An ice spike is an ice formation, often in the shape of an inverted icicle, that projects upwards from the surface of a body of frozen water. Ice spikes created by natural processes on the surface of small bodies of frozen water have been reported for many decades, although their occurrence is quite rare. A mechanism for their formation, now known as the Bally–Dorsey model, was proposed in the early 20th century but this was not tested in the laboratory for many years. In recent years a number of photographs of natural ice spikes have appeared on the Internet as well as methods of producing them artificially by freezing distilled water in domestic refrigerators or freezers. This has allowed a small number of scientists to test the hypothesis in a laboratory setting and, although the experiments appear to confirm the validity of the Bally–Dorsey model, they have raised further questions about how natural ice spikes form, and more work remains to be done before the phenomenon is fully understood. Natural ice spikes can grow into shapes other than a classic spike shape, and have been variously reported as ice candles, ice towers or ice vases as there is no standard nomenclature for these other forms. One particularly unusual form takes the shape of an inverted pyramid. [1]
Although natural ice spikes are usually measured in inches or centimeters, a report that appeared in the Harbor Creek Historical Society Newsletter by Canadian Gene Heuser, who hiked across frozen Lake Erie in 1963, spoke of "small pinholes in the ice through which the water below was periodically forced under pressure to spout up into the air and freeze" producing five-foot-high (1.5 m) "frozen spurts that looked to him like telephone poles standing straight up all over the lake". [2]
Ice spikes have been reported as a rare natural phenomenon for decades. [3] A model of the mechanism of formation was put forth independently by O. Bally and H.E. Dorsey in the early 20th century and this is still the most widely accepted explanation of the phenomenon today. [4] Spikes tend to form in containers such as bird baths and pet drinking bowls, where the water freezes quickly, rather than in large bodies of water such as lakes and ponds. [5] A number of web pages displaying photographs of unusual ice formations and discussing the phenomenon have been published, and a number of cases of ice spikes being formed on ice cubes in domestic refrigerators have been reported. [6] [7] The ability to grow ice spikes in a controlled environment has prompted a small number of investigations by the researchers in the Physics Department of the California Institute of Technology under the direction of Kenneth G. Libbrecht into the conditions needed for the spikes to form. [3] [4]
Naturally occurring ice spikes, often in the form of circular ice candles or polyhedral ice towers (usually triangular), are occasionally found in containers of frozen rainwater or tapwater. [8] Water expands by 9% as it freezes into ice and the simplest shape of an ice crystal that reflects its internal structure is a hexagonal prism. The top and bottom faces of the crystal are hexagonal planes called basal planes and the direction that is perpendicular to the basal planes is called the c-axis. [9]
The process begins when surface water nucleates around irregularities where it meets the container wall. If the c-axis of the first crystal to form is not vertical, the basal plane intersects the surface along a line perpendicular to the c-axis and ice needles tend to propagate across the surface along this line. Simply put, the surface freezes from the edges inward, so that only a small surface hole remains unfrozen. [9] The crystallite curtains tend to join at an angle of 60 degrees and so the hole is often triangular. [6] The continuing freezing of water that is below the surface ice then slowly pushes the remaining water up through the hole. Reaching very cold air, the edge of the extruded water freezes while remaining liquid in the center. more freezing below pushes more water up, the edge freezes, and so on. If the rate of extrusion of water is the same as the rate of freezing at the lip of the hole, then this process is continually repeated and successive layers form an upward-growing tube of ice. [9] The formation of ice spikes is related to the shape of the water body, the concentration of dissolved impurities, air temperature and circulation above the water. [3] Spikes that grow from a crystallite formed below the surface of the water may project from the ice sheet at a steep angle, rather than perpendicular to it. [5] The ice spike process is rare - more commonly the surface freezes over entirely, and as water under the surface freezes it pushes all of the surface ice upward.
