Isotopes of sulfur

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Isotopes of sulfur  (16S)
Main isotopes Decay
abun­dance half-life (t1/2) mode pro­duct
32S94.8% stable
33S0.760%stable
34S4.37%stable
35S trace 87.37 d β 35Cl
36S0.02%stable
34S abundances vary greatly (between 3.96 and 4.77 percent) in natural samples.
Standard atomic weight Ar°(S)
  • [32.059, 32.076]
  • 32.06±0.02 (abridged) [1] [2]

Sulfur (16S) has 23 known isotopes with mass numbers ranging from 27 to 49, four of which are stable: 32S (95.02%), 33S (0.75%), 34S (4.21%), and 36S (0.02%). The preponderance of sulfur-32 is explained by its production from carbon-12 plus successive fusion capture of five helium-4 nuclei, in the so-called alpha process of exploding type II supernovas (see silicon burning).

Contents

Other than 35S, the radioactive isotopes of sulfur are all comparatively short-lived. 35S is formed from cosmic ray spallation of 40 Ar in the atmosphere. It has a half-life of 87 days. The next longest-lived radioisotope is sulfur-38, with a half-life of 170 minutes. The shortest-lived is 49S, with a half-life shorter than 200 nanoseconds. Heavier radioactive isotopes of sulfur decay to chlorine.

When sulfide minerals are precipitated, isotopic equilibration among solids and liquid may cause small differences in the δ34S values of co-genetic minerals. The differences between minerals can be used to estimate the temperature of equilibration. The δ13C and δ34S of coexisting carbonates and sulfides can be used to determine the pH and oxygen fugacity of the ore-bearing fluid during ore formation.

In most forest ecosystems, sulfate is derived mostly from the atmosphere; weathering of ore minerals and evaporites also contribute some sulfur. Sulfur with a distinctive isotopic composition has been used to identify pollution sources, and enriched sulfur has been added as a tracer in hydrologic studies. Differences in the natural abundances can also be used in systems where there is sufficient variation in the 34S of ecosystem components. Rocky Mountain lakes thought to be dominated by atmospheric sources of sulfate have been found to have different δ34S values from oceans believed to be dominated by watershed sources of sulfate.

List of isotopes

Nuclide [3]
[n 1]
Z N Isotopic mass (Da) [4]
[n 2] [n 3]
Half-life
Decay
mode

[n 4]
Daughter
isotope

[n 5]
Spin and
parity
[n 6] [n 7]
Natural abundance (mole fraction)
Excitation energyNormal proportionRange of variation
27S [n 8] 161127.01828(43)#15.5(15) ms β+ (96.6%)27P(5/2+)
β+, p (2.3%)26Si
β+, 2p (1.1%)25Al
28S161228.00437(17)125(10) msβ+ (79.3%)28P0+
β+, p (20.7%)27Si
29S161328.99661(5)188(4) msβ+ (53.6%)29P5/2+#
β+, p (46.4%)28Si
30S161429.98490677(22)1.1759(17) sβ+30P0+
31S161530.97955701(25)2.5534(18) sβ+31P1/2+
32S [n 9] 161631.9720711744(14)Stable0+0.9499(26)0.94454-0.95281
33S161732.9714589099(15)Stable3/2+0.0075(2)0.00730-0.00793
34S161833.96786701(5)Stable0+0.0425(24)0.03976-0.04734
35S161934.96903232(4)87.37(4) dβ35Cl3/2+Trace [n 10]
36S162035.96708070(20)Stable0+0.0001(1)0.00013−0.00027
37S162136.97112551(21)5.05(2) minβ37Cl7/2−
38S162237.971163(8)170.3(7) minβ38Cl0+
39S162338.97513(5)11.5(5) sβ39Cl(7/2)−
40S162439.975483(4)8.8(22) sβ40Cl0+
41S162540.979593(4)1.99(5) sβ (>99.9%)41Cl7/2−#
β, n (<.1%)40Cl
42S162641.981065(3)1.016(15) sβ (>96%)42Cl0+
β, n (<4%)41Cl
43S162742.986908(5)265(13) msβ (60%)43Cl3/2−#
β, n (40%)42Cl
43mS319(5) keV415.0(26) ns IT 43S(7/2−)
44S162843.990119(6)100(1) msβ (81.7%)44Cl0+
β, n (18.2%)43Cl
44mS1365.0(8) keV2.619(26) µsIT44S0+
45S162944.99572(111)68(2) msβ, n (54%)44Cl3/2−#
β (46%)45Cl
46S163046.00037(54)#50(8) msβ46Cl0+
47S163147.00791(54)#20# ms
[>200 ns]
β47Cl3/2−#
48S163248.01370(64)#10# ms
[>200 ns]
β48Cl0+
49S [5] 163349.02264(72)#β49Cl3/2−#
This table header & footer:
  1. mS  Excited nuclear isomer.
  2. ()  Uncertainty (1σ) is given in concise form in parentheses after the corresponding last digits.
  3. #  Atomic mass marked #: value and uncertainty derived not from purely experimental data, but at least partly from trends from the Mass Surface (TMS).
  4. Modes of decay:
    IT: Isomeric transition
    n: Neutron emission
    p: Proton emission
  5. Bold symbol as daughter  Daughter product is stable.
  6. () spin value  Indicates spin with weak assignment arguments.
  7. #  Values marked # are not purely derived from experimental data, but at least partly from trends of neighboring nuclides (TNN).
  8. Has 2 halo protons
  9. Heaviest theoretically stable nuclide with equal numbers of protons and neutrons
  10. Cosmogenic

• The beams of several radioactive isotopes (such as those of 44S) have been studied theoretically within the framework of the synthesis of superheavy elements, especially those ones in the vicinity of island of stability. [6] [7]

See also

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References

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