(Benzene)ruthenium dichloride dimer

(benzene)ruthenium dichloride dimer

Names
Other names Dichloro(benzene)ruthenium(II) dimer, bis(η6-benzene)di-μ-chlorodichlorodiruthenium, (benzene)dichlororuthenium dimer, benzeneruthenium dichloride dimer, benzeneruthenium(II) chloride dimer
Identifiers
CAS Number	37366-09-9  Y
3D model (JSmol)	Interactive image
ChemSpider	9137359
ECHA InfoCard	100.155.159
EC Number	626-792-3
PubChem CID	10962144
CompTox Dashboard (EPA)	DTXSID40449898
InChI InChI=1S/2C6H6.4ClH.2Ru/c2*1-2-4-6-5-3-1;;;;;;/h2*1-6H;4*1H;;/q;;;;;;2*+2/p-4 Key: YGXMUPKIEHNBNQ-UHFFFAOYSA-J
SMILES C1=CC=CC=C1.C1=CC=CC=C1.Cl[Ru]Cl.Cl[Ru]Cl
Properties
Chemical formula	C12H12Cl4Ru2
Molar mass	500.17 g·mol−1
Appearance	Red-brown solid
Density	2.343 g/cm3
Melting point	decomposes
Solubility in water	Slightly, with hydrolysis
Hazards
GHS labelling:
Pictograms
Signal word	Warning
Hazard statements	H315, H319, H335
Precautionary statements	P261, P264, P271, P280, P302+P352, P304+P340, P305+P351+P338, P312, P321, P332+P313, P337+P313, P362, P403+P233, P405, P501
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). Y  verify  (what is  YN ?) Infobox references

(Benzene)ruthenium dichloride dimer is the organoruthenium compound with the formula [(C₆H₆)RuCl₂]₂. This red-coloured, diamagnetic solid is a reagent in organometallic chemistry and homogeneous catalysis.

Preparation, structure, and reactions

The dimer is prepared by the reaction of cyclohexadienes with hydrated ruthenium trichloride. ^[1] As verified by X-ray crystallography, each Ru center is coordinated to three chloride ligands and a η ⁶-benzene. ^[2] The complex can be viewed as an edge-shared bioctahedral structure.

(Benzene)ruthenium dichloride dimer reacts with Lewis bases to give monometallic adducts:

[(C₆H₆)RuCl₂]₂ + 2 PPh₃ → 2 (C₆H₆)RuCl₂(PPh₃)

Related compounds

• (cymene)ruthenium dichloride dimer, a more soluble analogue of (benzene)ruthenium dichloride dimer.
• (mesitylene)ruthenium dichloride dimer, another more soluble derivative. ^[3]

References

1. Bennett, M. A.; Huang, T. N.; Matheson, T. W.; Smith, A. K. (1982). "16. (η ⁶ -Hexamethylbenzene)Ruthenium Complexes". (η⁶-Hexamethylbenzene)ruthenium Complexes. Inorganic Syntheses. Vol. 21. pp. 74–78. doi:10.1002/9780470132524.ch16. ISBN   9780471865209.
2. J. Canivet; B. Therrien; G. Suss-Fink (2005). "Di-μ-chlorobis[(η⁶-benzene) chlororuthenium(II)] Chloroform Disolvate". Acta Crystallographica Section E. 61 (6): m1090. doi:10.1107/S1600536805014157. S2CID   62686720.
3. Carole, William A.; Colacot, Thomas J. (2011). "Dichloro(mesitylene)ruthenium Dimer". Encyclopedia of Reagents for Organic Synthesis. doi:10.1002/047084289X.rn01290. ISBN   978-0471936237.