Ice nucleus

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Ice nucleation mechanisms describe four modes that are responsible for the formation of primary ice crystals in the atmosphere. Ice Nucleation Mechanisms.png
Ice nucleation mechanisms describe four modes that are responsible for the formation of primary ice crystals in the atmosphere.

An ice nucleus, also known as an ice nucleating particle (INP), is a particle which acts as the nucleus for the formation of an ice crystal in the atmosphere.

Contents

Ice nucleation mechanisms

There are a number of mechanisms of ice nucleation in the atmosphere through which ice nuclei can catalyse the formation of ice particles. In the upper troposphere, water vapor can deposit directly onto solid particles. In clouds warmer than about 37 °C where liquid water can persist in a supercooled state, ice nuclei can trigger droplets to freeze. [1]

Contact nucleation can occur if an ice nucleus collides with a supercooled droplet, but the more important mechanism of freezing is when an ice nucleus becomes immersed in a supercooled water droplet and then triggers freezing.

In the absence of an ice nucleating particle, pure water droplets can persist in a supercooled state to temperatures approaching 37 °C where they freeze homogeneously. [2] [3] [4]

As per Web of Science, the key word "ice nucleation" that appeared under Met Atm Sci and Env Sci categories till Dec 2021 was plotted using number of papers published.

Growth of number of papers with keyword Ice Nucleation Growth of number of papers with keyword Ice Nucleation.jpg
Growth of number of papers with keyword Ice Nucleation

There are several research groups that study ice nucleating properties of atmospheric aerosols (for example see FIN-02 research article by DeMott et al. 2018 or the FIN-02 INP measurement intercomparison study [5] ). The ice nucleation research capability is also available through user facility call at EMSL, PNNL. [6]

Cloud dynamics

Ice particles can have a significant effect on cloud dynamics. They are known to be important in the processes by which clouds can become electrified, which causes lightning. They are also known to be able to form the seeds for rain droplets. It has become clear that the concentration of ice nucleating particles in shallow clouds is a key factor in cloud-climate feedbacks. [7] [8]

Atmospheric particulate matter

Many different types of atmospheric particulate matter can act as ice nuclei, both natural and anthropogenic, including those composed of desert dust, soot, organic matter, bacteria (e.g. Pseudomonas syringae ), pollen, fungal spores and volcanic ash amongst others. [1] [9] However, the exact nucleation potential of each type varies greatly, depending on the exact atmospheric conditions. Very little is known about the spatial distribution of these particles, their overall importance for global climate through ice cloud formation, and whether human activity has played a major role in changing these effects.

See also

Related Research Articles

<span class="mw-page-title-main">Ice</span> Frozen water: the solid state of water

Ice is water that is frozen into a solid state, typically forming at or below temperatures of 32 °F, 0 °C, or 273.15 K. As a naturally occurring crystalline inorganic solid with an ordered structure, ice is considered to be a mineral. Depending on the presence of impurities such as particles of soil or bubbles of air, it can appear transparent or a more or less opaque bluish-white color.

<span class="mw-page-title-main">Cirrus cloud</span> Genus of atmospheric cloud

Cirrus is a genus of high cloud made of ice crystals. Cirrus clouds typically appear delicate and wispy with white strands. Cirrus are usually formed when warm, dry air rises, causing water vapor deposition onto rocky or metallic dust particles at high altitudes. Globally, they form anywhere between 4,000 and 20,000 meters above sea level, with the higher elevations usually in the tropics and the lower elevations in more polar regions.

<span class="mw-page-title-main">Cloud albedo</span> Fraction of incoming sunlight reflected by clouds

Cloud albedo is a measure of the albedo or reflectivity of a cloud. Clouds regulate the amount of solar radiation absorbed by a planet and its solar surface irradiance. Generally, increased cloud cover correlates to a higher albedo and a lower absorption of solar energy. Cloud albedo strongly influences the Earth's energy budget, accounting for approximately half of Earth's albedo. Cloud albedo depends on the total mass of water, the size and shape of the droplets or particles and their distribution in space. Thick clouds reflect a large amount of incoming solar radiation, translating to a high albedo. Thin clouds tend to transmit more solar radiation and, therefore, have a low albedo. Changes in cloud albedo caused by variations in cloud properties have a significant effect on global climate.