Small ice spikes can be formed artificially on ice cubes produced in domestic refrigerators; using distilled water in plastic ice cube trays. The formation of the spike is similar to that of the naturally occurring spike in that the expansion of interior water and, the reduction of volume in the interior of the cube, increase the pressure on the water pushing it upward through the hole. The growth of the tube ceases when the drop at the top of the tube freezes entirely, which is substantially before the rest of the water in the cube is frozen. [4] This method produces small spikes which are usually round or triangular in cross section with sharp tips. Experiments using this method have been carried out in laboratory settings but it has been found that spikes are less likely to form in ice cubes made from non-distilled water as impurities in the water inhibit spike formation. [nb 1] [10] This poses the question of how naturally occurring ice spikes form in tapwater or rainwater and, Libbrecht and Lui have suggested that, in the case of the small spikes grown in a refrigerator, impurities will become increasingly concentrated in the small unfrozen droplet at the top of the tube reducing the freezing rate and so the growth of the tube. However, they believe that on the rare occasions when exceptionally large spikes grow in natural, outdoor ice formations, some other mechanism must remove the impurities that build up at the top of the growing tube. Either impurities are forced into pockets that freeze more slowly, or perhaps a convective flow, which would be insignificant in the smaller, artificially grown spikes, replaces the water at the top of the tube with fresh water from below. [3]
The results of the work carried out at Caltech have suggested experiments that might further elucidate this phenomenon. [3] [4]
A crystal or crystalline solid is a solid material whose constituents are arranged in a highly ordered microscopic structure, forming a crystal lattice that extends in all directions. In addition, macroscopic single crystals are usually identifiable by their geometrical shape, consisting of flat faces with specific, characteristic orientations. The scientific study of crystals and crystal formation is known as crystallography. The process of crystal formation via mechanisms of crystal growth is called crystallization or solidification.
Frost is a thin layer of ice on a solid surface, which forms from water vapor that deposits onto a freezing surface. Frost forms when the air contains more water vapor than it can normally hold at a specific temperature. The process is similar to the formation of dew, except it occurs below the freezing point of water typically without crossing through a liquid state.
Diamond dust is a ground-level cloud composed of tiny ice crystals. This meteorological phenomenon is also referred to simply as ice crystals and is reported in the METAR code as IC. Diamond dust generally forms under otherwise clear or nearly clear skies, so it is sometimes referred to as clear-sky precipitation. Diamond dust is most commonly observed in Antarctica and the Arctic, but can occur anywhere with a temperature well below freezing. In the polar regions of Earth, diamond dust may persist for several days without interruption.
Freezing is a phase transition in which a liquid turns into a solid when its temperature is lowered below its freezing point. In accordance with the internationally established definition, freezing means the solidification phase change of a liquid or the liquid content of a substance, usually due to cooling.
Ice crystals are solid ice in symmetrical shapes including hexagonal columns, hexagonal plates, and dendritic crystals. Ice crystals are responsible for various atmospheric optic displays and cloud formations.
An icicle is a spike of ice formed when water falling from an object freezes.
Freezing food preserves it from the time it is prepared to the time it is eaten. Since early times, farmers, fishermen, and trappers have preserved grains and produce in unheated buildings during the winter season. Freezing food slows decomposition by turning residual moisture into ice, inhibiting the growth of most bacterial species. In the food commodity industry, there are two processes: mechanical and cryogenic. The freezing kinetics is important to preserve the food quality and texture. Quicker freezing generates smaller ice crystals and maintains cellular structure. Cryogenic freezing is the quickest freezing technology available due to the ultra low liquid nitrogen temperature −196 °C (−320 °F).
The Mpemba effect is the name given to the observation that a liquid which is initially hot can freeze faster than the same liquid which begins cold, under otherwise similar conditions. There is disagreement about its theoretical basis and the parameters required to produce the effect.
In physics and chemistry, flash freezing is the process whereby objects are rapidly frozen. This is done by subjecting them to cryogenic temperatures, or it can be done through direct contact with liquid nitrogen at −196 °C (−320.8 °F). It is commonly used in the food industry.
An ice cube is a small piece of ice, which is typically rectangular as viewed from above and trapezoidal as viewed from the side. Ice cubes are products of mechanical refrigeration and are usually produced to cool beverages. They may be produced at home in a freezer with an ice tray or in an automated ice-making accessory. They may also be produced industrially and sold commercially.
