Mineral spring

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The Mineral Spring, etching by Wenceslas Hollar (1607-1677). The unidentified central European spring features a sunken stone basin and ornamental retaining wall. Wenceslas Hollar - The mineral spring (State 4).jpg
The Mineral Spring, etching by Wenceslas Hollar (1607–1677). The unidentified central European spring features a sunken stone basin and ornamental retaining wall.
Tourists and pilgrims having a bath in a hot spring in Gurudwara Complex, Manikaran in Uttrakhand state of India, c. May 2009. Hot springs at Manikaran,Himachal Pradesh.jpg
Tourists and pilgrims having a bath in a hot spring in Gurudwara Complex, Manikaran in Uttrakhand state of India, c. May 2009.
A chalybeate (iron-laden) mineral spring at Breznik, Bulgaria Breznik-iron-water-spring.jpg
A chalybeate (iron-laden) mineral spring at Breznik, Bulgaria
Tap tapan spring in Azarshahr, Iran Tap Tapan Mineral Spring.jpg
Tap tapan spring in Azarshahr, Iran

Mineral springs are naturally occurring springs that produce hard water, water that contains dissolved minerals. Salts, sulfur compounds, and gases are among the substances that can be dissolved in the spring water during its passage underground. In this they are unlike sweet springs, which produce soft water with no noticeable dissolved gasses. The dissolved minerals may alter the water's taste. Mineral water obtained from mineral springs, and the precipitated salts such as Epsom salt have long been important commercial products.

Contents

Some mineral springs may contain significant amounts of harmful dissolved minerals, such as arsenic, and should not be drunk. [1] [2] Sulfur springs smell of rotten eggs due to hydrogen sulfide (H2S), which is hazardous and sometimes deadly. It is a gas, and it usually enters the body when it is breathed in. [3] The quantities ingested in drinking water are much lower and are not considered likely to cause harm, but few studies on long-term, low-level exposure have been done, as of 2003. [4]

The water of mineral springs is sometimes claimed to have therapeutic value. Mineral spas are resorts that have developed around mineral springs, where (often wealthy) patrons would repair to "take the waters" — meaning that they would drink (see hydrotherapy and water cure) or bathe in (see balneotherapy) the mineral water. Historical mineral springs were often outfitted with elaborate stone-works — including artificial pools, retaining walls, colonnades, and roofs — sometimes in the form of fanciful "Greek temples", gazebos, or pagodas. Others were entirely enclosed within spring houses.

Types

For many centuries, in Europe, North America, and elsewhere, commercial proponents of mineral springs classified them according to the chemical composition of the water produced and according to the medicinal benefits supposedly accruing from each:

Deposits

Stepped travertine terrace formations at Badab-e Surt, Iran Badab Surt Najafi2.jpg
Stepped travertine terrace formations at Badab-e Surt, Iran

Types of sedimentary rock – usually limestone (calcium carbonate) – are sometimes formed by the evaporation, or rapid precipitation, of minerals from spring water as it emerges, especially at the mouths of hot mineral springs. In cold mineral springs, the rapid precipitation of minerals results from the reduction of acidity when the CO2 gas bubbles out. (These mineral deposits can also be found in dried lakebeds.) Spectacular formations, including terraces, stalactites, stalagmites and 'frozen waterfalls' can result (see, for example, Mammoth Hot Springs).

One light-colored porous calcite of this type is known as travertine and has been used extensively in Italy and elsewhere as building material. Travertine can have a white, tan, or cream-colored appearance and often has a fibrous or concentric 'grain'.

Another type of spring water deposit, containing siliceous as well as calcareous minerals, is known as tufa. Tufa is similar to travertine but is even softer and more porous.

Chaybeate springs may deposit iron compounds such as limonite. Some such deposits were large enough to be mined as iron ore.

See also

Related Research Articles

<span class="mw-page-title-main">Sulfur</span> Chemical element, symbol S and atomic number 16

Sulfur (also spelled sulphur in British English) is a chemical element; it has symbol S and atomic number 16. It is abundant, multivalent and nonmetallic. Under normal conditions, sulfur atoms form cyclic octatomic molecules with the chemical formula S8. Elemental sulfur is a bright yellow, crystalline solid at room temperature.

