Names | |
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IUPAC name Tricyclohexyltin hydroxide | |
Other names | |
Identifiers | |
6099492 | |
ChEBI | |
ChemSpider | |
ECHA InfoCard | 100.032.757 |
EC Number |
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31094 | |
KEGG | |
PubChem CID |
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RTECS number |
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UNII | |
UN number | 2811 |
CompTox Dashboard (EPA) | |
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Properties | |
(C6H11)3SnOH | |
Molar mass | 385.179 g·mol−1 |
Appearance | Colorless crystals or white crystalline powder [1] |
Odor | Nearly odorless [1] |
Melting point | 196 °C (385 °F; 469 K) Decomposes above 121 to 131 °C (250 to 268 °F; 394 to 404 K) [1] |
Boiling point | 228 °C (442 °F; 501 K) (decomposes) [1] |
Almost insoluble (less than 1 mg/L) [1] | |
Solubility |
|
Solubility in Chloroform | 216 g/kg [1] |
Solubility in Methanol | 37 g/kg [1] |
Solubility in Toluene | 10 g/kg [1] |
Solubility in Benzene | 16 g/kg [1] |
Vapor pressure | Negligible [1] |
Hazards | |
Occupational safety and health (OHS/OSH): | |
Main hazards | Kidneys and liver damage. [1] High exposure damages the nervous system. [2] |
Ingestion hazards | Abdominal pain, diarrhea, nausea, vomiting [1] |
Inhalation hazards | Respiratory system and throat irritation [1] [2] |
Eye hazards | Irritation and burns |
Skin hazards | Irritation and burns, can be absorbed into the body through the skin |
GHS labelling: [3] | |
Warning | |
H302, H312, H332, H410 | |
P261, P264, P270, P271, P273, P280, P301+P317, P302+P352, P304+P340, P317, P321, P330, P362+P364, P391, P501 | |
Lethal dose or concentration (LD, LC): | |
LD50 (median dose) |
|
LC50 (median concentration) | 244 mg/m3 (inhalation, rat), 290 mg/m3 (inhalation, mouse) |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). |
Cyhexatin, also known as tricyclohexyltin hydroxide is an organometallic compound of tin with the chemical formula (C6H11)3SnOH.
Cyhexatin forms colorless crystals or white crystalline powder. It is practically insoluble in water. The powder is wettable by water. [1]
Cyhexatin is stable in aqueous suspensions in neutral and alkaline conditions (pH above 6), but reacts exothermically with strong acids, acting as a base, to form salts.[ which? ] Reacts with strong oxidizers. Decomposes upon exposure to ultraviolet light to dicyclohexyltin oxide (C6H11)2SnO (which is not an analog of ketones R2C=O because it exists as a polymer) and cyclohexylstannanoic acid (C6H11)SnO2H. Contact with metals may emit flammable hydrogen gas. Upon heating above 120 °C (248 °F) it decomposes to bis(tricyclohexyltin) oxide ((C6H11)3Sn)2O, emitting irritating and toxic fumes and acrid smoke. [1]
Cyhexatin is used in paints. [2]
In agriculture, cyhexatin is used as a pesticide against insects, as well as parasitic mites that attack plants, like vegetables (e.g. cucurbits), fruit trees (e.g. pome fruits, stone fruits), hops, walnut, strawberry, vines and ornamentals. [1] The chemical is not used in the United States. [4]
Cyhexatin is not combustible, but decomposes upon heating to produce corrosive and toxic fumes. Some components of those fumes are oxidizers, thus, they can cause combustible materials to ignite, like wood, oil, some plastics, paper and clothes. Containers of cyhexatin may explode when heated. Cyhexatin is very toxic to aquatic life. [1]
Cyhexatin is not classified as a human carcinogen, but is classified as a teratogen. It is toxic by contact with skin, inhalation and ingestion. The compound and its fumes irritate and burn eyes. Contact with skin causes pruritus and burns. Cyhexatin can be absorbed into the body through the skin, and skin should be washed immediately upon contact with this chemical. Inhalation of its fumes causes irritation of the respiratory system, coughing, headache, dizziness and sore throat. It can cause abdominal pain, diarrhea, nausea and vomiting. [1] It causes damage to kidneys and liver, as well as nervous system. [2] Cyhexatin is a central nervous system depressant. [1]
Aqua regia is a mixture of nitric acid and hydrochloric acid, optimally in a molar ratio of 1:3. Aqua regia is a fuming liquid. Freshly prepared aqua regia is colorless, but it turns yellow, orange or red within seconds from the formation of nitrosyl chloride and nitrogen dioxide. It was so named by alchemists because it can dissolve noble metals like gold and platinum, though not all metals.
Mercury(II) oxide, also called mercuric oxide or simply mercury oxide, is the inorganic compound with the formula HgO. It has a red or orange color. Mercury(II) oxide is a solid at room temperature and pressure. The mineral form montroydite is very rarely found.