A refrigerator, commonly fridge, is a commercial and home appliance consisting of a thermally insulated compartment and a heat pump that transfers heat from its inside to its external environment so that its inside is cooled to a temperature below the room temperature. Refrigeration is an essential food storage technique around the world. The low temperature reduces the reproduction rate of bacteria, so the refrigerator lowers the rate of spoilage. A refrigerator maintains a temperature a few degrees above the freezing point of water. The optimal temperature range for perishable food storage is 3 to 5 °C. A freezer is a specialized refrigerator, or portion of a refrigerator, that maintains its contents’ temperature below the freezing point of water. The refrigerator replaced the icebox, which had been a common household appliance for almost a century and a half. The United States Food and Drug Administration recommends that the refrigerator be kept at or below 4 °C (40 °F) and that the freezer be regulated at −18 °C (0 °F).
A domestic ice cream maker is a machine used to make small quantities of ice cream for personal consumption. Ice cream makers may prepare the mixture by employing the hand-cranking method or by employing an electric motor. The resulting preparation is often chilled through either pre-cooling the machine or by employing a machine that freezes the mixture.
Rime ice forms when supercooled water droplets freeze onto surfaces. In the atmosphere, there are three basic types of rime ice:
In thermodynamics, nucleation is the first step in the formation of either a new thermodynamic phase or structure via self-assembly or self-organization within a substance or mixture. Nucleation is typically defined to be the process that determines how long an observer has to wait before the new phase or self-organized structure appears. For example, if a volume of water is cooled significantly below 0 °C, it will tend to freeze into ice, but volumes of water cooled only a few degrees below 0 °C often stay completely free of ice for long periods (supercooling). At these conditions, nucleation of ice is either slow or does not occur at all. However, at lower temperatures nucleation is fast, and ice crystals appear after little or no delay.
An icemaker, ice generator, or ice machine may refer to either a consumer device for making ice, found inside a home freezer; a stand-alone appliance for making ice, or an industrial machine for making ice on a large scale. The term "ice machine" usually refers to the stand-alone appliance.
Anchor ice is defined by the World Meteorological Organization as "submerged ice attached or anchored to the bottom, irrespective of the nature of its formation". It may also be called bottom-fast ice. Anchor ice is most commonly observed in fast-flowing rivers during periods of extreme cold, at the mouths of rivers flowing into very cold seawater, in the shallow sub or intertidal during or after storms when the air temperature is below the freezing point of the water, and the subtidal in the Antarctic along ice shelves or near floating glacier tongues, and in shallow lakes.
Needle ice is a needle-shaped column of ice formed by groundwater. Needle ice forms when the temperature of the soil is above 0 °C (32 °F) and the surface temperature of the air is below 0 °C (32 °F). Liquid water underground rises to the surface by capillary action, and then freezes and contributes to a growing needle-like ice column. The process usually occurs at night when the air temperature reaches its minimum.
A snowflake is a single ice crystal that has achieved a sufficient size, and may have amalgamated with others, which falls through the Earth's atmosphere as snow. Each flake nucleates around a tiny particle in supersaturated air masses by attracting supercooled cloud water droplets, which freeze and accrete in crystal form. Complex shapes emerge as the flake moves through differing temperature and humidity zones in the atmosphere, such that individual snowflakes differ in detail from one another, but may be categorized in eight broad classifications and at least 80 individual variants. The main constituent shapes for ice crystals, from which combinations may occur, are needle, column, plate, and rime. Snow appears white in color despite being made of clear ice. This is due to diffuse reflection of the whole spectrum of light by the small crystal facets of the snowflakes.
Pumpable icetechnology (PIT) uses thin liquids, with the cooling capacity of ice. Pumpable ice is typically a slurry of ice crystals or particles ranging from 5 micrometers to 1 cm in diameter and transported in brine, seawater, food liquid, or gas bubbles of air, ozone, or carbon dioxide.
A brinicle is a downward-growing hollow tube of ice enclosing a plume of descending brine that is formed beneath developing sea ice.