progressive.svg
EC Number
  • 225-464-3
PubChem CID
UNII
  • InChI=1S/CH4N2O.H3O4P/c2-1(3)4;1-5(2,3)4/h(H4,2,3,4);(H3,1,2,3,4)
    Key: DZHMRSPXDUUJER-UHFFFAOYSA-N
  • C(=O)(N)N.OP(=O)(O)O
Properties
CH7N2O5P
Molar mass 158.050 g·mol−1
Hazards
GHS labelling:
GHS-pictogram-acid.svg
Danger
H314
P260, P264, P280, P301+P330+P331, P303+P361+P353, P304+P340, P305+P351+P338, P310, P321, P363, P405, P501
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Urea phosphate is a 1:1 combination of urea and phosphoric acid that is used as a fertilizer. It has an NPK formula of 17-44-0, [1] and is soluble in water, producing a strongly acidic solution.

Urea phosphate is available in fertilizer vendor bags that carry a UP signet on the packaging. It is sometimes added to blends which contain calcium nitrate, magnesium nitrate and potassium nitrate to produce water-soluble formulas such as 15-5-15 and 13-2-20. The acidity of urea phosphate allows Ca, Mg and P to co-exist in solution. Under less acidic conditions, there would be precipitation of Ca–Mg phosphates. Urea phosphate is often used in drip irrigation to clean pipe systems. [2] [3]

The phosphoric acid and urea molecules in the urea phosphate crystal structure form a complex hydrogen-bonding network, [4] with the hydrogen atoms bonding more strongly to urea molecules. [5] It freely dissociates when dissolved in water.

Urea phosphate is produced as a non-ionic adduct of urea and phosphoric acid, [6] with the typical 17-44-0 grade of fertilizer produced using wet process phosphoric acid at concentrations that vary from 54% [1] to 90%: [7]

H3PO4(aq) + (NH2)2CO(s) → (NH2)2CO · H3PO4(s)

Related Research Articles

Urea, also called carbamide, is an organic compound with chemical formula CO(NH2)2. This amide has two amino groups joined by a carbonyl functional group. It is thus the simplest amide of carbamic acid.

<span class="mw-page-title-main">Fertilizer</span> Substance added to soils to supply plant nutrients for a better growth

A fertilizer or fertiliser is any material of natural or synthetic origin that is applied to soil or to plant tissues to supply plant nutrients. Fertilizers may be distinct from liming materials or other non-nutrient soil amendments. Many sources of fertilizer exist, both natural and industrially produced. For most modern agricultural practices, fertilization focuses on three main macro nutrients: nitrogen (N), phosphorus (P), and potassium (K) with occasional addition of supplements like rock flour for micronutrients. Farmers apply these fertilizers in a variety of ways: through dry or pelletized or liquid application processes, using large agricultural equipment or hand-tool methods.

<span class="mw-page-title-main">Urease</span> Multiprotein Nickel-containing complex which hydrolyses urea

Ureases, functionally, belong to the superfamily of amidohydrolases and phosphotriesterases. Ureases are found in numerous bacteria, fungi, algae, plants, and some invertebrates, as well as in soils, as a soil enzyme. They are nickel-containing metalloenzymes of high molecular weight.

<span class="mw-page-title-main">Phosphoric acid</span> Chemical compound (PO(OH)3)

Phosphoric acid is a colorless, odorless phosphorus-containing solid, and inorganic compound with the chemical formula H3PO4. It is commonly encountered as an 85% aqueous solution, which is a colourless, odourless, and non-volatile syrupy liquid. It is a major industrial chemical, being a component of many fertilizers.

The nitrophosphate process is a method for the industrial production of nitrogen fertilizers invented by Erling Johnson in the municipality of Odda, Norway around 1927.

<span class="mw-page-title-main">3,3'-Diaminobenzidine</span> Chemical compound

3,3′-Diaminobenzidine (DAB) is an organic compound with the formula (C6H3(NH2)2)2. This derivative of benzidine is a precursor to polybenzimidazole, which forms fibers that are renowned for their chemical and thermal stability. As its water-soluble tetrahydrochloride, DAB has been used in immunohistochemical staining of nucleic acids and proteins.