<span class="mw-page-title-main">Hydrogen sulfide</span> Poisonous, corrosive and flammable gas

Hydrogen sulfide is a chemical compound with the formula H2S. It is a colorless chalcogen-hydride gas, and is poisonous, corrosive, and flammable, with trace amounts in ambient atmosphere having a characteristic foul odor of rotten eggs. Swedish chemist Carl Wilhelm Scheele is credited with having discovered the chemical composition of purified hydrogen sulfide in 1777.

<span class="mw-page-title-main">Sodium carbonate</span> Chemical compound

Sodium carbonate is the inorganic compound with the formula Na2CO3 and its various hydrates. All forms are white, odourless, water-soluble salts that yield alkaline solutions in water. Historically, it was extracted from the ashes of plants grown in sodium-rich soils, and because the ashes of these sodium-rich plants were noticeably different from ashes of wood, sodium carbonate became known as "soda ash". It is produced in large quantities from sodium chloride and limestone by the Solvay process, as well as by carbonating sodium hydroxide which is made using the Chlor-alkali process.

<span class="mw-page-title-main">Carbonated water</span> Water containing dissolved carbon dioxide gas

Carbonated water is water containing dissolved carbon dioxide gas, either artificially injected under pressure or occurring due to natural geological processes. Carbonation causes small bubbles to form, giving the water an effervescent quality. Common forms include sparkling natural mineral water, club soda, and commercially produced sparkling water.

<span class="mw-page-title-main">Travertine</span> Form of limestone deposited by mineral springs

Travertine is a form of terrestrial limestone deposited around mineral springs, especially hot springs. It often has a fibrous or concentric appearance and exists in white, tan, cream-colored, and rusty varieties. It is formed by a process of rapid precipitation of calcium carbonate, often at the mouth of a hot spring or in a limestone cave. In the latter, it can form stalactites, stalagmites, and other speleothems. It is frequently used in Italy and elsewhere as a building material. Similar deposits formed from ambient-temperature water are known as tufa.

Sulfide (British English also sulphide) is an inorganic anion of sulfur with the chemical formula S2− or a compound containing one or more S2− ions. Solutions of sulfide salts are corrosive. Sulfide also refers to large families of inorganic and organic compounds, e.g. lead sulfide and dimethyl sulfide. Hydrogen sulfide (H2S) and bisulfide (SH) are the conjugate acids of sulfide.

<span class="mw-page-title-main">Spring (hydrology)</span> Point at which water emerges from an aquifer to the surface

A spring is a natural exit point at which groundwater emerges out of the aquifer and flows onto the top of the Earth's crust (pedosphere) to become surface water. It is a component of the hydrosphere, as well as a part of the water cycle. Springs have long been important for humans as a source of fresh water, especially in arid regions which have relatively little annual rainfall.

<span class="mw-page-title-main">Mineral water</span> Drinking water from a mineral spring

Mineral water is water from a mineral spring that contains various minerals, such as salts and sulfur compounds. It is usually still, but may be sparkling (carbonated/effervescent).

<span class="mw-page-title-main">Tufa</span> Porous limestone rock formed when carbonate minerals precipitate out of ambient temperature water

Tufa is a variety of limestone formed when carbonate minerals precipitate out of water in unheated rivers or lakes. Geothermally heated hot springs sometimes produce similar carbonate deposits, which are known as travertine. Tufa is sometimes referred to as (meteogene) travertine. It should not be confused with hot spring (thermogene) travertine. Tufa, which is calcareous, should also not be confused with tuff, a porous volcanic rock with a similar etymology that is sometimes also called "tufa".

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<span class="mw-page-title-main">Limescale</span> Hard, chalky deposit of calcium carbonate

Limescale is a hard, chalky deposit, consisting mainly of calcium carbonate (CaCO3). It often builds up inside kettles, boilers, and pipework, especially that for hot water. It is also often found as a similar deposit on the inner surfaces of old pipes and other surfaces where hard water has flowed. Limescale also forms as travertine or tufa in hard water springs.

<span class="mw-page-title-main">Efflorescence</span> Migration of a salt to the surface of a porous material

In chemistry, efflorescence is the migration of a salt to the surface of a porous material, where it forms a coating. The essential process involves the dissolving of an internally held salt in water, or occasionally in another solvent. The water, with the salt now held in solution, migrates to the surface, then evaporates, leaving a coating of the salt.