Lead(II,IV) oxide, also called red lead or minium, is the inorganic compound with the formula Pb3O4. A bright red or orange solid, it is used as pigment,the manufacture of batteries, and rustproof primer paints. It is an example of a mixed valence compound, being composed of both Pb(II) and Pb(IV) in the ratio of two to one.
Cyanogen iodide or iodine cyanide (ICN) is a pseudohalogen composed of iodine and the cyanide group. It is a highly toxic inorganic compound. It occurs as white crystals that react slowly with water to form hydrogen cyanide.
Calcium sulfide is the chemical compound with the formula CaS. This white material crystallizes in cubes like rock salt. CaS has been studied as a component in a process that would recycle gypsum, a product of flue-gas desulfurization. Like many salts containing sulfide ions, CaS typically has an odour of H2S, which results from small amount of this gas formed by hydrolysis of the salt.
Potassium nitrite (distinct from potassium nitrate) is the inorganic compound with the chemical formula KNO2. It is an ionic salt of potassium ions K+ and nitrite ions NO2−, which forms a white or slightly yellow, hygroscopic crystalline powder that is soluble in water.
Lead(IV) oxide, commonly known as lead dioxide, is an inorganic compound with the chemical formula PbO2. It is an oxide where lead is in an oxidation state of +4. It is a dark-brown solid which is insoluble in water. It exists in two crystalline forms. It has several important applications in electrochemistry, in particular as the positive plate of lead acid batteries.
Aluminium arsenide is a semiconductor material with almost the same lattice constant as gallium arsenide and aluminium gallium arsenide and wider band gap than gallium arsenide. (AlAs) can form a superlattice with gallium arsenide (GaAs) which results in its semiconductor properties. Because GaAs and AlAs have almost the same lattice constant, the layers have very little induced strain, which allows them to be grown almost arbitrarily thick. This allows for extremely high performance high electron mobility, HEMT transistors, and other quantum well devices.
Zinc peroxide (ZnO2) appears as a bright yellow powder at room temperature. It was historically used as a surgical antiseptic. More recently zinc peroxide has also been used as an oxidant in explosives and pyrotechnic mixtures. Its properties have been described as a transition between ionic and covalent peroxides. Zinc peroxide can be synthesized through the reaction of zinc chloride and hydrogen peroxide.
Tetrafluorohydrazine or perfluorohydrazine, N2F4, is a colourless, nonflammable, reactive inorganic gas. It is a fluorinated analog of hydrazine.
Potassium nitrate is an oxidizer so storing it near fire hazards or reducing agents should be avoided to minimise risk in case of a fire.
Bleach is the generic name for any chemical product that is used industrially or domestically to remove colour (whitening) from fabric or fiber or to disinfect after cleaning. It often refers specifically to a dilute solution of sodium hypochlorite, also called "liquid bleach".
Dimethylzinc, also known as zinc methyl, DMZ, or DMZn, is a toxic organozinc compound with the chemical formula Zn(CH3)2. It belongs to the large series of similar compounds such as diethylzinc.
Malaoxon (Liromat, Malation oxon, Malthon oxon) is a chemical compound with the formula C10H19O7PS. More specifically, it is a phosphorothioate. It is a breakdown product of, and more toxic than, malathion.
Lithium tetrachloroaluminate is an inorganic compound with the formula Li[AlCl4]. It consists of lithium cations Li+ and tetrahedral tetrachloroaluminate anions [AlCl4]−.
Sodium ethyl xanthate (SEX) is an organosulfur compound with the chemical formula CH3CH2OCS2Na. It is a pale yellow powder, which is usually obtained as the dihydrate. Sodium ethyl xanthate is used in the mining industry as a flotation agent. A closely related potassium ethyl xanthate (KEX) is obtained as the anhydrous salt.
Carbophenothion also known as Stauffer R 1303 as for the manufacturer, Stauffer Chemical, is an organophosphorus chemical compound. It was used as a pesticide for citrus fruits under the name of Trithion. Carbophenothion was used as an insecticide and acaricide. Although not used anymore it is still a restricted use pesticide in the United States. The chemical is identified in the US as an extremely hazardous substance according to the Emergency Planning and Community Right-to-Know Act.
Compounds of lead exist with lead in two main oxidation states: +2 and +4. The former is more common. Inorganic lead(IV) compounds are typically strong oxidants or exist only in highly acidic solutions.
Trifluoroacetyl chloride (also known as TFAC) is a toxic gaseous chemical compound with the chemical formula C2ClF3O. TFAC is the perfluorinated version of acetyl chloride. The compound is a gas, but it is usually shipped as a liquid under high pressure.
Dibutyltin dilaurate is an organotin compound with the formula (CH310CO2)2Sn(CH2CH2CH2CH3)2. It is a colorless viscous and oily liquid. It is used as a catalyst.