<span class="mw-page-title-main">Freezing</span> Phase transition in which a liquid turns into a solid due to a decrease in thermal energy

Freezing is a phase transition where a liquid turns into a solid when its temperature is lowered below its freezing point. In accordance with the internationally established definition, freezing means the solidification phase change of a liquid or the liquid content of a substance, usually due to cooling.

<span class="mw-page-title-main">Ice crystal</span> Water ice in symmetrical shapes

Ice crystals are solid ice in symmetrical shapes including hexagonal columns, hexagonal plates, and dendritic crystals. Ice crystals are responsible for various atmospheric optic displays and cloud formations.

<span class="mw-page-title-main">Supercooling</span> Lowering the temperature of a liquid below its freezing point without it becoming a solid

Supercooling, also known as undercooling, is the process of lowering the temperature of a liquid below its freezing point without it becoming a solid. It is achieved in the absence of a seed crystal or nucleus around which a crystal structure can form. The supercooling of water can be achieved without any special techniques other than chemical demineralization, down to −48.3 °C (−54.9 °F). Droplets of supercooled water often exist in stratus and cumulus clouds. An aircraft flying through such a cloud sees an abrupt crystallization of these droplets, which can result in the formation of ice on the aircraft's wings or blockage of its instruments and probes.

<span class="mw-page-title-main">Cloud condensation nuclei</span> Small particles on which water vapor condenses

Cloud condensation nuclei (CCNs), also known as cloud seeds, are small particles typically 0.2 µm, or one hundredth the size of a cloud droplet. CCNs are a unique subset of aerosols in the atmosphere on which water vapour condenses. This can affect the radiative properties of clouds and the overall atmosphere. Water requires a non-gaseous surface to make the transition from a vapour to a liquid; this process is called condensation.

In physics and chemistry, flash freezing is the process whereby objects are frozen in just a few hours by subjecting them to cryogenic temperatures, or through direct contact with liquid nitrogen at −196 °C (−320.8 °F). It is commonly used in the food industry.

<span class="mw-page-title-main">Cloud physics</span> Study of the physical processes in atmospheric clouds

Cloud physics is the study of the physical processes that lead to the formation, growth and precipitation of atmospheric clouds. These aerosols are found in the troposphere, stratosphere, and mesosphere, which collectively make up the greatest part of the homosphere. Clouds consist of microscopic droplets of liquid water, tiny crystals of ice, or both, along with microscopic particles of dust, smoke, or other matter, known as condensation nuclei. Cloud droplets initially form by the condensation of water vapor onto condensation nuclei when the supersaturation of air exceeds a critical value according to Köhler theory. Cloud condensation nuclei are necessary for cloud droplets formation because of the Kelvin effect, which describes the change in saturation vapor pressure due to a curved surface. At small radii, the amount of supersaturation needed for condensation to occur is so large, that it does not happen naturally. Raoult's law describes how the vapor pressure is dependent on the amount of solute in a solution. At high concentrations, when the cloud droplets are small, the supersaturation required is smaller than without the presence of a nucleus.

<span class="mw-page-title-main">Nucleation</span> Initial step in the phase transition or molecular self-assembly of a substance

In thermodynamics, nucleation is the first step in the formation of either a new thermodynamic phase or structure via self-assembly or self-organization within a substance or mixture. Nucleation is typically defined to be the process that determines how long an observer has to wait before the new phase or self-organized structure appears. For example, if a volume of water is cooled below 0 °C, it will tend to freeze into ice, but volumes of water cooled only a few degrees below 0 °C often stay completely free of ice for long periods (supercooling). At these conditions, nucleation of ice is either slow or does not occur at all. However, at lower temperatures nucleation is fast, and ice crystals appear after little or no delay.

The Wegener–Bergeron–Findeisen process, is a process of ice crystal growth that occurs in mixed phase clouds in regions where the ambient vapor pressure falls between the saturation vapor pressure over water and the lower saturation vapor pressure over ice. This is a subsaturated environment for liquid water but a supersaturated environment for ice resulting in rapid evaporation of liquid water and rapid ice crystal growth through vapor deposition. If the number density of ice is small compared to liquid water, the ice crystals can grow large enough to fall out of the cloud, melting into rain drops if lower level temperatures are warm enough.