<span class="mw-page-title-main">Calcium sulfide</span> Chemical compound of formula CaS

Calcium sulfide is the chemical compound with the formula CaS. This white material crystallizes in cubes like rock salt. CaS has been studied as a component in a process that would recycle gypsum, a product of flue-gas desulfurization. Like many salts containing sulfide ions, CaS typically has an odour of H2S, which results from small amount of this gas formed by hydrolysis of the salt.

<span class="mw-page-title-main">Kipp's apparatus</span> Laboratory device for preparing gases

Kipp's apparatus, also called a Kipp generator, is an apparatus designed for preparation of small volumes of gases. It was invented around 1844 by the Dutch pharmacist Petrus Jacobus Kipp and widely used in chemical laboratories and for demonstrations in schools into the second half of the 20th century.

<span class="mw-page-title-main">Sulfur water</span> Water exposed to hydrogen sulfide gas

Sulfur water is a condition where water is exposed to hydrogen sulfide gas, giving a distinct "rotten egg" smell. This condition has different purposes in culture varying to health and implications to plumbing.

In ore deposit geology, supergene processes or enrichment are those that occur relatively near the surface as opposed to deep hypogene processes. Supergene processes include the predominance of meteoric water circulation (i.e. water derived from precipitation) with concomitant oxidation and chemical weathering. The descending meteoric waters oxidize the primary (hypogene) sulfide ore minerals and redistribute the metallic ore elements. Supergene enrichment occurs at the base of the oxidized portion of an ore deposit. Metals that have been leached from the oxidized ore are carried downward by percolating groundwater, and react with hypogene sulfides at the supergene-hypogene boundary. The reaction produces secondary sulfides with metal contents higher than those of the primary ore. This is particularly noted in copper ore deposits where the copper sulfide minerals chalcocite (Cu2S), covellite (CuS), digenite (Cu18S10), and djurleite (Cu31S16) are deposited by the descending surface waters.

Stone sealing is the application of a surface treatment to products constructed of natural stone to retard staining and corrosion. All bulk natural stone is riddled with interconnected capillary channels that permit penetration by liquids and gases. This is true for igneous rock types such as granite and basalt, metamorphic rocks such as marble and slate, and sedimentary rocks such as limestone, travertine, and sandstone. These porous channels act like a sponge, and capillary action draws in liquids over time, along with any dissolved salts and other solutes. Very porous stone, such as sandstone absorb liquids relatively quickly, while denser igneous stones such as granite are significantly less porous; they absorb smaller volumes, and more slowly, especially when absorbing viscous liquids.

<span class="mw-page-title-main">Cleaning agent</span> Substance used to remove dirt or other contaminants

Cleaning agents or hard-surface cleaners are substances used to remove dirt, including dust, stains, foul odors, and clutter on surfaces. Purposes of cleaning agents include health, beauty, removing offensive odor, and avoiding the spread of dirt and contaminants to oneself and others. Some cleaning agents can kill bacteria and clean at the same time. Others, called degreasers, contain organic solvents to help dissolve oils and fats.

<span class="mw-page-title-main">La Saline Natural Area</span> Nature preserve in Canada

La Saline Natural Area in the boreal forest of northeastern Alberta, Canada, preserves Saline Lake, a saline oxbow lake adjacent to the Athabasca River north of Fort McMurray. The lake is an important stop for waterfowl and other birds that migrate along the Athabasca River. Large deposits of tufa have accumulated around the salt springs on the lake's southeastern shore.

References

  1. "Import Alert 29-02: Detention Without Physical Examination of Bottled Water due to Arsenic Due to Inorganic Arsenic". www.accessdata.fda.gov. FDA.
  2. "Bottled water brand with high levels of arsenic pulled from store shelves". NBC News.
  3. "PUBLIC HEALTH STATEMENT: Hydrogen Sulfide" (PDF). DEPARTMENT of HEALTH AND HUMAN SERVICES, Public Health ServiceAgency for Toxic Substances and Disease Registry, US Centers for Disease Control. December 2016.
  4. "Hydrogen Sulfide in Drinking-water" (PDF). World Health Organization. 2003.