<span class="mw-page-title-main">Sulfamic acid</span> Chemical compound

Sulfamic acid, also known as amidosulfonic acid, amidosulfuric acid, aminosulfonic acid, sulphamic acid and sulfamidic acid, is a molecular compound with the formula H3NSO3. This colourless, water-soluble compound finds many applications. Sulfamic acid melts at 205 °C before decomposing at higher temperatures to water, sulfur trioxide, sulfur dioxide and nitrogen.

<span class="mw-page-title-main">Phosphoric acids and phosphates</span> Class of chemical species; phosphorus oxoacids and their deprotonated derivatives

In chemistry, a phosphoric acid, in the general sense, is a phosphorus oxoacid in which each phosphorus (P) atom is in the oxidation state +5, and is bonded to four oxygen (O) atoms, one of them through a double bond, arranged as the corners of a tetrahedron. Two or more of these PO4 tetrahedra may be connected by shared single-bonded oxygens, forming linear or branched chains, cycles, or more complex structures. The single-bonded oxygen atoms that are not shared are completed with acidic hydrogen atoms. The general formula of a phosphoric acid is Hn+2−2xPnO3n+1−x, where n is the number of phosphorus atoms and x is the number of fundamental cycles in the molecule's structure, between 0 and n + 2/2.

<span class="mw-page-title-main">Ammonium phosphate</span> Chemical compound

Ammonium phosphate is the inorganic compound with the formula (NH4)3PO4. It is the ammonium salt of orthophosphoric acid. A related "double salt", (NH4)3PO4.(NH4)2HPO4 is also recognized but is impractical to use. Both triammonium salts evolve ammonia. In contrast to the unstable nature of the triammonium salts, the diammonium phosphate (NH4)2HPO4 and monoammonium salt (NH4)H2PO4 are stable materials that are commonly used as fertilizers to provide plants with fixed nitrogen and phosphorus.

<span class="mw-page-title-main">Phosphorus pentoxide</span> Chemical compound

Phosphorus pentoxide is a chemical compound with molecular formula P4O10 (with its common name derived from its empirical formula, P2O5). This white crystalline solid is the anhydride of phosphoric acid. It is a powerful desiccant and dehydrating agent.

<span class="mw-page-title-main">Arsenic acid</span> Chemical compound

Arsenic acid or arsoric acid is the chemical compound with the formula H3AsO4. More descriptively written as AsO(OH)3, this colorless acid is the arsenic analogue of phosphoric acid. Arsenate and phosphate salts behave very similarly. Arsenic acid as such has not been isolated, but is only found in solution, where it is largely ionized. Its hemihydrate form (2H3AsO4·H2O) does form stable crystals. Crystalline samples dehydrate with condensation at 100 °C.

<span class="mw-page-title-main">Biuret</span> Chemical compound

Biuret is a chemical compound with the chemical formula HN(CONH2)2. It is a white solid that is soluble in hot water. A variety of organic derivatives are known. The term "biuret" also describes a family of organic compounds with the chemical formula R1R2N−C(=O)−N(R3)−C(=O)−NR4R5, where R1, R2, R3, R4 and R5 are hydrogen, organyl or other groups. Also known as carbamylurea, it results from the condensation of two equivalents of urea. It is a common undesirable impurity in urea-based fertilizers, as biuret is toxic to plants.

<span class="mw-page-title-main">Dipotassium phosphate</span> Chemical compound

Dipotassium phosphate (K2HPO4) (also dipotassium hydrogen orthophosphate; potassium phosphate dibasic) is the inorganic compound with the formula K2HPO4.(H2O)x (x = 0, 3, 6). Together with monopotassium phosphate (KH2PO4.(H2O)x), it is often used as a fertilizer, food additive, and buffering agent. It is a white or colorless solid that is soluble in water.

<span class="mw-page-title-main">Fertigation</span> Adding fertilizers to an irrigation system

Fertigation is the injection of fertilizers, used for soil amendments, water amendments and other water-soluble products into an irrigation system.

<span class="mw-page-title-main">Urea nitrate</span> Chemical compound

Urea nitrate is a fertilizer-based high explosive that has been used in improvised explosive devices in Afghanistan, Pakistan, Iraq, and various terrorist acts elsewhere in the world such as in the 1993 World Trade Center bombings. It has a destructive power similar to better-known ammonium nitrate explosives, with a velocity of detonation between 3,400 m/s (11,155 ft/s) and 4,700 m/s (15,420 ft/s). It has chemical formula of CH5N3O4 or (NH2)2COHNO3.