<span class="mw-page-title-main">Atmospheric icing</span> Weather condition in which water droplets freeze onto objects they come in contact with

Atmospheric icing occurs in the atmosphere when water droplets suspended in air freeze on objects they come in contact with. It is not the same as freezing rain, which is caused directly by precipitation. Icing conditions can be particularly dangerous to aircraft, as the built-up ice changes the aerodynamics of the flight surfaces and airframe, which can increase the risk of a stall and potentially accidents. For this reason, on-board ice protection systems have been developed on aircraft intended to fly through these conditions.

Amorphous ice is an amorphous solid form of water. Common ice is a crystalline material wherein the molecules are regularly arranged in a hexagonal lattice, whereas amorphous ice lacks long-range order in its molecular arrangement. Amorphous ice is produced either by rapid cooling of liquid water, or by compressing ordinary ice at low temperatures.

<span class="mw-page-title-main">Crystal growth</span> Major stage of a crystallization process

A crystal is a solid material whose constituent atoms, molecules, or ions are arranged in an orderly repeating pattern extending in all three spatial dimensions. Crystal growth is a major stage of a crystallization process, and consists of the addition of new atoms, ions, or polymer strings into the characteristic arrangement of the crystalline lattice. The growth typically follows an initial stage of either homogeneous or heterogeneous nucleation, unless a "seed" crystal, purposely added to start the growth, was already present.

<span class="mw-page-title-main">Graupel</span> Precipitation that forms when supercooled droplets of water freeze on a falling snowflake

Graupel, also called soft hail, hominy snow, or snow pellets, is precipitation that forms when supercooled water droplets in air are collected and freeze on falling snowflakes, forming 2–5 mm (0.08–0.20 in) balls of crisp, opaque rime.

<span class="mw-page-title-main">CLOUD experiment</span> Aerosol nucleation experiment at CERN

Cosmics Leaving Outdoor Droplets (CLOUD) is an experiment being run at CERN by a group of researchers led by Jasper Kirkby to investigate the microphysics between galactic cosmic rays (GCRs) and aerosols under controlled conditions. This is a fixed-target experiment that began operation in November 2009, though it was originally proposed in 2000.

<span class="mw-page-title-main">Snowflake</span> Ice crystals that fall as snow

A snowflake is a single ice crystal that has achieved a sufficient size, and may have amalgamated with others, which falls through the Earth's atmosphere as snow. Each flake nucleates around a tiny particle in supersaturated air masses by attracting supercooled cloud water droplets, which freeze and accrete in crystal form. Complex shapes emerge as the flake moves through differing temperature and humidity zones in the atmosphere, such that individual snowflakes differ in detail from one another, but may be categorized in eight broad classifications and at least 80 individual variants. The main constituent shapes for ice crystals, from which combinations may occur, are needle, column, plate, and rime. Snow appears white in color despite being made of clear ice. This is due to diffuse reflection of the whole spectrum of light by the small crystal facets of the snowflakes.

Classical nucleation theory (CNT) is the most common theoretical model used to quantitatively study the kinetics of nucleation.

<span class="mw-page-title-main">Cirrus cloud thinning</span> Proposed form of climate engineering

Cirrus cloud thinning (CCT) is a proposed form of climate engineering. Cirrus clouds are high cold ice that, like other clouds, both reflect sunlight and absorb warming infrared radiation. However, they differ from other types of clouds in that, on average, infrared absorption outweighs sunlight reflection, resulting in a net warming effect on the climate. Therefore, thinning or removing these clouds would reduce their heat trapping capacity, resulting in a cooling effect on Earth's climate. This could be a potential tool to reduce anthropogenic global warming. Cirrus cloud thinning is an alternative category of climate engineering, in addition to solar radiation management and greenhouse gas removal.

<span class="mw-page-title-main">North Atlantic Aerosols and Marine Ecosystems Study</span>

The North Atlantic Aerosols and Marine Ecosystems Study (NAAMES) was a five-year scientific research program that investigated aspects of phytoplankton dynamics in ocean ecosystems, and how such dynamics influence atmospheric aerosols, clouds, and climate. The study focused on the sub-arctic region of the North Atlantic Ocean, which is the site of one of Earth's largest recurring phytoplankton blooms. The long history of research in this location, as well as relative ease of accessibility, made the North Atlantic an ideal location to test prevailing scientific hypotheses in an effort to better understand the role of phytoplankton aerosol emissions on Earth's energy budget.

References

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