<span class="mw-page-title-main">Copper(II) phosphate</span> Chemical compound

Copper(II) phosphate are inorganic compounds with the formula Cu3(PO4)2. They can be regarded as the cupric salts of phosphoric acid. Anhydrous copper(II) phosphate and a trihydrate are blue solids.

<span class="mw-page-title-main">Ammonium carbamate</span> Chemical compound

Ammonium carbamate is a chemical compound with the formula [NH4][H2NCO2] consisting of ammonium cation NH+4 and carbamate anion NH2COO. It is a white solid that is extremely soluble in water, less so in alcohol. Ammonium carbamate can be formed by the reaction of ammonia NH3 with carbon dioxide CO2, and will slowly decompose to those gases at ordinary temperatures and pressures. It is an intermediate in the industrial synthesis of urea (NH2)2CO, an important fertilizer.

<span class="mw-page-title-main">Triuret</span> Chemical compound

Triuret is an organic compound with the formula (H2NC(O)NH)2CO. It is a product from the pyrolysis of urea. Triuret is a colorless, crystalline, hygroscopic solid, slightly soluble in cold water or ether, and more soluble in hot water. It is a planar molecule. The central carbonyl is hydrogen-bonded to both terminal amino groups.

<span class="mw-page-title-main">Thorium(IV) nitrate</span> Chemical compound

Thorium(IV) nitrate is a chemical compound, a salt of thorium and nitric acid with the formula Th(NO3)4. A white solid in its anhydrous form, it can form tetra- and pentahydrates. As a salt of thorium it is weakly radioactive.

Protactinium compounds are compounds containing the element protactinium. These compounds usually have protactinium in the +5 oxidation state, although these compounds can also exist in the +2, +3 and +4 oxidation states.

References

  1. 1 2 Stinson, John M. (1977). Purified Liquid Fertilizers from Wet-process Acid Via Solid Urea Phosphate. National Fertilizer Development Center, Tennessee Valley Authority. p. 3.
  2. Ramachandrula, Venkata Ramamohan; Kasa, Ramamohan Reddy (2022-10-01). "Prevention and treatment of drip emitter clogging: a review of various innovative methods". Water Practice and Technology. 17 (10): 2059–2070. doi:10.2166/wpt.2022.115. ISSN   1751-231X.
  3. Stroehlein, J. L.; Rubeiz, I. G.; Oebker, N. F. (April 1986). "Urea Phosphate Applied by Subsurface Drip Irrigation Increases Availability of Soil Nitrogen and Phosphorus". Vegetable Report. hdl: 10150/214135 .
  4. Sundera-Rao, R. V. G.; Turley, J. W.; Pepinsky, R. (1957). "The crystal structure of urea phosphate". Acta Crystallogr. 10 (6): 435–436. Bibcode:1957AcCry..10..435S. doi: 10.1107/S0365110X57001425 .
  5. Rodrigues, Bernardo Lages; Tellgren, Roland; Fernandes, Nelson G. (2001-06-01). "Experimental electron density of urea–phosphoric acid (1/1) at 100 K". Acta Crystallographica Section B Structural Science. 57 (3): 353–358. doi:10.1107/S0108768101004359. ISSN   0108-7681.
  6. Lagier, Claudia M.; Zuriaga, Mariano; Monti, Gustavo; Olivieri, Alejandro C. (September 1996). "Urea-phosphoric acid complex studied by variable temperature 31P NMR spectroscopy and semiempirical calculations". Journal of Physics and Chemistry of Solids. 57 (9): 1183–1190. Bibcode:1996JPCS...57.1183L. doi:10.1016/0022-3697(95)00294-4.
  7. Jančaitienė, Kristina; Medekšaitė, Agnė; Šlinkšienė, Rasa (2023-11-14). "Influence of the Process Parameters on the Synthesis of Urea Phosphate and the Properties of the Obtained Product". Crystals. 13 (11): 1584. doi: 10.3390/cryst13111584 . ISSN   2073-4352.